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The thermal and detailed kinetic analysis of dipicolinate complexes

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Abstract

The [Cu(pydc)(eim)3]·H2O (1), [Cu(pydc)(4hp)(H2O)] (2) and [Ni(pydc)(3hp)(H2O)2][Cu(pydc)(3hp)(H2O)2]·3H2O (3) complexes (H2pydc = 2,6-pyridinedicarboxylic acid or dipicolinic acid, eim = 2-ethylimidazole, 4hp = 4-hydroxypyridine, 3hp = 3-hydroxypyridine) were studied by thermo-gravimetric analysis at an ambient temperature up to 1000 K under nitrogen atmosphere. The complexes are stable about 350 K, and the decomposition reactions were carried out in seven, three and four stages for the complexes 1, 2 and 3, respectively. Following detailed thermo-gravimetrical analysis of the complexes, the decomposition mechanism was suggested for all complexes. The kinetic analysis of all decomposition stages of each compound was performed except for the final stages. The values of the activation energy, E a, were obtained using model-free Kissinger–Akahira–Sunose and Flyn–Wall–Ozawa methods for all decomposition stages.

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Acknowledgements

This work was supported by Dumlupinar University, Project No. 2012/22.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Dumlupınar University, 43820, Kutahya, Turkey

    Nazlı Uzun & Alper Tolga Çolak

  2. Department of Chemistry, Faculty of Arts and Sciences, Mehmet Akif Ersoy University, 15100, Burdur, Turkey

    Fatih Mehmet Emen

  3. Department of Material Science and Engineering, Faculty of Technology, Pamukkale University, 20070, Denizli, Turkey

    Gülbanu Koyundereli Çılgı

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  1. Nazlı Uzun
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Correspondence to Alper Tolga Çolak.

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Uzun, N., Çolak, A.T., Emen, F.M. et al. The thermal and detailed kinetic analysis of dipicolinate complexes. J Therm Anal Calorim 124, 1735–1744 (2016). https://doi.org/10.1007/s10973-016-5251-y

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  • DOI: https://doi.org/10.1007/s10973-016-5251-y

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