Skip to main content
Log in

Thermal stability and flame retardancy of guanidinium and imidazolium borate finished cotton fabrics

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The aim of this study was to investigate the effect of guanidinium nonaborate (GB) and imidazolium borate (IB) on thermal stability and flammability properties of cotton fabrics. The flame retardant and thermal stability properties of treated cotton fabrics were investigated using limiting oxygen index (LOI) and thermogravimetric analysis. The residues remained after LOI test were characterized by conducting attenuated total reflectance-Fourier-transform infrared spectroscopy and scanning electron microscopy with a wavelength-dispersive X-ray spectrometer. The results showed that both boron compounds increased the LOI value of cotton fabric as the amount increased by several combined flame retardant effects. IB-treated cotton fabrics had higher LOI value than GB-treated ones due to the higher increment in char yield which was the predominant flame retardant action of both boron compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Weil ED, Levchik SV. Flame retardants for plastics and textiles. Munich: Hanser Publications; 2009.

    Book  Google Scholar 

  2. Grand AF, Wilkie CA. Fire retardancy of polymeric materials. New York: Marcel Dekker; 2000.

    Google Scholar 

  3. Gaan S, Sun G. Effect of phosphorus flame retardants on thermo-oxidative decomposition of cotton. Polym Degrad Stab. 2007;92:968–74.

    Article  CAS  Google Scholar 

  4. Hu S, Hu Y, Song L, Lu H. The potential of ferric pyrophosphate for influencing the thermal degradation of cotton fabrics. J Therm Anal Calorim. 2012;109:27–32.

    Article  CAS  Google Scholar 

  5. Lecoeur E, Vroman I, Bourbigot S, Delobel R. Optimization of monoguanidine dihydrogen phosphate and amino propylethoxysilane based flame retardant formulations for cotton. Polym Degrad Stab. 2006;91:1909–14.

    Article  CAS  Google Scholar 

  6. Lessan F, Montazer M, Monghadam MB. A novel durable flame-retardant cotton fabric using sodium hypophosphite, nano TiO2 and maleic acid. Thermochim Acta. 2011;520:48–54.

    Article  CAS  Google Scholar 

  7. Liodakis S, Fetsis IK, Agiovlasitis IP. The fire-retarding effect of inorganic phosphorus compounds on the combustion of cellulosic materials. J Therm Anal Calorim. 2009;98:285–91.

    Article  CAS  Google Scholar 

  8. Mostashari SM, Baie S. TG studies of synergism between rep phosphorus (RP)-calcium chloride used in the flame-retardancy for a cotton fabric favorable to green chemistry. J Therm Anal Calorim. 2010;99:431–6.

    Article  CAS  Google Scholar 

  9. Rupper P, Gaan S, Salimova V, Heuberger M. Characterization of chars obtained from cellulose treated with phosphoramidate flame retardants. J Anal Appl Pyrol. 2010;87:93–8.

    Article  CAS  Google Scholar 

  10. Siriviriyanun A, O’Rear EA, Yanumet N. The effect of phosphorus content on the thermal and the burning properties of cotton fabric coated with ultrathin film of a phosphorus-containing polymer. Polym Degrad Stab. 2009;94:558–65.

    Article  CAS  Google Scholar 

  11. Alongi J, Colleoni C, Rosace G, Malucelli G. Thermal and fire stability of cotton fabrics coated with hybrid phosphorus-doped silica films. J Therm Anal Calorim. 2012;110:1207–16.

    Article  CAS  Google Scholar 

  12. Alongi J, Ciobanu M, Malucelli G. Sol–gel treatments on cotton fabrics for improving thermal and flame stability. Effect of the structure of alkoxysilane precursor. Carbohydr Polym. 2012;87:627–35.

    Article  CAS  Google Scholar 

  13. Alongi J, Ciobanu M, Malucelli G. Thermal stability, flame retardancy and mechanical properties of cotton fabrics treated with inorganic coatings synthesized through sol–gel process. Carbohydr Polym. 2012;87:2093–9.

    Article  CAS  Google Scholar 

  14. Cireli A, Onar N, Ebeoglu MF, Kayatekin I, Kutlu B, Culha O, Celik E. Development of flame retardancy properties of new halogen-free phosphorus doped SiO2 thin films on fabrics. J Appl Polym Sci. 2007;105:3747–56.

    Article  CAS  Google Scholar 

  15. Alongi J, Malucelli G. Cotton fabrics treated with novel oxidic phases acting as effective smoke suppressants. Carbohydr Polym. 2012;90:251–60.

    Article  CAS  Google Scholar 

  16. Kandola BK, Horrocks AR, Horrocks S. Complex char formation in flame–retarded fibre–intumescent combinations. Fire Mater. 2001;25:153–60.

    Article  CAS  Google Scholar 

  17. Karacan I, Soy T. Structure and properties of oxidatively stabilized viscose rayon fibers with boric acid and phosphoric acid prior to carbonization and activation steps. J Mater Sci. 2013;48:2009–21.

    Article  CAS  Google Scholar 

  18. Lazko J, Landery N, Laoutid F, Dangreau L, Huguet MH, Talon O. Flame retardant treatments of insulating agro-materials from flax short fibers. Polym Degrad Stab. 2013;98:1043–51.

    Article  CAS  Google Scholar 

  19. Qu H, Wu W, Wu H, Xie J, Xu J. Study on the effects of flame retardants on the thermal decomposition of wood by TG–MS. J Therm Anal Calorim. 2011;103:935–42.

    Article  CAS  Google Scholar 

  20. Xie K, Gao A, Zhang Y. Flame retardant finishing of cotton fabric based on synergistic compounds boron and nitrogen. Carbohydr Polym. 2013;98:706–10.

    Article  CAS  Google Scholar 

  21. Xu JZ, Gao M, Guo HZ, Liu XL, Li Z, Wang H, Tian CM. Study on the thermal degradation of cellulosic fibers treated with flame retardants. J Fire Sci. 2002;20:227–35.

    Article  CAS  Google Scholar 

  22. Wilkie CA, Morgan AB. Fire retardancy of polymeric materials. New York: CRC Press; 2010.

    Google Scholar 

  23. Schubert DM, Visi MZ, Knobler CB. Guanidinium and imidazolium borates containing the first examples of an isolated nonaborate oxoanion: [B9O12 (OH)6]3−. Inorg Chem. 2000;39:2250–1.

    Article  CAS  Google Scholar 

  24. Wood GL, Janik JF, Visi MZ, Schubert DM, Paine RT. New borate precursors for boron nitride powder synthesis. Chem Mater. 2005;17:1855–9.

    Article  CAS  Google Scholar 

  25. Wu L, Cheng L, Yang G. Syntheses and structures of two new borates [NH3 (CH2)4N(CH2)4N(CH2)3NH3][B5O6(OH)4]2 and [NH2(CH2)4N(CH2)2NH3][B7O10(OH)3]. J Clust Sci. 2013;24:811–20.

    Article  CAS  Google Scholar 

  26. Yang CQ, He Q. Applications of micro scale combustion calorimetry to the studies of cotton and nylon fabrics treated with organophosphorus flame retardants. J Anal Appl Pyrol. 2011;91:125–33.

    Article  CAS  Google Scholar 

  27. Wang G, Sun Y, Yang G. Syntheses and crystal structures of two new pentaborates. J Solid State Chem. 2005;178:729–35.

    Article  CAS  Google Scholar 

  28. Balakrishnan H, Hassan A, Isitman NA, Kaynak C. On the use of magnesium hydroxide towards halogen-free flame-retarded polyamide-6/polypropylene blends. Polym Degrad Stab. 2012;97:1447–57.

    Article  CAS  Google Scholar 

  29. Jimenez M, Duquesne S, Bourbigot S. Characterization of the performance of an intumescent fire protective coating. Surf Coat Tech. 2006;201:979–87.

    Article  CAS  Google Scholar 

  30. Balasi CD, Branca C, Galgano A. Flame retarding of wood by impregnation with boric acid-pyrolysis products and char oxidation rates. Polym Degrad Stab. 2007;92:752–64.

    Article  Google Scholar 

  31. Gaan S, Sun G. Effect of nitrogen additives on thermal decomposition of cotton. J Anal Appl Pyrol. 2009;84:108–15.

    Article  CAS  Google Scholar 

  32. Gao M, Sun C, Zhu K. Thermal degradation of wood treated with guanidine compounds in air. J Therm Anal Calorim. 2004;75:221–32.

    Article  CAS  Google Scholar 

  33. Wahyudiono, Kanetake T, Sasaki M, Goto M. Decomposition of a lignin model compound under hydrothermal conditions. Chem Eng Technol. 2007;30:1113–22.

    Article  CAS  Google Scholar 

  34. Gaan S, Sun G, Hutches K, Engelhard MH. Effect of nitrogen additives on flame retardant action of tributyl phosphate: phosphorus–nitrogen synergism. Polym Degrad Stab. 2008;93:99–108.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mehmet Dogan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dogan, M. Thermal stability and flame retardancy of guanidinium and imidazolium borate finished cotton fabrics. J Therm Anal Calorim 118, 93–98 (2014). https://doi.org/10.1007/s10973-014-3950-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-014-3950-9

Keywords

Navigation