Abstract
This work includes the applications of radiation processing to decompose dimethyl phthalate (DMP) with gamma and gamma/H2O2 processes. Changes in amounts of DMP, dissolved oxygen, total acidity and formaldehyde with irradiation dose were followed. The qualitative analysis of the DMP and the intermediates were determined by using a gas chromatography combined to mass spectrometry and ion chromatography. The results indicated that degradation rate of DMP was affected by H2O2 concentration, irradiation dose and removal efficiency of 25 mg L−1 DMP can reach 100% for 1.42 kGy irradiation dose in the concentration of 4.8 mM H2O2, respectively.
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Olujimi O, Fatoki OJ, Okonkow J (2010) Endocrine disrupting chemicals (phenol and phthalates) in the south African environment: a need for more monitoring. J Water SA 36:671–682
Teilmann G, Juul A, Skakkebaek NE, Toppari J (2002) Putative effects of endocrine disrupters on pubertal development in the human. Best Pract Res Clin Endocrinol Metabol 16:105–112
Colborn T, vomSaal FS, Soto AM (1993) Developmental effects of endocrine-disrupting chemicals in wildlife and humans. J Environ Health Persp 101:378–384
Barcelo D, Kettrup A (2004) Endocrine disruptors. J Anal Bioanal Chem 378:547–548
AdeniyiaM Dayomi M, Siebep O, Okedeyi O (2008) An assessment of the levels of phthalate esters and metals in the muledane open dump, Thohoyandou, Limpopo Province. Chem Cent J 2:2–9
Burger AE, Moolman AP (2006) First phase of an endocrine research programme for South African water systems. J Water Pract Technol 1:1–8
Ge J, Li LinM, ZhaoF DaiX (2011) Comparative studies on toxicokinetics and residues of dimethyl phthalate (DMP) in tilapia at different water temperatures. Turk J Fish Aquat Sci 11:253–259
Tç Hancı, İmren C, Alaton A, Kabadaşlı I, Tünay O (2009) H2O2/UV-C oxidation of potential endocrine disrupting compounds: a case study with dimethyl phthalate. J Photochem Photobiol Sci 5:620–627
Mossini E, Macerata E, Giola E, Brambilla L, Castiglioni C, Mariani M (2015) Physico chemical properties of irradiated i-SANEX diluents. J Nukl 60:893–898
Getoff N (2002) Factors influencing the efficiency of radiation-induced degradation of water pollutants. J Radiat Phys Chem 65:437–446
CaiY Jiang G, Liu J (2003) Solid-phase extraction of several phthalate esters from environmental water samples on column packed with polytetrafluoroethylene turning. J Anal Sci 19:1491–1494
Şolpan D, Torun M, Güven O (2007) Effect of gamma-irradiation on aqueous solutions of Apollofix dyes. J Nukl 52:109–113
Şolpan D, Torun M (2012) The removal of chlorinated organic herbicide in water by gama irradiation. J Radioanal Nucl Chem 293:21–38
Hansch C, Hoekman LA (1995) Exploring QSAR—hydrophobic, electronic, and steric constants. J Am Chem Soc 6:354–360
Baltussen E, David F, SandraP Janssen H, Cramers C (1999) Automotive sorptive extraction thermal desorption-gas chromatography mass spectrometry analysis: determination of phenols in water samples. J Microcolumn Sep 11:471–474
Yoshida T, Tanabe T, Chen A (2003) Method for the degradation of dibutylphthalate in water by gamma-ray irradiation. J Radioanal Nucl Chem 255:265–267
Chiron S, Fernandez-Alba A, Rodriguez A, Garcia-Calvo E (2000) Pesticide chemical oxidation: state-of-the-art. J Water Res 34:366–377
Nash T (1973) The colorometric estimation of formaldehyde by means of the Hantzsch method. J Biochem 55:416–421
Manilal VB, Haridas A, Alexander R (1992) Photocatalytic treatment of toxic organics in wastewater: toxicity of photodegradation products. J Water Res 26(8):1035–1038
Getoff N (1997) Peroxyl radicals in the treatment of waste solutions, peroxyl radicals. J Chichester 8:483–506
Sedlak DL, Andren AW (1991) Aqueous-phase oxidation of polychlorinated biphenyls by hydroxyl radicals. J Environ Sci Technol 25:1419–1427
An T, Gao Y, Li G, Kamat P, Peller J, Joyce M (2014) Kinetics and mechanism of OH mediated degradation of dimethyl phthalate in aqueous solution: experimental and theoretical studies. J Environ Sci Technol 48:641–648
Zhao H, Yi C, Yi R, Wang H, Yin L, Muhammad I, Zhongfei MA (2018) Research on the degradation mechanism of dimethyl phthalate in drinking water by strong ionization discharge. J Plasma Sci Technol 20:3–4
Liu Q, Chen C, Chen HZ, Yang SG, He H, Sun C (2013) Degradation mechanisms of dimethyl phthalate in the UV–H2O2 system. J Huan Jing Ke Xue 34:2670–2676
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Şolpan, D., Mehrnia, M. Dimethyl phthalate (DMP) degradation in aqueous solution by gamma-irradiation/H2O2. J Radioanal Nucl Chem 317, 841–851 (2018). https://doi.org/10.1007/s10967-018-5944-8
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DOI: https://doi.org/10.1007/s10967-018-5944-8