Skip to main content
Log in

A comparison of INAA and ICP-MS/ICP-AES methods for the analysis of meteorite samples

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Instrumental neutron activation analysis (INAA), inductively coupled plasma atomic emission spectrometry (ICP-AES) and ICP mass spectrometry (ICP-MS) (hereafter, ICPs) were applied to meteorite samples for the determination of elemental content. The analytical applicability and suitability of the three methods have been compared. Those comparisons led to the refinement of our analytical procedures for INAA and ICPs, yielding more reliable data. Our INAA data proved to be reliable enough for classifying meteorites, while the ICPs, especially ICP-MS, can characterize elemental abundance features in detail, as demonstrated by REE abundance patterns for the Allende meteorite. In this manner, INAA and ICPs can be used in a complementary fashion in cosmochemical studies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Jarosewich E, Clarke RS Jr, Barrows JN (1987) The Allende meteorite reference sample. Smithson Contrib Earth Sci 27:1–49

    Article  Google Scholar 

  2. Bennett J, Grave P, Stopic A (2012) Establishing a basis for nuclear archaeometry in Australia using the 20 MW OPAL research reactor. J Radioanal Nucl Chem 291:13–17

    Article  CAS  Google Scholar 

  3. Aso K, Ebihara M (2013) Precise determination of trace amounts of phosphorus in geological samples by inductively coupled plasma atomic emission spectrometry with ion-exchange separation. Anal Chim Acta 779:8–13

    Article  Google Scholar 

  4. Shirai N, Toktaganov M, Takahashi H, Yokotsuka Y, Sekimoto S, Ebihara M (2015) Multielemental analysis of Korean geological reference samples by INAA, ICP-AES and ICP-MS. J Radioanal Nucl Chem 303:1367–1374

    Article  CAS  Google Scholar 

  5. Vu CD, Sucgang R, Tran T, Ho D, Shirai N, Ebihara M (2017) Measurements of REE and other elements mass fractions in environmental reference materials (NIST SRM 1646a, NIST SRM 1400, IAEA-359 and IAEA-450) by INAA, ICP-AES and ICP-MS. Geostand Geoanal Res 41:303–315

    Article  Google Scholar 

  6. Ebihara M, Ozaki H, Kato F, Nakahara H (1997) Determination of chlorine, bromine and iodine in rock samples by radiochemical neutron activation analysis. J Radioanal Nucl Chem 216:107–112

    Article  CAS  Google Scholar 

  7. Ozaki H, Ebihara M (2007) Determination of trace halogens in rock samples by radiochemical neutron activation analysis coupled with ko-standardization method. Anal Chim Acta 583:384–391

    Article  CAS  Google Scholar 

  8. Nakamoto T, Oura Y, Ebihara M (2007) Comparative study of activation analyses for the determination of trace halogens in geological and cosmochemical samples. Anal Sci 23:1113–1119

    Article  CAS  Google Scholar 

  9. Kallemeyn GW, Wasson JT (1981) The compositional classification of chondrites—I. The carbonaceous chondrite groups. Geochim Cosmochim Acta 45:1217–1230

    Article  CAS  Google Scholar 

  10. Kallemeyn GW, Rubin AE, Wang D, Wasson JT (1989) Ordinary chondrites: bulk compositions, classification, lithophile-element fractionations and composition-petrographic type relationships. Geochim Cosmochim Acta 53:2747–2767

    Article  CAS  Google Scholar 

  11. Barrat JA, Zanda B, Moynier F, Bollinger C, Liorzou C, Bayon G (2012) Geochemistry of CI chondrites: major and trace elements, and Cu and Zn Isotopes. Geochim Cosmochim Acta 83:79–92

    Article  CAS  Google Scholar 

  12. Anders W, Grevesse N (1989) Abundances of the elements: meteoritic and solar. Geochim Cosmochim Acta 53:197–214

    Article  CAS  Google Scholar 

  13. Shinotsuka K, Hidaka H, Ebihara M (1995) Detailed abundances of rare earth elements, Th and U in chondritic meteorites: an ICS-MS study. Meteoritics 30:694–699

    Article  CAS  Google Scholar 

  14. Shinotsuka K, Ebihara M (1997) Precise determination of rare earths, thorium and uranium in chondritic meteorites by ICP-MS—a comparative study with RNAA. Anal Chim Acta 338:237–246

    Article  CAS  Google Scholar 

  15. Khan R, Shirai N, Ebihara M (2015) Chemical characteristic of R chondrites in the light of P, REEs, Th and U abundances. Earth Planet Sci Lett 422:18–27

    Article  CAS  Google Scholar 

  16. Shirai N, Okamoto C, Yamaguchi A, Ebihara M (2016) Siderophile elements in brecciated HED meteorites and the nature of projectile materials in HED meteorites. Earth Planet Sci Lett 437:57–65

    Article  CAS  Google Scholar 

  17. Clarke RS Jr, Jarosewich E, Mason B, Nelen J, Gomez M, Hyde JR (1971) The Allende, Mexico, meteorite shower. Smithson Contrib Earth Sci 5:1–53

    Google Scholar 

  18. Akhter R, Shirai N, Ebihara M (2016) Chemical characterization of a chromitite reference sample GPt-5 using INAA and ICP-MS. Geochem J 50:179–185

    Article  CAS  Google Scholar 

  19. Ebihara M, Sekimoto S, Shirai N, Hamajima Y, Yamamoto M, Kumagai K, Oura Y, Ireland TR, Kitajima F, Nagao K, Nakamura T, Naraoka H, Noguchi T, Okazaki R, Tsuchiyama A, Uesugi M, Yurimoto H, Zorensky ME, Abe M, Fujimura A, Mukai T, Yada Y (2011) Neutron activation analysis of a particle returned from asteroid Itokawa. Science 333:1119–1121

    Article  CAS  Google Scholar 

  20. Ebihara M, Shirai N, Sekimoto S, Nakamura T, Tsuchiyama A, Matsuno J, Matsumoto T, Tanaka M, Abe M, Fujimura A, Ishibashi Y, Karouji Y, Mukai T, Okada T, Uesugi M, Yada T (2015) Chemical and mineralogical compositions of two grains recovered from an asteroid Itokawa. Meteor Planet Sci 50:243–254

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The Antarctic meteorites used in this study were loaned by the National Institute of Polar Research, Japan, to which our thanks go. This work was financially supported in part by a grant-in-aid defrayed by the Japanese Ministry of Education, Culture, Sports, Science and Technology, MEXT (#25246038 to ME).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mitsuru Ebihara.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ebihara, M., Shirai, N., Bennett, J.W. et al. A comparison of INAA and ICP-MS/ICP-AES methods for the analysis of meteorite samples. J Radioanal Nucl Chem 318, 1681–1687 (2018). https://doi.org/10.1007/s10967-018-6309-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-018-6309-z

Keywords

Navigation