Skip to main content
Log in

Sediment geochronology and geochemical behavior of major and rare earth elements in the Oualidia Lagoon in the western Morocco

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Naturally occurring radionuclides and 137Cs were measured in a sediment core and surface deposit collected from the bed channel of the Oualidia Lagoon located in the western Morocco. Major and rare earth elements (REE) profiles were determined by instrumental NAA technique. 210Pb and 137Cs were used to establish the sedimentation chronology over the last decades by using conventional models. 210Pb displayed relatively higher concentrations and rate of supply to the sediment than typical levels found in other coastal areas in Morocco. REE ratios and Ce anomalies showed that the direct incorporation of particles from seawater to the bed sediment is the most important, followed by the terrigenous component.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Hilmi K, Koutitonsky VG, Orbi A, Lakhdar Idrissi J, Chagdali M (2005) Oualidia lagoon, Morocco: an estuary without a river. Afr J Aquat Sci 30(1):1–10

    Article  Google Scholar 

  2. Hilmi K, Orbi A, Lakhdar Idrissi J (2009) Hydrodynamisme de la lagune de Oualidia (Maroc) durant l’été et l’automne 2005. Bull Inst Sci 31:29–34

    Google Scholar 

  3. Zourarah B, Maanan M, Carruesco C, Aajjane A, Mehdi K, Conceição Freitas M (2007) Fifty-year sedimentary record of heavy metal pollution in the lagoon of Oualidia (Moroccan Atlantic coast). Estuar Coast Shelf Sci 72:359–369

    Article  Google Scholar 

  4. Maanan M, Ruiz-Fernández AC, Maanan M, Fattal P, Zourarah B, Sahabi M (2014) A long-term record of land use change impacts on sediments in Oualidia lagoon, Morocco. Int J Sediment Res 29:1–10

    Article  Google Scholar 

  5. Rubio B, Nombela MA, Vilas F (2000) Geochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution. Mar Pollut Bull 40:968–980

    Article  CAS  Google Scholar 

  6. Lopez P, Navarro E, Marce R, Ordoñez J, Caputo L, Armengol J (2006) Elemental ratios in sediments as indicators of ecological processes in Spanish reservoirs. Limnetica 25(1–2):499–512

    Google Scholar 

  7. Tranchida G, Oliveri E, Angelone M, Bellanca A, Censi P, D’Elia M, Neri R, Placenti F, Sprovieri M, Mazzola S (2011) Distribution of rare earth elements in marine sediments from the Strait of Sicily (western Mediterranean Sea): evidence of phosphogypsum waste contamination. Mar Pollut Bull 62:182–191

    Article  CAS  Google Scholar 

  8. Nie Y, Liu X, Emslie SD (2014) Distribution and sources of rare earth elements in ornithogenic sediments from the Ross Sea region, Antarctica. Microchem J 114:247–260

    Article  CAS  Google Scholar 

  9. Laissaoui A, Benmansour M, Ziad N, IbnMajah M, Abril JM, Mulsow S (2008) Anthropogenic radionuclides in the water column and a sediment core from the Alboran Sea: application to radiometric dating and reconstruction of historical water column radionuclide concentration. J Paleolimnol 40(3):823–833

    Article  Google Scholar 

  10. Kirchner G (2011) 210Pb as a tool for establishing sediment chronologies: examples of potentials and limitations of conventional dating models. J Environ Radioact 102:490–494

    Article  CAS  Google Scholar 

  11. Rharbi N, Ramdani M, Berrahou A, Lakhdar Idrissi A (2001) Caractéristiques hydrologiques et écologiques de la lagune de Oualidia, milieu paralique de la côte atlantique marocaine. Mar life 11(1–2):3–9

    Google Scholar 

  12. Matthews KM, Kim CK, Martin P (2007) Determination of 210Po in environmental materials: a review of analytical methodology. Appl Radiat Isot 65:267–279

    Article  CAS  Google Scholar 

  13. Brenner M, Claire L, Schelske CL, William FK (2004) Inputs of dissolved and particulate 226Ra to lakes and implications for 210Pb dating recent sediments. J Paleolimnol 32:53–66

    Article  Google Scholar 

  14. Ramos-Lerate I, Barrera M, Ligero RA, Casas-Ruiz M (1998) A new method for gamma-efficiency calibration of voluminal samples in cylindrical geometry. J Environ Radioact 38(1):47–57

    Article  CAS  Google Scholar 

  15. He Q, Walling DE (1996) Use of fallout 210Pb measurements to investigate longer-term rates and patterns of overbank sediment deposition on the floodplains of lowland rivers. Earth Surf Process Landf 21:141–154

    Article  CAS  Google Scholar 

  16. Kim Y, Kim K, Kang HD, Kim W, Doh SH, Kim DS, Kim BK (2007) The accumulation of radiocesium in coarse marine sediment: effects of mineralogy and organic matter. Mar Pollut Bull 54:1341–1350

    Article  CAS  Google Scholar 

  17. United Nations Scientific Committee on Effects of Atomic Radiation (2000) Exposures from natural radiation sources, UNSCEAR Report, New York

  18. Laissaoui A, Mas JL, Hurtado S, Ziad N, Villa M, Benmansour M (2013) Radionuclide activities and metal concentrations in sediments of the Sebou Estuary, NW Morocco, following a flooding event. Environ Monit Assess 185:5019–5029

    Article  CAS  Google Scholar 

  19. Abril JM (2003) A new theoretical treatment of compaction and the advective-diffusive processes in sediments: a reviewed basis for radiometric dating models. J Paleolimnol 30(4):363–370

    Article  Google Scholar 

  20. Freudenthal T, Meggers H, Henderiks J, Kuhlmann H, Moreno A, Wefer G (2002) Upwelling intensity and filament activity off Morocco during the last 250,000 years. Deep Sea Res Part II 49(17):3655–3674

    Article  CAS  Google Scholar 

  21. Makaoui A, Orbi A, Hilmi S, Zizah K, Larissi J, Talbi M (2005) Upwelling of the Moroccan Atlantic coast between 1994 and 1998. C R Geosci 337(16):1518–1524

    Article  Google Scholar 

  22. Ruiz-Fernandez AC, Hillaire-Marcel C, de Vernal A, Machain-Castillo ML, Vasquez L, Sholkovitz ER, Landing WM, Lewis BL (1994) Ocean particle chemistry: the fractionation of the rare earth elements between suspended particles and seawater. Geochim Cosmochim Acta 58:1567–1580

  23. Taylor SR (1964) Trace element abundances and the chondritic Earth model. Geochim Cosmochim Acta 28(12):1989–1998

    Article  CAS  Google Scholar 

  24. Bounouira H, Choukri A, Cherkaoui R, Gaudry A, Delmas R, Mariet C, Hakam OM, Chakiri S (2008) Multielement analytical procedure coupling INAA, ICP-MS and ICP-AES: application to the determination of major and trace elements in sediment samples of the Bouregreg river (Morocco). J Radioanal Nucl Chem 278(1):65–79

    Article  CAS  Google Scholar 

  25. Lavilla I, Filgueiras AV, Valverde F, Millos J, Palanca A, Bendicho C (2006) Depth profile of trace elements in a sediment core of a high-altitude lake deposit at the Pyrenees, Spain. Water Air Soil Pollut 172(1–4):273–293

    Article  CAS  Google Scholar 

  26. Taylor SR, McLennan SM (1985) The Continental Crust; its composition and evolution; an examination of the geochemical record preserved in sedimentary rocks. Blackwell, Oxford

    Google Scholar 

  27. Wei G, Liu Y, Li X, Shao L, Liang X (2003) Climatic impact on Al, K, Sc and Ti in marine sediments: evidence from ODP Site 1144, South China Sea. Geochem J 37:593–602

    Article  CAS  Google Scholar 

  28. Gao S, Luo TC, Zhang BR, Zhang HF, Han YW, Zhao ZD, Hu YK (1998) Chemical composition of the continental crust as revealed by studies in East China. Geochim Cosmochim Acta 62:1959–1975

    Article  CAS  Google Scholar 

  29. Zhang J, Nozaki Y (1996) Rare earth elements and yttrium in seawater: ICP-MS determinations in the East Caroline, Coral Sea, and South Fiji basins of the western South Pacific Ocean. Geochim Cosmochim Acta 60:4631–4644

    Article  CAS  Google Scholar 

  30. De Baar HJW, Bacon MP, Brewer PG (1985) Rare earth elements in the Pacific and Atlantic oceans. Geochim Cosmochim Acta 49:1943–1959

    Article  Google Scholar 

  31. Condie KC (1991) Another look at rare earth elements in shales. Geochim Cosmochim Acta 55:2527–2531

    Article  CAS  Google Scholar 

  32. Oliveira SMB, Larizzatti FE, Fávaro DIT, Moreira SRD, Mazzilli BP, Piovano EL (2003) Rare earth element patterns in lake sediments as studied by neutron activation analysis. J Radioanal Nucl Chem 258(3):531–535

    Article  CAS  Google Scholar 

  33. Kumar Krishnan, Saion Elias, Halimah MK, Yap CK, Hamzah Muhd Suhaimi (2014) Rare earth element (REE) in surface mangrove sediment by instrumental neutron activation analysis. J Radioanal Nucl Chem 301(3):667–676

    Article  CAS  Google Scholar 

  34. Minai Y, Matsumoto R, Watanabe Y, Tominaga T (1992) Geochemistry of rare earths and other trace elements in sediments from sites 798 and 799, Japan Sea. In: Proceedings of the ocean drilling program, scientific results,s Vol 127/128

  35. Nagarajan R, Madhavaraju J, Armstrong-Altrin JS, Nagendra R (2011) Geochemistry of neoproterozoic limestones of the Shahabad formation, Bhima basin, Karnataka, southern India. Geosci J 15(1):9–25

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work has been carried out within the framework of the regional IAEA - TC project RAF/7/009 “Supporting an Integrated Approach for Marine Pollution Monitoring Using Nuclear Analytical Techniques”, and the program REMER (Réseau National des Sciences et Techniques de la Mer) related to marine pollution.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Laissaoui.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mejjad, N., Laissaoui, A., El-Hammoumi, O. et al. Sediment geochronology and geochemical behavior of major and rare earth elements in the Oualidia Lagoon in the western Morocco. J Radioanal Nucl Chem 309, 1133–1143 (2016). https://doi.org/10.1007/s10967-016-4714-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-016-4714-8

Keywords

Navigation