Abstract
Parent–progeny isotope relationships provide critical signatures in forensic efforts designed to determine the history of interdicted nuclear materials. Unfortunately, there is substantial need for new standards and QC strategies yielding confidence in such chronometric measurements. Here, we investigate the initial isolation of progeny uranium in certified reference material-126a for use as a precision comparator in a thermal ionization mass spectrometry-based QC strategy seeking to provide improved uncertainties in isotopic and chronometric measurements for nuclear materials containing elevated U-236, such as plutonium. Application to real-world Pu either preserved or improved upon uncertainties associated with key parent–daughter ratios and further constrained associated chronometric windows.
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Acknowledgements
The authors would like to grateful acknowledge the US DHS/DNDO Nuclear Forensics Postdoctoral Fellowship (HSHQDC-14-X-00028) and Dr. Lav Tandon for their support of Dr. B. L. Byerly throughout this work. The Institutional Number for this document is LA-UR-15-27958.
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Stanley, F.E., Mathew, K.J., Byerly, B.L. et al. Pursuing standards strategies in nuclear forensics: investigating extraction of progeny uranium in CRM-126a as a quality control material in Pu–U chronometry. J Radioanal Nucl Chem 311, 1819–1824 (2017). https://doi.org/10.1007/s10967-016-5133-6
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DOI: https://doi.org/10.1007/s10967-016-5133-6