Skip to main content
Log in

Application of the single comparator method to instrumental photon activation analysis

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Instrumental photon activation analysis (IPAA) is nondestructive and multi-elemental analysis method like instrumental neutron activation analysis. We applied the single comparator method to IPAA to determine the elemental mass fractions in various types of reference samples using only an Ni comparator instead of using standard samples for each element. The samples were irradiated by bremsstrahlung with three different maximum energy from electron accelerators at different two Universities. Compared to reference values, most of the determined results were within ± 20%, among which many were within ± 10%. The yield ratio values used in this study can be used for any accelerators.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. Simonits A, De Corte F, Hoste J (1975) Single-comparator methods in reactor neutron activation analysis. J Radioanal Chem 24:31–46

    Article  CAS  Google Scholar 

  2. Kyzero for Windows. http://www.kayzero.com/. Accessed 1 Apr 2022

  3. Rossbach M, Blaauw M, Bacchi MA, Lin X (2007) The k0-IAEA program. J Radioanal Nucl Chem 274:657–662

    Article  CAS  Google Scholar 

  4. Chahidi H, Bounouira H, Amsil H, Choukri A, Embarch K, Didi A, Ilyas A, Laraki K, Marah H (2021) Performance of k0 standardization method in neutron activation analysis using Kayzero for Windows software at the National Center for Energy, Sciences and Nuclear Techniques (CNESTEN-Morocco). J Radioanal Nucl Chem 327:59–64

    Article  CAS  Google Scholar 

  5. Tran TA, Ho MD, Ho VD, Trinh VC, Nguyen DQ, Nguyen TT (2020) Standardization and application of internal monostandard NAA method using the Dalat research reactor. J Radioanal Nucl Chem 325:743–750

    Article  CAS  Google Scholar 

  6. Esen AN, Haciyakupoglu S, Erenturk S (2018) Comparison of relative INAA and k0-INAA using proficiency test materials at ITU TRIGA Mark II research reactor. J Radioanal Nucl Chem 315:677–683

    Article  CAS  Google Scholar 

  7. Baker CA (1967) Gamma-activation analysis. A review. Analyst 92:601. https://doi.org/10.1039/an9679200601

    Article  CAS  Google Scholar 

  8. Lutz GJ (1971) Photon activation analysis: a review. Anal Chem 43:93–103

    Article  CAS  Google Scholar 

  9. Segebade C, Starovoitova VN, Borgwardt T, Wells D (2017) Principle, methodologies, and applications of photon activation analysis: a review. J Radioanal Nucl Chem 312:443–459

    Article  CAS  Google Scholar 

  10. Oura Y, Ohtsuki T, Hirose K, Ebihara M (2008) Linear electron accelerator for radioanalytical studies at Tohoku University. J Radioanal Nucl Chem 278:723–726

    Article  CAS  Google Scholar 

  11. Toh Y, Segawa M, Maeda M, Tsuneyama M, Kimura A, Nakamura S, Endo S, Ebihara M (2021) Non-destructive quantitative analysis of difficult-to-measure radionuclides 107Pd and 99Tc. Anal Chem. https://doi.org/10.1021/acs.analchem.1c01233

    Article  PubMed  Google Scholar 

  12. Eke C, Boztosun I, Segebade C (2019) Photon activation analysis of sand samples from Antalya in Turkey with a clinical electron linear accelerator. Radiochim Acta 107:149–156

    Article  CAS  Google Scholar 

  13. Mirani F, Calzolari D, Formenti A, Passoni M (2021) Superintense laser-driven photon activation analysis. Comminications Phys. https://doi.org/10.1038/s42005-021-00685-2

    Article  Google Scholar 

  14. Live Chart of Nuclides, International Atomic Energy Agency Nuclear Data Services https://www-nds.iaea.org/relnsd/vcharthtml/VChartHTML.html Accessed 1 Apr 2022

  15. Segebade C (1983) Photon Activation Analysis. de Gryter

  16. Oura Y, Terasaki H, Yamaguchi Y, Hara T, Kaneko J, Kuroiwa N, Endo I, Miura Y (2017) Radiochemical measurement of photonuclear reaction yields for photon activation analysis. ELPH Annual Report 2017, Tohoku Univ. 111–116 (in Japanese)

  17. Imai N, Terashima S, Itoh S, Ando A (1995) 1994 Compilation of analytical data for minor and trace elements in seventeen GSJ geochemical reference samples, “Igneous rock series.” Geostandards Newslett 19:135–213

    Article  CAS  Google Scholar 

  18. Terashima S, Imai N, Tominaga M, Hirata S, Taniguchi M (2000) Preparation of new GSJ geochemical reference material: JSO-2 soil. Bunseki Kagaku 49:319–324 (in Japanese)

    Article  CAS  Google Scholar 

  19. Okai T, Terashima S, Imai N (2002) Collaborative analysis of GSJ geochemical reference materials JCu-1 (Copper ore) and JZn-1 (Zinc ore). Bunseki Kagaku 51:973–977 (in Japanese)

    Article  CAS  Google Scholar 

  20. Okamoto K (1987), Kikan Kannkyoukennkyu, 66:124–133 (in Japanese)

  21. Ebihara M, Oura Y, Ishii T, Setoguchi M, Nakahara H, Ohtsuki T (2000) How effectively is thew photon activation analysis applied to meteorite samples? J Radioanal Nucl Chem 244:491–496

    Article  CAS  Google Scholar 

  22. Miyamoto Y (1999), PhD theiss, Kanazawa Univeresity (in Japanese)

  23. Geochemical Survey of Japan, GSJ Geochemical Reference Samples of Data Base, http://www.aist.go.jp/RIODB/geostand/welcome.html

  24. National Institute of Standards and Technology (2011), Certificate of Analysis for Standard Reference Material 1632c, Bituminous

  25. National Institute of Standards and Technology (1998), Certificate of Analysis for Standard Reference Material 1648, Urban Particulate Matter

  26. National Institute for Environmental Studies (1987), Certified Reference Material No.8, Vehicle Exhaust Particulates

  27. Togashi S, Kamioka H, Tanaka T, Ando A (1990) Re-evaluation of Cr concentration in some geostandard rocks by INAA. J Min Pder Econ Geol 85:91–97 (in Japanese)

  28. Robouch P, Arana G, Eguskiza M, Pommé S, Etxebarria N (2000) Uncertainty Budget for k0-NAA. J Radioanal Nucl Chem 245(1):195–197

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors thank Drs. K. Tsukada and H. Kikunaga, as well as the LINAC crew members of the Research Center for Electron Photon Science, Tohoku University, for invaluable while conducting the experiments. This study was carried out partially under auspices of the visiting Researcher’s Program of the Institute for Integrated Radiation and Nuclear Science, Kyoto University.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yasuji Oura.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Reza, M.S., Taniguchi, R., Kaneko, J. et al. Application of the single comparator method to instrumental photon activation analysis. J Radioanal Nucl Chem 331, 2609–2619 (2022). https://doi.org/10.1007/s10967-022-08309-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-022-08309-x

Keywords

Navigation