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Crystal structure and thermodynamic properties of sodium d-gluconate Na[d-C6H11O7](s)

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Abstract

The sodium d-gluconate Na[d-C6H11O7](s) has been synthesized and characterized by elemental analysis and X-ray crystallography. X-ray single-crystal analysis reveals that the compound exhibits an obvious chelate property of d-gluconate anions to sodium cation, and the latter is coordinated to six d-gluconate anions. The lattice potential energy of the compound and ionic volume of the d-gluconate anion are obtained from crystallographic data. In accordance with law of Hess, a reasonable thermochemical cycle is designed and the standard molar enthalpy of formation of the compound Na[d-C6H11O7](s) is determined to be −(1472.68 ± 0.48) kJ mol−1 by use of an isoperibol solution-reaction calorimeter. Molar enthalpies of dissolution of Na[d-C6H11O7](s) at various molalities are measured at T = 298.15 K in the double-distilled water. According to Pitzer’s electrolyte solution theory, molar enthalpy of dissolution of the title compound at infinite dilution is determined to be (23.783 ± 0.128) kJ mol−1.

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Acknowledgements

This work is financially supported by the National Natural Science Foundations of China under the contract NSFC Nos. 21273171 and 21273100.

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Authors and Affiliations

  1. College of Chemical Engineering and Modern Materials, Shangluo University/Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, Shangluo, 726000, Shaanxi Province, People’s Republic of China

    You-Ying Di & Chun-Sheng Zhou

  2. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Yu-Han Zhang, Yu-Pu Liu & Yu-Xia Kong

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  1. You-Ying Di
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Correspondence to You-Ying Di.

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Di, YY., Zhang, YH., Liu, YP. et al. Crystal structure and thermodynamic properties of sodium d-gluconate Na[d-C6H11O7](s). J Therm Anal Calorim 127, 1835–1843 (2017). https://doi.org/10.1007/s10973-016-6033-2

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