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Ni olivine: thermal behavior of liebenbergite

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Abstract

The synthetic samples of nickel olivine were measured in the temperature range 100–630 K by the X-ray powder diffraction method. Temperature dependencies of molar volumes and coefficients of bulk thermal expansion of liebenbergite were determined. Interpolation and extrapolation of the experimental data were performed by the procedure based on the Debye–Mie–Gruneisen theory of solid body in the range from 50 to 2000 K, and the Gruneisen coefficient and Debye temperature were calculated. Heat capacity and its behavior in accordance with temperature were evaluated.

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Acknowledgements

We thank Tolstyh O. for the help in measurements and Kuznetsov G. for the fruitful cooperation in calculations. This work was supported by the Russian Foundation for Basic Research (№ 0330-2016-0016).

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  1. Institute of Geology and Mineralogy SB RAS, Koptyuga 3, Novosibirsk, Russian Federation, 630090

    Yuliya Gartvich & Valeriy Galkin

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  1. Yuliya Gartvich
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  2. Valeriy Galkin
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Correspondence to Yuliya Gartvich.

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Gartvich, Y., Galkin, V. Ni olivine: thermal behavior of liebenbergite. J Therm Anal Calorim 136, 2333–2339 (2019). https://doi.org/10.1007/s10973-018-7859-6

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  • DOI: https://doi.org/10.1007/s10973-018-7859-6

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