Abstract
A novel macroporous silica-based HDEHP-CMPO impregnated polymeric solid-phase extractant showed an excellent uranium adsorption efficiency from HNO3, HCl, and H2SO4 media with the wide concentration range from the near neutral to high acidic conditions. The adsorption equilibrium data were well described with the Redlich–Peterson isotherm with the relatively high uranium adsorption capacity. Furthermore, the HDEHP-CMPO/SiO2-P showed a significant selectivity for U(VI) among the coexisting elements while the co-extraction of Fe(III) with U(VI) was observed. In desorption process, Fe(III) and U(VI) were separated and desorbed efficiently using the 1 M H2SO4 solution at 55 °C and 1 M NH4HCO3 solution at 25 °C, respectively.
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Zhang JY, Zhang N, Zhang L, Fang Y, Deng W, Yu M, Wang Z, Li L, Liu X, Li J (2015) Adsorption of uranyl ions on amine-functionalization of MIL-101(Cr) nanoparticles by a facile coordination-based post-synthetic strategy and x-ray absorption spectroscopy studies. Sci Rep 5:13514. https://doi.org/10.1038/srep13514
Wang F, Li H, Liu Q, Li Z, Li R, Zhang H, Liu L, Emelchenko GA, Wang J (2016) A graphene oxide/amidoxime hydrogel for enhanced uranium capture. Sci Rep 6:19367. https://doi.org/10.1038/srep19367
Guo Y, Ren T (2017) When it is unfamiliar to me: local acceptance of planned nuclear power plants in China in the post-fukushima era. Energy Policy 100:113–125. https://doi.org/10.1016/j.enpol.2016.10.002
Wu Y (2017) Public acceptance of constructing coastal/inland nuclear power plants in post-Fukushima China. Energy Policy 101:484–491. https://doi.org/10.1016/j.enpol.2016.11.008
Bai Z-Q, Yuan L-Y, Zhu L, Liu Z-R, Chu S-Q, Zheng L-R, Zhang J, Chai Z-F, Shi W-Q (2015) Introduction of amino groups into acid-resistant MOFs for enhanced U(vi) sorption. J Mater Chem A 3(2):525–534. https://doi.org/10.1039/C4TA04878D
Siva Kesava Raju C, Subramanian MS (2007) Sequential separation of lanthanides, thorium and uranium using novel solid phase extraction method from high acidic nuclear wastes. J Hazard Mater 145(1–2):315–322. https://doi.org/10.1016/j.jhazmat.2006.11.024
Han R, Zou W, Wang Y, Zhu L (2007) Removal of uranium (VI) from aqueous solutions by manganese oxide coated zeolite: discussion of adsorption isotherms and pH effect. J Environ Radioact 93(3):127–143. https://doi.org/10.1016/j.jenvrad.2006.12.003
Prabhakaran D, Subramanian MS (2004) Selective extraction of U(VI), Th(IV), and La(III) from acidic matrix solutions and environmental samples using chemically modified Amberlite XAD-16 resin. Anal Bioanal Chem 379(3):519–525. https://doi.org/10.1007/s00216-004-2600-7
Mondal S, Singh D, Anitha M, Sharma J, Hubli R, Singh H (2014) New synergistic solvent mixture of DNPPA and bidentate octyl (phenyl) CMPO for enhanced extraction of uranium (VI) from phosphoric acid medium. Hydrometallurgy 147:95–102
Hadadian M, Mallah MH, Moosavian MA, Safdari J, Davoudi M (2016) Separation of uranium (VI) using dispersive liquid-liquid extraction from leach liquor. Prog Nucl Energy 90:212–218. https://doi.org/10.1016/j.pnucene.2016.03.024
Quinn JE, Wilkins D, Soldenhoff KH (2013) Solvent extraction of uranium from saline leach liquors using DEHPA/Alamine 336 mixed reagent. Hydrometallurgy 134–135:74–79. https://doi.org/10.1016/j.hydromet.2013.01.014
Zhu Z, Pranolo Y, Cheng CY (2016) Uranium recovery from strong acidic solutions by solvent extraction with Cyanex 923 and a modifier. Miner Eng 89:77–83. https://doi.org/10.1016/j.mineng.2016.01.016
Amaral JCBS, Morais CA (2010) Thorium and uranium extraction from rare earth elements in monazite sulfuric acid liquor through solvent extraction. Miner Eng 23(6):498–503. https://doi.org/10.1016/j.mineng.2010.01.003
Fouad HK, Bishay AF (2010) Uranium uptake from acidic solutions using synthetic titanium and magnesium based adsorbents. J Radioanal Nucl Chem 283(3):765–772. https://doi.org/10.1007/s10967-009-0435-6
Ansari SA, Mohapatra PK (2017) A review on solid phase extraction of actinides and lanthanides with amide based extractants. J Chromatogr A 1499:1–20. https://doi.org/10.1016/j.chroma.2017.03.035
Kim JS, Han KS, Kim SJ, Kim S-D, Lee J-Y, Han C, Rajesh Kumar J (2016) Synergistic extraction of uranium from Korean black shale ore leach liquors using amine with phosphorous based extractant systems. J Radioanal Nucl Chem 307(2):843–854. https://doi.org/10.1007/s10967-015-4327-7
Singh H, Vijayalakshmi R, Mishra S, Gupta C (2001) Studies on uranium extraction from phosphoric acid using di-nonyl phenyl phosphoric acid-based synergistic mixtures. Hydrometallurgy 59(1):69–76
Singh H, Mishra SL, Vijayalakshmi R (2004) Uranium recovery from phosphoric acid by solvent extraction using a synergistic mixture of di-nonyl phenyl phosphoric acid and tri-n-butyl phosphate. Hydrometallurgy 73(1–2):63–70. https://doi.org/10.1016/j.hydromet.2003.08.006
Biswas S, Pathak PN, Singh DK, Roy SB, Manchanda VK (2012) Evaluation of dinonyl phenyl phosphoric acid (DNPPA) and its synergistic mixtures with neutral oxodonors for extraction and recovery of uranium from nitric acid medium. Int J Miner Process 104–105:17–23. https://doi.org/10.1016/j.minpro.2011.11.011
Meera R, Luxmi Varma R, Reddy MLP (2004) Enhanced extraction of thorium(IV) and uranium(VI) with 1-phenyl-3-methyl-4-pivaloyl-5-pyrazolone in the presence of various neutral organophosphorus extractants. Radiochim Acta. https://doi.org/10.1524/ract.92.1.17.25402
Sato T (1964) The synergic effect of tri-n-butyl phosphate in the extraction of uranium (VI) from sulphuric acid solutions by di-(2-ethylhexyl)-phosphoric acid. J Inorg Nucl Chem 26(2):311–319. https://doi.org/10.1016/0022-1902(64)80075-0
Sato T (1965) The extraction of uranium (VI) from hydrochloric acid solutions by DI-(2-ethylhexyl)-phosphoric acid. J Inorg Nucl Chem 27(8):1853–1860. https://doi.org/10.1016/0022-1902(65)80329-3
Yusan SD, Akyil S (2008) Sorption of uranium(VI) from aqueous solutions by akaganeite. J Hazard Mater 160(2–3):388–395. https://doi.org/10.1016/j.jhazmat.2008.03.009
Zhang X, Ji L, Wang J, Li R, Liu Q, Zhang M, Liu L (2012) Removal of uranium(VI) from aqueous solutions by magnetic Mg–Al layered double hydroxide intercalated with citrate: kinetic and thermodynamic investigation. Colloids Surf A 414:220–227. https://doi.org/10.1016/j.colsurfa.2012.08.031
Michard P, Guibal E, Vincent T, Le Cloirec P (1996) Sorption and desorption of uranyl ions by silica gel: pH, particle size and porosity effects. Microporous Mater 5(5):309–324. https://doi.org/10.1016/0927-6513(95)00067-4
Belgacem A, Rebiai R, Hadoun H, Khemaissia S, Belmedani M (2014) The removal of uranium (VI) from aqueous solutions onto activated carbon developed from grinded used tire. Environ Sci Pollut Res 21(1):684–694. https://doi.org/10.1007/s11356-013-1940-2
Mellah A, Chegrouche S, Barkat M (2006) The removal of uranium(VI) from aqueous solutions onto activated carbon: kinetic and thermodynamic investigations. J Colloid Interface Sci 296(2):434–441. https://doi.org/10.1016/j.jcis.2005.09.045
Wang G, Liu J, Wang X, Xie Z, Deng N (2009) Adsorption of uranium (VI) from aqueous solution onto cross-linked chitosan. J Hazard Mater 168(2):1053–1058
Abdi S, Nasiri M, Mesbahi A, Khani MH (2017) Investigation of uranium (VI) adsorption by polypyrrole. J Hazard Mater 332:132–139. https://doi.org/10.1016/j.jhazmat.2017.01.013
Tabushi I, Kobuke Y, Nishiya T (1979) Extraction of uranium from seawater by polymer-bound macrocyclic hexaketone. Nature 280(5724):665–666
Meng H, Gao Q, Li Z, Wang X, Ma F, Zhou W, Zhang L (2015) Synthesis of a highly dense and selective imprinted polymer via pre-irradiated surface-initiated graft polymerization. J Mater Chem A 3(25):13237–13243. https://doi.org/10.1039/C5TA02279G
Kilincarslan A, Akyil S (2005) Uranium adsorption characteristic and thermodynamic behavior of clinoptilolite zeolite. J Radioanal Nucl Chem 264(3):541–548. https://doi.org/10.1007/s10967-005-0750-5
Han R, Zou W, Wang Y, Zhu L (2007) Removal of uranium (VI) from aqueous solutions by manganese oxide coated zeolite: discussion of adsorption isotherms and pH effect. J Environ Radioact 93(3):127–143
Awwad NS, Daifullah AAM (2005) Preconcentration of U(VI) from aqueous solutions after sorption using Sorel’s cement in dynamic mode. J Radioanal Nucl Chem 264(3):623–628. https://doi.org/10.1007/s10967-005-0762-1
Parab H, Joshi S, Shenoy N, Verma R, Lali A, Sudersanan M (2005) Uranium removal from aqueous solution by coir pith: equilibrium and kinetic studies. Bioresour Technol 96(11):1241–1248. https://doi.org/10.1016/j.biortech.2004.10.016
Swarnalatha K, Ayoob S (2016) Adsorption studies on coir pith for heavy metal removal. Int J Sustain Eng 9(4):259–265. https://doi.org/10.1080/19397038.2016.1152323
Psareva TS, Zakutevskyy OI, Chubar NI, Strelko VV, Shaposhnikova TO, Carvalho JR, Correia MJN (2005) Uranium sorption on cork biomass. Colloids Surf A 252(2–3):231–236. https://doi.org/10.1016/j.colsurfa.2004.10.115
Missana T, García-Gutiérrez M, Maffiotte C (2003) Experimental and modeling study of the uranium (VI) sorption on goethite. J Colloid Interface Sci 260(2):291–301. https://doi.org/10.1016/S0021-9797(02)00246-1
El-Maghrabi HH, Abdelmaged SM, Nada AA, Zahran F, El-Wahab SA, Yahea D, Hussein GM, Atrees MS (2017) Magnetic graphene based nanocomposite for uranium scavenging. J Hazard Mater 322:370–379. https://doi.org/10.1016/j.jhazmat.2016.10.007
Zhou L, Bosscher M, Zhang C, Özçubukçu S, Zhang L, Zhang W, Li CJ, Liu J, Jensen MP, Lai L, He C (2014) A protein engineered to bind uranyl selectively and with femtomolar affinity. Nat Chem 6(3):236–241. https://doi.org/10.1038/nchem.1856, http://www.nature.com/nchem/journal/v6/n3/abs/nchem.1856.html#supplementary-information
Sprynskyy M, Kowalkowski T, Tutu H, Cukrowska EM, Buszewski B (2011) Adsorption performance of talc for uranium removal from aqueous solution. Chem Eng J 171(3):1185–1193. https://doi.org/10.1016/j.cej.2011.05.022
Li F, Gao Z, Li X, Fang L (2014) The effect of Paecilomyces catenlannulatus on removal of U(VI) by illite. J Environ Radioact 137:31–36. https://doi.org/10.1016/j.jenvrad.2014.06.014
Saito T, Brown S, Chatterjee S, Kim J, Tsouris C, Mayes RT, Kuo L-J, Gill G, Oyola Y, Janke CJ, Dai S (2014) Uranium recovery from seawater: development of fiber adsorbents prepared via atom-transfer radical polymerization. J Mater Chem A 2(35):14674–14681. https://doi.org/10.1039/C4TA03276D
Sylwester ER, Hudson EA, Allen PG (2000) The structure of uranium (VI) sorption complexes on silica, alumina, and montmorillonite. Geochim Cosmochim Acta 64(14):2431–2438. https://doi.org/10.1016/S0016-7037(00)00376-8
Ling L, W-x Zhang (2015) Enrichment and encapsulation of uranium with iron nanoparticle. J Am Chem Soc 137(8):2788–2791. https://doi.org/10.1021/ja510488r
Z-b Zhang, Y-f Qiu, Dai Y, P-f Wang, Gao B, Z-m Dong, X-h Cao, Y-h Liu, Z-g Le (2016) Synthesis and application of sulfonated graphene oxide for the adsorption of uranium(VI) from aqueous solutions. J Radioanal Nucl Chem 310(2):547–557. https://doi.org/10.1007/s10967-016-4813-6
Lee HI, Kim JH, Kim JM, Kim S, Park J-N, Hwang JS, Yeon J-W, Jung Y (2010) Application of ordered nanoporous silica for removal of uranium ions from aqueous solutions. J Nanosci Nanotechnol 10(1):217–221. https://doi.org/10.1166/jnn.2010.1498
Sprynskyy M, Kovalchuk I, Buszewski B (2010) The separation of uranium ions by natural and modified diatomite from aqueous solution. J Hazard Mater 181(1–3):700–707. https://doi.org/10.1016/j.jhazmat.2010.05.069
Shuibo X, Chun Z, Xinghuo Z, Jing Y, Xiaojian Z, Jingsong W (2009) Removal of uranium (VI) from aqueous solution by adsorption of hematite. J Environ Radioact 100(2):162–166. https://doi.org/10.1016/j.jenvrad.2008.09.008
Li X, Li F, Jin Y, Jiang C (2015) The uptake of uranium by tea wastes investigated by batch, spectroscopic and modeling techniques. J Mol Liq 209:413–418. https://doi.org/10.1016/j.molliq.2015.06.014
Zhao Y, Liu C, Feng M, Chen Z, Li S, Tian G, Wang L, Huang J, Li S (2010) Solid phase extraction of uranium(VI) onto benzoylthiourea-anchored activated carbon. J Hazard Mater 176(1–3):119–124. https://doi.org/10.1016/j.jhazmat.2009.11.005
Kadous A, Didi MA, Villemin D (2010) A new sorbent for uranium extraction: ethylenediamino tris(methylenephosphonic) acid grafted on polystyrene resin. J Radioanal Nucl Chem 284(2):431–438. https://doi.org/10.1007/s10967-010-0495-7
Zhang A, Hu Q, Wang W, Kuraoka E (2008) Application of a macroporous silica-based CMPO-impregnated polymeric composite in group partitioning of long-lived minor actinides from highly active liquid by extraction chromatography. Ind Eng Chem Res 47(16):6158–6165
Zha F, Wang X, Wang X, Khayambashi A, Wei Y, Tang F, He L (2017) Synthesis of a novel silica-based macroporous HNA/SiO2-P adsorbent and its adsorption behavior for uranium from aqueous solutions. J Radioanal Nucl Chem 311(3):1793–1802. https://doi.org/10.1007/s10967-016-5141-6
Merdivan M, Düz MZ, Hamamci C (2001) Sorption behaviour of uranium (VI) with N, N-dibutyl-N′-benzoylthiourea impregnated in Amberlite XAD-16. Talanta 55(3):639–645
Wang H, Ma L, Cao K, Geng J, Liu J, Song Q, Yang X, Li S (2012) Selective solid-phase extraction of uranium by salicylideneimine-functionalized hydrothermal carbon. J Hazard Mater 229–230:321–330. https://doi.org/10.1016/j.jhazmat.2012.06.004
Shu Q, Khayambashi A, Zou Q, Wang X, Wei Y, He L, Tang F (2017) Studies on adsorption and separation characteristics of americium and lanthanides using a silica-based macroporous bi(2-ethylhexyl) phosphoric acid (HDEHP) adsorbent. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-017-5293-z
Shu Q, Khayambashi A, Wang X, Wei Y (2018) Studies on adsorption of rare earth elements from nitric acid solution with macroporous silica-based bis(2-ethylhexyl)phosphoric acid impregnated polymeric adsorbent. Adsorpt Sci Technol. https://doi.org/10.1177/0263617417748112
Shu Q, Khayambashi A, Wang X, Wang X, Feng L, Wei Y (2017) Effects of γ irradiation on bis(2-ethylhexyl)phosphoric acid supported by macroporous silica-based polymeric resins. Radiochim Acta. https://doi.org/10.1515/ract-2017-2758
Zhang A, Zhu Y, Liu Y, Chai Z (2011) Preparation of a macroporous silica-based pyridine impregnated material and its adsorption for palladium. Ind Eng Chem Res 50(11):6898–6905. https://doi.org/10.1021/ie1021893
Khayambashi A, Wang X, Wei Y (2016) Solid phase extraction of uranium (VI) from phosphoric acid medium using macroporous silica-based D2EHPA-TOPO impregnated polymeric adsorbent. Hydrometallurgy 164:90–96
Wei Y, Kumagai M, Takashima Y, Modolo G, Odoj R (2000) Studies on the separation of minor actinides from high-level wastes by extraction chromatography using novel silica-based extraction resins. Nucl Technol 132(3):413–423
Zhang A, Wei Y, Kumagai M (2004) Synthesis of a novel macroporous silica-based polymeric material containing 4, 4′, (5′)-di (tert-butylcyclohexano)-18-crown-6 functional group and its adsorption mechanism for strontium. React Funct Polym 61(2):191–202
Zhao Y, Li J, Zhao L, Zhang S, Huang Y, Wu X, Wang X (2014) Synthesis of amidoxime-functionalized Fe3O4@SiO2 core–shell magnetic microspheres for highly efficient sorption of U(VI). Chem Eng J 235:275–283. https://doi.org/10.1016/j.cej.2013.09.034
Ho Y-S, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34(5):451–465
Boparai HK, Joseph M, O’Carroll DM (2011) Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. J Hazard Mater 186(1):458–465
Freundlich U (1906) Uber die adsorption in losungen. J Phys Chem 57:385–470
Weber TW, Chakravorti RK (1974) Pore and solid diffusion models for fixed-bed adsorbers. AIChE J 20(2):228–238
Wu F-C, Liu B-L, Wu K-T, Tseng R-L (2010) A new linear form analysis of Redlich–Peterson isotherm equation for the adsorptions of dyes. Chem Eng J 162(1):21–27. https://doi.org/10.1016/j.cej.2010.03.006
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Khayambashi, A., Shu, Q., Wei, Y. et al. HDEHP-CMPO/SiO2-P: a promising solid-phase extractant for uranium recovery from different acidic media. J Radioanal Nucl Chem 316, 221–231 (2018). https://doi.org/10.1007/s10967-018-5734-3
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DOI: https://doi.org/10.1007/s10967-018-5734-3