Abstract
A number of samples of sodium and silver phosphate glasses doped with various compositions of some transition metals viz. iron, manganese and zinc chlorides alongwith undoped samples of sodium and silver phosphate glasses were synthesized and characterized by X-ray diffraction, IR spectral, electrical conductivity and differential scanning calorimetry (DSC). The glass transition temperature (T g) and crystallization temperature (T c) values obtained from DSC curves were found to increase with increasing concentration of the dopant Fe/Mn/Zn chlorides in both sodium and silver phosphate glasses and the following sequence is observed:
T g(–FeCl3)>T g(–MnCl2)>T g(–ZnCl2)
T c(–FeCl3)>T c(–MnCl2)>T c(–ZnCl2)
The increase in T g and T c values indicate enhanced chemical durability of the doped glasses. The electrical conductivity values and the results of FTIR spectral studies have been correlated with the structural changes in the glass matrix by the addition of different transition metal cations as dopants.
Similar content being viewed by others
References
RK Brow (2000) J. Non-Cryst. Solids 263 1 Occurrence Handle10.1016/S0022-3093(99)00620-1
MD Ingram (1997) Curr. Opin. Solid State Mater. Sci. 2 399 Occurrence Handle10.1016/S1359-0286(97)80079-4 Occurrence Handle1:CAS:528:DyaK2sXmtFGqtL8%3D
H Yung PY Shih HS Liu TS Chin (1997) J. Am. Ceram. Soc. 80 2213 Occurrence Handle10.1111/j.1151-2916.1997.tb03110.x Occurrence Handle1:CAS:528:DyaK2sXmt1eru7w%3D
RK Brow (1993) J. Am. Ceram. Soc. 76 913 Occurrence Handle10.1111/j.1151-2916.1993.tb05315.x Occurrence Handle1:CAS:528:DyaK3sXls1Gqu7c%3D
GR Moridi CA Horgarth (1978) Int. J. Electron 44 297 Occurrence Handle10.1080/00207217808900820 Occurrence Handle1:CAS:528:DyaE1cXltl2htbs%3D
SS Das BP Baranwal CP Gupta P Singh (2003) J. Power Sources 114 346 Occurrence Handle10.1016/S0378-7753(02)00604-3 Occurrence Handle1:CAS:528:DC%2BD3sXhtlKjtrc%3D
LE Bausa F Jaque JG Sole A Duran (1998) J. Mater. Sci. 23 1921 Occurrence Handle10.1007/BF01115751
M Jamnicky P Znasik D Tunega MD Ingram (1995) J. Non-Cryst. Solids 185 151 Occurrence Handle10.1016/0022-3093(94)00642-3 Occurrence Handle1:CAS:528:DyaK2MXmsVSmtrY%3D
U Selveraj KJ Rao (1985) J. Non-Cryst. Solids 72 315 Occurrence Handle10.1016/0022-3093(85)90187-5
SH Kim T Yoko (1995) J. Am. Ceram. Soc. 78 1061 Occurrence Handle10.1111/j.1151-2916.1995.tb08437.x Occurrence Handle1:CAS:528:DyaK2MXltVOmu7c%3D
C Hunter MD Ingram (1986) Phys. Chem. Glasses 27 51 Occurrence Handle1:CAS:528:DyaL28XitFWltb4%3D
X Yu DE Day GJ Long RK Brow (1997) J. Non-Cryst. Solids 215 21 Occurrence Handle10.1016/S0022-3093(97)00022-7 Occurrence Handle1:CAS:528:DyaK2sXktVaisLk%3D
L Murawski RJ Barczynski D Samatowicz (2003) J. Solid State Ionics 157 293 Occurrence Handle10.1016/S0167-2738(02)00224-2 Occurrence Handle1:CAS:528:DC%2BD3sXhsVSqt7g%3D
AA Kutub AS Shawoosh (1997) J. Mater. Sci. 32 5491 Occurrence Handle10.1023/A:1018655920217 Occurrence Handle1:CAS:528:DyaK2sXnt1aktLo%3D
PY Shih SW Yung TS Shin (1998) J. Non-Cryst. Solids 224 143 Occurrence Handle10.1016/S0022-3093(97)00460-2 Occurrence Handle1:CAS:528:DyaK1cXhvVGlurY%3D
SS Das BP Barnwal CP Gupta P Singh (2005) Indian J. Eng. Mater. Sci. 12 58 Occurrence Handle1:CAS:528:DC%2BD2MXmtVShs74%3D
SS Das P Singh (2004) J. Therm. Anal. Cal. 78 731 Occurrence Handle1:CAS:528:DC%2BD2cXhtVGmt7nL
DV Bavbande R Misra JM Juneja (2004) J. Therm. Anal. Cal. 78 775 Occurrence Handle1:CAS:528:DC%2BD2cXhtVGmt7nN
Zs Éhen F Giordano L Jicsinszky J Sztatisz Cs Novák (2005) J .Therm. Anal. Cal. 80 419 Occurrence Handle10.1007/s10973-005-0670-1
SS Das BP Barnwal SA Rayeeny CP Gupta (2001) Phys. Chem. Glasses 42 74 Occurrence Handle1:CAS:528:DC%2BD3MXntlSnsrw%3D
A Mogus-Milankovic B Santic DE Day CS Ray (2001) J. Non-Cryst. Solids 283 119 Occurrence Handle10.1016/S0022-3093(01)00355-6 Occurrence Handle1:CAS:528:DC%2BD3MXjtFelsrw%3D
K Meyer (1997) J. Non-Cryst. Solids 209 227 Occurrence Handle10.1016/S0022-3093(96)00563-7 Occurrence Handle1:CAS:528:DyaK2sXns1Wruw%3D%3D
YM Moustafa K El- Egili (1998) J. Non-Cryst. Solids 240 144 Occurrence Handle10.1016/S0022-3093(98)00711-X Occurrence Handle1:CAS:528:DyaK1cXmsVWqtrs%3D
SW Martin (1991) Eur. J. Solid State Inorg. Chem. 28 163 Occurrence Handle1:CAS:528:DyaK3MXht1Ont7c%3D
DL Sidebottom (2000) Phys. Rev. B 61 14507 Occurrence Handle10.1103/PhysRevB.61.14507 Occurrence Handle1:CAS:528:DC%2BD3cXjslWgsbg%3D
R Gresch W Muller-Warmuth H Dutz (1979) J. Non-Cryst. Solids 34 127 Occurrence Handle10.1016/0022-3093(79)90012-7 Occurrence Handle1:CAS:528:DyaE1MXmtVWktbo%3D
PY Shih SW Yung TS Chin (1999) J. Non-Cryst. Solids 244 211 Occurrence Handle10.1016/S0022-3093(99)00011-3 Occurrence Handle1:CAS:528:DyaK1MXhs1arsr4%3D
SA Agnihotry SS Das P Singh (2005) J. Non-Cryst. Solids 351 3730 Occurrence Handle10.1016/j.jnoncrysol.2005.09.034
PY Shih (2004) Mater. Chem. Phys. 84 151 Occurrence Handle10.1016/j.matchemphys.2003.11.016 Occurrence Handle1:CAS:528:DC%2BD2cXosFWltg%3D%3D
JD Lee et al. (1999) Concise Inorganic Chemistry (5th Edn) Black Well Science USAC
L Montagne G Palavit R Delaval (1997) J. Non-Cryst. Solids 215 1 Occurrence Handle10.1016/S0022-3093(97)00032-X Occurrence Handle1:CAS:528:DyaK2sXktVaisL8%3D
I Bratu I Ardelean A Barbu V Mih D Maniu G Botezan (1999) J. Mol. Structure 482–483 689 Occurrence Handle10.1016/S0022-2860(98)00940-5
GK Marasinghe M Karabulut CS Ray DE Day MG Shumsky WB Yelon CH Booth PG Allen DK Shuh (1997) J. Non-Cryst. Solids 222 144 Occurrence Handle1:CAS:528:DyaK1cXit1Khtg%3D%3D
B Pivac A Mogus-Milankovic DE Day (1998) J. Non-Cryst. Solids 226 41 Occurrence Handle10.1016/S0022-3093(98)00367-6 Occurrence Handle1:CAS:528:DyaK1cXjs1anu7g%3D
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Das, S.S., Srivastava, V. Sodium and silver phosphate glasses doped with chlorides of Fe, Mn and Zn. J Therm Anal Calorim 87, 365–369 (2007). https://doi.org/10.1007/s10973-006-7738-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-006-7738-4