Skip to main content
Log in

Radiation-induced coloration of xylenol blue/film containing hexachloroethane for food irradiation applications

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Polyvinyl butyral films mixed with xylenol blue (XB) indicator and hexachloroethane (HCE) were prepared for possible application in food irradiation. Upon γ–irradiation the films undergo visual color change from yellow (XB, pH 8) to red (XB, pH 2.8) by H+ formation in the presence of HCE. The dosimetric characteristics of films containing different dye and HCE concentrations were investigated spectrophotometrically at λ max 555 nm. Radiation sensitivity is enhanced with HCE and, accordingly red color intensity. The prepared films can be applicable in dose range 0.25–10 kGy with uncertainty of dose reaching 4.45 % at 1σ.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Ranjbar AH, Aliabadi R, Amraei R, Tabasi M, Mirjalily G (2009) ESR response of bulk samples of clear fused quartz (CFQ) material to high doses from 10 MeV electrons: its possible application for radiation processing and medical sterilization. Appl Radiat Isot 67:1023–1026

    Article  CAS  Google Scholar 

  2. Correcher V, García-Guinea J (2011) Application of the EN1788 European standard for the control of saffron, pepper and blends. Food Control 22:173–179

    Article  CAS  Google Scholar 

  3. Buchalla R, Boess C, Bogl KW (2000) Analysis of volatile radiolysis products in gamma-irradiated LDPE and polypropylene films by thermal desorption-gas chromatography-mass spectrometry. Appl Radiat Isot 52:251–269

    Article  CAS  Google Scholar 

  4. Khan AA, Khan HM (2008) DNA comet assay: a simple screening technique for identification of some irradiated foods. J Radioanal Nucl Chem 275:337–342

    Article  CAS  Google Scholar 

  5. Soliman YS, Abdel-Fattah AA (2013) Leuco crystal violet/poly(vinyl butyral) thin film as a high-dose Dosimeter. Radiat Meas 49:1–6

    Article  CAS  Google Scholar 

  6. Soliman YS, Beshir WB, Abdel-Fattah AA, Abdel-Rehim F (2013) Dosimetric studies for gamma radiation validation of medical devices. Appl Radiat Isot 71:21–28

    Article  CAS  Google Scholar 

  7. Soliman YS, Basfar AA, Msalam RI (2014) A radiochromic film based on leucomalachite green for high-dose dosimetry applications. Radiat Meas 62:45–51

    Article  CAS  Google Scholar 

  8. Beshir WB (2013) Radiation sensitive indicator based on tetrabromophenol blue dyed poly(vinyl alcohol). Radiat Phys Chem 86:129–135

    Article  CAS  Google Scholar 

  9. Basfar AA, Rabaeh KA, Moussa AA, Msalam RI (2011) Dosimetry characterization of nitro-blue tetrazolium polyvinyl butyral films for radiation processing. Radiat Phys Chem 80:763–766

    Article  CAS  Google Scholar 

  10. Uribe RM, Barcelo M, McLaughlin WL, Buenfil A, Rios J (1999) Initial color development in radiochromic dye films after a short intense pulse of accelerated electrons. Radiat Phys Chem 35:724–727

    Google Scholar 

  11. Mai HH, Solomon HM, Taguchi M, Kojima T (2008) Polyvinyl butyral films containing leuco-malachite green as low-dose dosimeters. Radiat Phys Chem 77:457–462

    Article  CAS  Google Scholar 

  12. Abdel-Fattah AA, Abdel-Rehim F, Soliman YS (2012) A new label dosimetry system based on pentacosa-diynoic acid monomer for low dose applications. Radiat Phys Chem 81:70–76

    Article  CAS  Google Scholar 

  13. Abdel-Fattah AA, Ebraheem S, El-Kelany M, Abdel-Rehim F (1996) High-dose film dosimeters based on bromophenol blue or xylenol orange dyed polyvinyl alcohol. Appl Radiat Isot 47:345–350

    Article  Google Scholar 

  14. Bhat NV, Nate MM, Bhat RM, Bhatt BC (2007) Effect of gamma irradiation on polyvinyl alcohol films doped with some dyes and their use in dosimetric studies. Indian J Pure Appl Phys 45:545–548

    CAS  Google Scholar 

  15. AlZahrany A, Rabaeh KA, Basfar AA (2011) Radiation induced color bleaching of methyl red in polyvinylbutyral film dosimeter. Radiat Phys Chem 80:1263–1267

    Article  CAS  Google Scholar 

  16. Abdel-Fattah AA, Hegazy ESA, Ezz El-Din H (2002) Radiation-chemical formation of HCl in Poly(vinyl butyral) films containing chloral hydrate for use in radiation dosimetry. Int J Polym Mater 51:851–874

    Article  CAS  Google Scholar 

  17. Abdel-Fattah AA, El-Kelany M (1998) Radiation-sensitive indicator based on radiation-chemical formation of acids in polyvinyl butyral films containing chloral hydrate. Radiat Phys Chem 51:317–325

    Article  CAS  Google Scholar 

  18. Mai HH, Duong DN, Kojima T (2004) Dyed polyvinyl chloride films for use as high-dose routine dosimeters in radiation processing. Radiat Phys Chem 69:439–444

    Article  CAS  Google Scholar 

  19. Gafar SM, El-Ahdal MA (2014) Dosimetric characteristics of 2,6-dinitro phenol for high dose dosimetry. Dyes Pigm 109:67–71

    Article  CAS  Google Scholar 

  20. Abdel-Fattah AA, El-Kelany M, Abdel-Rehim F (1996) Development of a radiation-sensitive indicator. Radiat Phys Chem 48:497–503

    Article  CAS  Google Scholar 

  21. Beshir WB, Eid S, Ebraheem S (2007) Use of bromocresol green dyed poly(vinyl butyral) film for dosimetric applications. Int J Polym Mater 56:1067–1077

    Article  CAS  Google Scholar 

  22. Greenspan L (1977) Equilibrium relative humidity of some saturated salt solutions 25 °C. J Res Nat Bur Stand 81A:89

    Article  Google Scholar 

  23. Bacci M, Baldini F, Bracci S (1991) Spectroscopic behavior of acid-base indicators after immobilization on glass supports. Appl Spectrosc 45:1508–1515

    Article  CAS  Google Scholar 

  24. Vytřas K (1974) Sulfonephthalein dyes. I. Spectrophotometric study of xylenol blue and bromoxylenol blue using colorimetric systems. Chem Pap 28:252–261

    Google Scholar 

  25. Cohen A (1922) Xylenol blue and its proposed use as a new and improved indicator in Chemical and Biochemical work. J Biochem 16(1):31–34

    Article  CAS  Google Scholar 

  26. Sigma-Aldrich website (2015) (http://www.sigmaaldrich.com/catalog/substance/xylenolblue4104812531511). Accessed 20 Oct 2015

  27. Meyer TD, Hemelsoet K, Speybroeck VV, Clerck KD (2014) Substituent effects on absorption spectra of pH indicators: an experimental and computational study of sulfonphthaleine dyes. Dyes Pigments 102:241–250

    Article  Google Scholar 

  28. Sadaoka Y, Sakai Y, Yamada M (1993) Optical properties of sulfonephthalein dyes entrapped within polymer matrices for quantification of ammonia vapour and humidity in air. J Mater Chem 3(8):877–881

    Article  CAS  Google Scholar 

  29. Sharp P, Miller A (2009) Guidelines for the calibration of routine dosimetry systems for use in radiation processing. National Physical Laboratory. NPL Rep. CIRM. 29

  30. ISO/ASTM 51707 (2014) Standard guide for estimation of measurement uncertainty in dosimetry for radiation processing. In: Annual book of ASTM standards. ASTM International, West Conshohocken

  31. Mehta K (2006) Radiation processing dosimetry: a practical manual. Radiat Phys Chem 76:1087

    Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Nasr City, Cairo, Egypt for basic research in the field of radiation technology applications.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yasser S. Soliman.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Soliman, Y.S., Beshir, W.B., Abdel-Fattah, A.A. et al. Radiation-induced coloration of xylenol blue/film containing hexachloroethane for food irradiation applications. J Radioanal Nucl Chem 310, 117–124 (2016). https://doi.org/10.1007/s10967-016-4747-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-016-4747-z

Keywords

Navigation