Abstract
In this work, experimental results for surface tension of aqueous solutions of 3-aminopropanoic acid, 4-aminobutanoic acid, 5-aminopentanoic acid and 6-aminohexanoic acid at T = (293.15, 298.15, 303.15 and 308.15) K at several concentrations are presented. The results were used to evaluate the limiting experimental slopes of surface tension with respect to mole fraction at each temperature. Surface tension measurements were taken using a LAUDA TVT-2 drop volume tensiometer with temperature control better than 0.1 K at T = (293.15, 298.15, 303.15 and 308.15) K The thermodynamic behavior of the aqueous α,ω-amino acid solutions is compared with that reported for α-amino acids in water. The surface behavior is discussed in terms of the effect of the hydrocarbon chain and the position of polar groups on water structure. The temperature dependence of the limiting slopes of surface tension with respect to mole fraction, derived from surface tension measurements, is discussed.
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References
Drost-Hansen W. Aqueous interfaces—methods of study and structural properties—part two. Ind Eng Chem. 1965;57:18–37.
Blandamer MJ, Cullis PM, Soldi LG, Engberts JBFN, Kacperska A, Van Os NM, Subha MCS. Thermodynamics of micellar systems: comparison of mass action and phase equilibrium models for the calculation of standard Gibbs energies of micelle formation. Adv Colloid Interface Sci. 1995;58:171–209.
Yaminsky VV. Ninham UBW. Surface forces vs. surface compositions. Colloid science from the Gibbs adsorption perspective. Adv Colloid Interface Sci. 1999;83:227–311.
Piñeiro A, Brocos P, Bravo R, Amigo A. A comprehensive approach to the surface tension of binary liquid mixtures. Fluid Phase Equilib. 2001;182:337–52.
Ramirez-Verduzco LF, Romero-Martinez A, Trejo A. Prediction of the surface tension, surface concentration, and the relative Gibbs adsorption isotherm of binary liquid systems. Fluid Phase Equilib. 2006;246:119–30.
Hoke BC, Chen JC. Binary aqueous organic surface tension temperature dependence. J Chem Eng Data. 2001;36:322–6.
Zhao H. Review: viscosity B-coefficients and standard partial molar volumes of amino acids, and their roles in interpreting the protein (enzyme) stabilization. Biophys Chem. 2006;122:157–83.
Matubayasi N, Miyamoto H, Nahimira J, Yano K, Tanaka T. Thermodynamic quantities of surface formation of aqueous electrolyte solutions: V. Aqueous solutions of aliphatic amino acids. J Colloid Interface Sci. 2002;250:431–7.
Pappenheimer JR, Lepie MP, Wyman JJ. The surface tension of aqueous solutions of dipolar ions. J Am Chem Soc. 1936;58:1851–5.
Belton JW. The capillary properties of α-amino-acids. Trans Faraday Soc. 1939;35:1293–8.
Glinski J, Chavepeyer G, Platten J. Surface properties of aqueous solutions of L-leucine. Biophys Chem. 2000;84:99–103.
Bull HB, Breese K. Surface tension of amino acid solutions: a hydrophobicity scale of the amino acid residues. Arch Biochem Biophys. 1974;161:665–70.
Romero CM, Oviedo CD. Effect of temperature on the solubility of α-amino acids and α, ω-amino acids in water. J Solut Chem. 2013;42:1355–62.
Romero CM, Cadena JC. Effect of temperature on the volumetric properties of α, ω-amino acids in dilute aqueous solutions. J Solut Chem. 2010;39:1474–83.
Romero CM, Cadena JC, Lamprecht I. Effect of temperature on the dilution enthalpies of α, ω-amino acids in aqueous solutions. J Chem Thermodyn. 2011;43:1441–5.
Weissberger A. Techniques in chemistry vol I, part 4: methods of chemistry. New York: Wiley Interscience; 1972.
Kitano I, Takaha K, Gemmei-Ide M. Raman spectroscopic study on the structure of water in aqueous solution of α, ω-amino acids. J Colloid Interface Sci. 2005;283:452–8.
Romero CM, Jiménez E, Suárez F. Effect of temperature on the behavior of surface properties of alcohols in aqueous solution. J Chem Thermodyn. 2009;41:513–6.
Connors KA, Wright JL. Dependence of surface tension on composition of binary aqueous-organic solutions. Anal Chem. 1989;61:194–8.
Romero CM, Suárez F. Apparent molar volume and surface tension of dilute aqueous solutions of carboxylic acids. J Chem Eng Data. 2011;56:1778–86.
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This work was supported by Grant DIB-8003195 from Universidad Nacional de Colombia.
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Cadena, J.C., Romero, C.M. Effect of temperature on the surface properties of α,ω-amino acids in dilute aqueous solutions. J Therm Anal Calorim 126, 1615–1619 (2016). https://doi.org/10.1007/s10973-016-5723-0
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DOI: https://doi.org/10.1007/s10973-016-5723-0