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Antimicrobial properties of polysiloxane/polyoxometallates

  • Original Paper: Sol-gel and hybrid materials for biological and health (medical) applications
  • Published:
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Abstract

Nanocomposites based on Keggin-type polyoxometalate H5PV2Mo10O40 (POM) and organically modified silicate (Ormosil) were prepared by sol-gel processes. The physical properties of the Ormosil/POM composites were examined using FTIR, UV, SEM, TEM and XRD. These techniques indicated that the POM was bond to the Ormosil matrix after impregnation. The antibacterial effects of Ormosil/POM and the Ormosil+POM were assessed by the zone of inhibition, minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC). A higher POM proportion used in the Ormosil/POM yielded a stronger antimicrobial effect that was superior to Ormosil+POM. The excellent antibacterial performance of Ormosil/POM-10 compositean was discovered. Ormosil/POM composites were therefore believed to have great potential for use as an antibacterial material.

Graphical Abstract

This study used the sol-gel method to produce Ormosil/POM nanocomposites with antimicrobial effects, suitable for antimicrobial textiles.

Highlights

  • The POM was chemically bonded to the carrier to solve the problem of separation.

  • The original structural characteristics of Ormosil and POM remained unaffected.

  • The addition of more POM led to a stronger interaction force with SiO2.

  • A higher POM proportion used in the Ormosil/POM yielded a stronger antimicrobial effect.

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Acknowledgements

The authors thank the National Science Council of the Republic of China for supporting this work (Grant NSC 96-2113-M-606-003-MY3).

Author contributions

W-CH: conceptualization, methodology, writing-original draft and writing. K-FC: review and editing. H-WY: acquisition of data, analysis and interpretation of data. K-HW: review and editing.

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Authors and Affiliations

  1. Department of Chemical and Materials Engineering, Chung Cheng Institute of Technology, National Defense University, Taoyuan, 33551, Taiwan

    Wen-Chien Huang, Ken-Fa Cheng & Kuo-Hui Wu

  2. National Chung Shan Institute of Science and Technology, System Manufacturing Center, Research of the Chemicals and Weapon Section, Shanshia, 23742, Taiwan

    Hsiu-Wen Yang

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Huang, WC., Cheng, KF., Yang, HW. et al. Antimicrobial properties of polysiloxane/polyoxometallates. J Sol-Gel Sci Technol 107, 629–639 (2023). https://doi.org/10.1007/s10971-023-06141-7

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  • DOI: https://doi.org/10.1007/s10971-023-06141-7

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