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Chemical stability of alkali elements’ uranyl vanadates in aqueous solutions

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Abstract

The chemical stability of uranyl vanadates AIVUO6∙nH2O (AI–Li, Na (n = 2), K, Rb, Cs (n = 0)) in aqueous solutions was investigated for the first time. The medium acidity was established to have the largest influence on the state of the studied compounds in heterogeneous aqueous-salt systems. The compounds were found to be stable in the pH range of 0 − 2–11 − 14. Alkaline elements uranyl vanadates’ solubility changes from 10−8 to 10−6 mol/l in neutral solutions to 10−4 to 10−1 mol/l in acidic and basic media. The chemical stability of AIVUO6⋅nH2O increases from lithium to caesium. The solubility products were calculated to be in the range of 10−29.2 (Li) to 10−34.1 (Cs). Gibbs free energies of the formation and dissolution of the studied compounds, their solubility curves and the speciation diagrams for U (VI) and V (V) in both liquid and solid phases were also calculated.

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Acknowledgements

The work was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation, project № 0729-2020-0039.

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Authors and Affiliations

  1. Chemical Department, Lobachevsky State University of Nizhni Novgorod, Gagarin Avenue, 23, Nizhni Novgorod, Russian Federation, 603022

    Oxana V. Nipruk, Nikolay G. Chernorukov, Кseniya A. Klinshova, Maxim O. Bakhmetev, Olga N. Tumaeva & Il’ya D. Udalov

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  1. Oxana V. Nipruk
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  2. Nikolay G. Chernorukov
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  3. Кseniya A. Klinshova
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  4. Maxim O. Bakhmetev
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  5. Olga N. Tumaeva
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  6. Il’ya D. Udalov
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Correspondence to Oxana V. Nipruk.

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Nipruk, O.V., Chernorukov, N.G., Klinshova, К.A. et al. Chemical stability of alkali elements’ uranyl vanadates in aqueous solutions. J Radioanal Nucl Chem 332, 355–367 (2023). https://doi.org/10.1007/s10967-022-08733-z

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  • DOI: https://doi.org/10.1007/s10967-022-08733-z

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