Abstract
A large amount of crude oils located in front of the combustion front experience low-temperature oxidation (LTO) reactions under relatively constant temperatures over a long period, as a result of the quite slow advancing speed of combustion front during an in situ combustion process. However, the isothermal LTO characteristics of crude oils are still less well understood. In this work, the evolution of mass losses and evolved gases of one crude oil and its saturates–aromatics–resins–asphaltenes (SARA) components during LTO under isothermal conditions was investigated using thermogravimetry connected with Fourier transform infrared spectroscopy. The results suggested that the mass loss at the LTO region was mostly caused by the evaporation of hydrocarbons. Almost no CO2 was emitted from 50 to 350 °C for saturates, aromatics, and resins, whereas the absorbance of CO2 was observed at 300 °C for asphaltenes. During LTO of the oil and its SARA components between 150 and 350 °C, the signal of compounds with C=O group was notably higher than that of compounds with C–O group. Additionally, the effect of the interactions between SARA components on the evolved gases and LTO reaction rate was analyzed. The interactions between SARA components promoted the formation of products with carbonyl group at 100 and 300 °C but inhibited the formation of these products at 200 °C. A better understanding to the gas products emitted by heavy oil LTO could be achieved based on this investigation on the SARA components.
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References
Pu WF, Zhao S, Pan JJ, Wang RY, Chen L, Kan N, Wang LL. Comparative analysis of quartz sand and detritus effects on thermal behavior and kinetics of heavy crude oil. Thermochim Acta. 2018;667:153–9.
Kok MV, Gul KG. Thermal characteristics and kinetics of crude oils and SARA fractions. Thermochim Acta. 2013;569:66–70.
Kok MV, Varfolomeev MA, Nurgaliev DK. Low-temperature oxidation reactions of crude oils using TGA–DSC techniques. J Therm Anal Calorim. 2020;141:775–81.
Vargas JAV, Santos RGD, Trevisan OV. Evaluation of crude oil oxidation by accelerating rate calorimetry. J Therm Anal Calorim. 2013;113:897–908.
Kok MV, Acar C. Kinetics of crude oil combustion. J Therm Anal Calorim. 2006;83(2):445–9.
Murugan P, Mahinpey N, Mani T, Asghari K. Effect of low-temperature oxidation on the pyrolysis and combustion of whole oil. Energy. 2010;35(5):2317–22.
Sarma H, Yazawa N, Moore R, Metha S, Okazawa N, Ferguson H, et al. Screening of three light-oil reservoirs for application of air injection process by accelerating rate calorimetric and TG/PDSC tests. J Can Pet Technol. 2002;41(3):50–61.
Jia C, Wang Q, Ge J, Xu X. Pyrolysis and combustion model of oil sands from non-isothermal thermogravimetric analysis data. J Therm Anal Calorim. 2014;116(2):1073–81.
Li YB, Chen Y, Pu WF, Gao H, Bai B. Experimental investigation into the oxidative characteristics of Tahe heavy crude oil. Fuel. 2017;209:194–202.
Zhao S, Pu W, Varfolomeev MA, Yuan C, Rodionov AA. Integrative investigation of low-temperature oxidation characteristics and mechanisms of heavy crude oil. Ind Eng Chem Res. 2019;58(31):14595–602.
Zhao S, Pu W, Varfolomeev MA, Yuan C, Pan J, Wang R, et al. Low-temperature oxidation of light and heavy oils via thermal analysis: Kinetic analysis and temperature zone division. J Pet Sci Eng. 2018;168:246–55.
Pu W, Zhao S, Hu L, Varfolomeev MA, Yuan C, Wang L, et al. Thermal effect caused by low temperature oxidation of heavy crude oil and its in-situ combustion behavior. J Pet Sci Eng. 2020;184:106521.
Zhao S, Pu WF, Varfolomeev MA, Yuan CD, Zhang JZ, Han XQ, et al. Comprehensive investigations into low temperature oxidation of heavy crude oil. J Pet Sci Eng. 2018;171:835–42.
Freitag NP, Verkoczy B. Low-temperature oxidation of oils in terms of SARA fractions: why simple reaction models don’t work. J Can Pet Technol. 2005;44:54–61.
Liu D, Song Q, Tang J, Zheng R, Yao Q. Interaction between saturates, aromatics and resins during pyrolysis and oxidation of heavy oil. J Pet Sci Eng. 2016;154:543–50.
Li YB, Pu WF, Sun L, Jin FY, Zhao JY, Zhao JZ, Huang T. Effect of formation factors on light crude oil oxidation via TG-FTIR. J Therm Anal Calorim. 2014;118:1685–95.
Varfolomeev MA, Galukhin A, Nurgaliev DK, Kok MV. Thermal decomposition of Tatarstan Ashal’cha heavy crude oil and its SARA fractions. Fuel. 2016;186:122–7.
Zhao S, Wanfen P, Chengdong Y, Xiaoqiang P, Jizhou Z, Liangliang W, et al. Thermal behavior and kinetic triplets of heavy crude oil and its SARA fractions during combustion by high-pressure differential scanning calorimetry. Energy Fuels. 2019;33:3176–86.
Wei B, Zou P, Shang J, Gao K, Li Y, Sun L, et al. Integrative determination of the interactions between SARA fractions of an extra-heavy crude oil during combustion. Fuel. 2018;234:850–7.
Zhao RB, Zhang CH, Yang FX, Heng MH, Shao PT, Wang YJ. Influence of temperature field on rock and heavy components variation during in-situ combustion process. Fuel. 2018;230:244–57.
Guan W, Xi C, Chen Y, Zhang X, Muhetar, Liang J, et al. Fire-flooding technologies in post-steam-injected heavy oil reservoirs. Pet Explor Dev. 2011;38(4):452–63.
Khansari Z, Gates ID, Mahinpey N. Low-temperature oxidation of Lloydminster heavy oil: Kinetic study and product sequence estimation. Fuel. 2014;115(1):534–8.
Khansari Z, Gates ID, Mahinpey N. Detailed study of low-temperature oxidation of an Alaska heavy oil. Energy Fuels. 2012;26(3):1592–7.
Yuan CD, Emelianov D, Varfolomeev MA. Oxidation behavior and kinetics of light, medium and heavy crude oils characterized by thermogravimetry coupled with Fourier-transform infrared spectroscopy (TG-FTIR). Energy Fuels. 2018;32(4):5571–81.
Kok MV, Varfolomeev MA, Nurgaliev DK. Thermal characterization of crude oils in the presence of limestone matrix by TGA-DTG-FTIR. J Pet Sci Eng. 2017;154:495–501.
Qi X, Chen L, Zhang L, Bai C, Xin H, Rao Z. In situ FTIR study on real-time changes of active groups during lignite reaction under low oxygen concentration conditions. J Energy Inst. 2019;92(5):1557–66.
Tian L, Yang W, Chen Z, Wang X, Yang H, Chen H. Sulfur behavior during coal combustion in oxy-fuel circulating fluidized bed condition by using TG-FTIR. J Energy Inst. 2016;89(2):264–70.
Liu Q, Wang S, Zheng Y, Luo Z, Cen K. Mechanism study of wood lignin pyrolysis by using TG–FTIR analysis. J Anal Appl Pyrolysis. 2008;82(1):170–7.
Hao JH, Che YJ, Tian YY, Li DW, Zhang JH, Qiao YY. Study on thermal cracking characteristics and kinetics of oil sand bitumen and its SARA fractions by TG–FTIR. Energy Fuels. 2017;31(2):1295–309.
Freitag NP. Chemical reaction mechanisms that govern oxidation rates during in-situ combustion and high-pressure air injection. SPE Reserv Eval Eng. 2016;19:645–54.
Ushakova A, Zatsepin V, Varfolomeev M, Emelyanov D. Study of the radical chain mechanism of hydrocarbon oxidation for in situ combustion process. J Combust. 2017;11:1–11.
Yuan C, Emelianov DA, Varfolomeev MA, Abaas M. Comparison of oxidation behavior of linear and branched alkanes. Fuel Process Technol. 2019;188:203–11.
Wang Z, Popolan-Vaida DM, Chen B, Moshammer K, Mohamed SY, Wang H, et al. Unraveling the structure and chemical mechanisms of highly oxygenated intermediates in oxidation of organic compounds. Proc Nat Acad Sci. 2017;114:13102–7.
Fu P, Hu S, Xiang J, Li P, Huang D, Jiang L, et al. FTIR study of pyrolysis products evolving from typical agricultural residues. J Anal Appl Pyrolysis. 2010;88(2):117–23.
Zhao S, Pu W, Sun B, Gu F, Wang L. Comparative evaluation on the thermal behaviors and kinetics of combustion of heavy crude oil and its SARA fractions. Fuel. 2019;239:117–25.
Wang T, Yang W, Wang J, Kalitaani S, Deng Z. Low temperature oxidation of crude oil: Reaction progress and catalytic mechanism of metallic salts. Fuel. 2018;225:336–42.
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This work was supported by Chinese Postdoctoral Science Foundation and Russian Government Program of Competitive Growth of Kazan Federal University.
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Huo, J., Zhao, S., Pan, J. et al. Evolution of mass losses and evolved gases of crude oil and its SARA components during low-temperature oxidation by isothermal TG–FTIR analyses. J Therm Anal Calorim 147, 4099–4112 (2022). https://doi.org/10.1007/s10973-021-10841-z
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DOI: https://doi.org/10.1007/s10973-021-10841-z