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Spectroscopic study of complexes from UO2(II), Th(IV) and Sm(III) based on the effects of the characteristic TBP, TOPO and D2EHPA bands in various organic solvents

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Abstract

In this work, we have studied the solvent effect on the of bonds deployment after liquid–liquid extraction of UO22+, Sm3+ and Th4+ by tributylphosphate (TBP), tri-n-octylphosphine oxide (TOPO) and di-(2-ethylhexyl) phosphoric acid (D2EHPA). The Infrared study of TBP, TOPO and D2EHPA and its related metal complexes in solvents (hexane, kerosene, chloroform, dichloromethane, cyclohexene and benzene) was examined. After this study, depending to the metal, extractant and diluents, we notice several changes. Stoichiometry of extracted complex in the organic phase was determined by the Job’s method. The complexes extracted were of types MEx, M3Ex7 et M7Ex3.

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Acknowledgements

We gratefully acknowledge the ATRST-Algeria for their financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Dr. Moulay Tahar University, BP 138, Saida, Algeria

    Baghdad Medjahed

  2. Laboratory of Separation and Purification Technology, Department of Chemistry, Faculty of Sciences, Tlemcen University, P.O. Box 119, Tlemcen, Algeria

    Baghdad Medjahed & Mohamed A. Didi

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  1. Baghdad Medjahed
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  2. Mohamed A. Didi
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Correspondence to Baghdad Medjahed or Mohamed A. Didi.

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Medjahed, B., Didi, M.A. Spectroscopic study of complexes from UO2(II), Th(IV) and Sm(III) based on the effects of the characteristic TBP, TOPO and D2EHPA bands in various organic solvents. J Radioanal Nucl Chem 318, 1427–1438 (2018). https://doi.org/10.1007/s10967-018-6220-7

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