Abstract
The conditions of pertechnetate ion precipitation with ferroin nitrate in nitric acid solutions were determined. The effect of precipitation condition on the composition and structure of ferroin pertechnetate complexes was analyzed. At aging of the precipitate in the mother liquor the formation of nitrosyl group in the complex was found, which is confirmed by appearance in the IR spectrum of the band at 1700 cm−1 belonging to the coordinated nitrosyl group. Analysis of the IR spectra of ferroin perrhenate and pertechnetate complexes showed that coordinated nitrosyl group is formed only in the presence of technetium in the complex structure.
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Boytsova TA, Murzin AA, Babain VA, Shadrin AYu (2014) Method of preparing technetium solutions. PATENT RU 2513724, Bull 11
Boytsova TA, Murzin AA, Babain VA, Lumpov AA, Kretser UL (2015) 10-Phenantroline complex of iron(II) nitrate: the challenging salt for the technetium precipitation from nitric acid solutions. J Radioanal Nucl Chem 304(1):273–279
Ryabchikov DI, Ryabuhin VA (1966) Analytical chemistry of rare-earth elements. Science, Moscow
Budyak NF, Ekimenkova TA (1975) The analysis of contact and conduct alloys. Metallurgy, Moscow
Bellami L (1957) IR spectra of the molecules. Foreign literature, Moscow
Inskeep RG (1962) RG Infrared spectra of metal complex ions below 600 cm. The spectra of the tris complexes of 1,10-phenan-throline and 2,2/-bipyridine with the transitional metals irons(ff) throimg zinc (ff). J Inorg Nucl Chem 1962(24):763–776
Baluka M, Hanuza J, Jezowska-Trzebiatowska B (1964) The oxychloro technetate (V). Bull Acad
Busey RH, Keller OL Jr (1965) J Chem Phys 41:215–225
Schwochau K (2000) Technetium. Chemistry and radiopharmaceutical applications. Wiley-VCH Verlag GmbH, Weinheim
Ivanov SM, Zubarev AA (2014) Synthesis of complex compounds. Adv Chem Chem Technol 4:47–50
Enemark JH, Feltham RD (1974) Principles of structure, bonding, and reactivity for metal nytrosyl complexes. Coord Chem Rev 13:339–406
RoyChowdhury S, Takomiyama Yukawa Yasuhiko, Bhattacharyya R (2004) The first heterobimetallic one dimention cyano bridged nitrosyl complex containing an alkaline earth metal: synthesis, characterization and crystal structure of the complex [Sr(phen)2(DMF)2][Fe(NO)(CN)5]. Inorg Chem Commun 7:1117–1119
Chen S-M (1998) Bicalyst electrocatalytic and oxidation of nitrate by Fe(II) and Cu(II) complex in the same solution. J Electroanal Chem 457:23–50
Melent’ev AB (2011) The behavior of technetium in the presence of a reducing and complexing agent in relation to the process of separating uranium and plutonium extracted at the reprocessing. Abstract of thesis, IPCE RAS, Moscow, p 21
Kolarik Z, Petrich G, Bleyl HJ (1990) Behaviour of technetium in the extraction with tributyl phosphate in the purex process. In: Proceedings of ISEC’90, Kyoto (Japan)
Atroschenko VI, Kergin SI (1949) Technology of nitric acid. Chemistry, Moscow-Leningrad
Rapoport FM, Il’inskaya AA (1963) Laboratory methods to obtain pure gases: scientific edition. Goschemizdat, Moscow
Nakamoto K (1966) IR spectra of inorganic and coordinated compounds. World, Moscow
Filipova IG, Simonov YuA, Gdanets M, Stavila V (2005) Crystal structure of tris(1,10-phenantroline) iron(II) dinitrate dehydrate. J Struct Chem 46(6):1095–1098
Tangen E (2008) Bonding low-coordinate complexes. Thesis’s, University of Tromsø, p 67
Lewandowska H (2014) Coordination chemistry of nitrosyls and its biochemical implications. Struct Bond 153:45–114
El Jamal MM, Hammud HH (2008) About the instability of [Fe(III)(phen)3]3+. J Univ Chem Technol Metall 43(3):349–356
Greenwood NN, Earnshaw A (1997) Chemistry of the elements. Elsevier, Amsterdam
RoyChowdhury S, Dinda S, Chakraborty S, Simonnet C, Mukherjee AK, Okamoto K-I, Bhattacharyya C (2005) X-ray crystal structure, EPR and electrochemical studies of two novel cyanonitrosylrhenates: K2[Re(NO)(CN)5]·(Phen)6·4.5H2O and K[Re(NO)(H2O)(CN)4]· (phen)5 ·CH3OH ·3H2O. Inorg Chem Commun 8:61–64
Lijuan L (2002) Some coordination chemistry of non-heme iron nitrosyl complexes. Comments Inorg Chem 23:335–353
Keller A, Szterenberg L, Glowiak T (1992) Reductive nitrosylation of molybdate(VI) by hydroxylamine in alcoholic solution. Preparation, spectroscopic characterization and electronic stuctureof mono- and dinitrosyl molybdenum complexes. Crystal structure of [Mo(NO)Cl(OMe)2(phen)]·MeOH. Inorg Chim Acta 202:19–25
Bitterwolf TE (2008) Photolysis of [Ru(bipy)2(NO)Cl](PF6)2 in frozen ionic gas matrices. Evidence for nitrosyl linkage isomerism and NO-loss in a physiologically relevant nitric oxide source. Inorg Chem Commun 11:772–773
Poelhsitz GV, Bogado AL, Donizetti de Souza G, Rodrigues-Filho E, Azevedo Batista A, Peres de Araujo M (2007) New nitrosyl ruthenium complex [RuCl(NO)(dcype)(bipy)](PF6)2: synthesis, NMR and ESI-MS/MS studies. Inorg Chem Commun 10:133–138
Eroy-Reveles AA, Leung Y, Beavers CM, Olmstead MM, Mascharak PK (2008) Near-infrared light activated release of nitric oxide from designed photoactive manganese nitrosyls: stradegy, design, and potential as NO donors. J Am Chem Soc 130(13):14447–14458
Wang R, Wang X, Sundberg EB, Nguyen P, Grant G, Sheth C, Zhao Q, Herron S, Kantardjieff KA, Li L (2009) Synthesis, structures, spectroscopic and electrochemical properties of dinitrosyl iron complexes with bipyridine, terpyridine, and 1,10-phenathroline. Inorg Chem 48:9779–9785
Dulnev PG, Krugova ED, Donchenko PA, Musatov AG, Manyl’skiy VD, Vilesov GI, Boyko AP (1998) Monohydrate complex of cobalt chloride with n-oxide 2- methylpyridine having the property to raise the productivity of pea. PATENT RU 2106352
Nageswara RN, Ulrich K (1992) Synthesis and characterization of trans-[Re(L-L)2O(OH)](ReO4)2 (L–L=2,2′-bipyridine, 4,4′-dimethyl-2,2′-bipyridine) and trans-[Re(L-L)2O2]ReO4 (L–L=1,10-phenantroline) complex. Polyhedron 11–13:1615–1622
Tribollet J, Galle G, Jonusauskas G, Deldicque D, Tondusson M, Letard JF, Freysz E (2011) Transient absorption spectroscopy of the iron(II) [Fe(phen)3]2+ complex: study of the non-radiative relaxation of an isolated iron(II) complex. Chem Phys Lett 513:42–47
Maruk OYa (2013) Structural features of the technetium (VII) in crystalline compounds and strong acids solutions. Abstract of thesis, IPCE RAS, Moscow, p 19
Garraway J, Willson PD (1984) The technetium-catalysed oxidation of hydrazine by nitric acid. J Less Common Met 97:191–203
Mashkin AN (1996) Influence of products of the catalytic oxidation of hydrazine by nitric acid in the presence of technetium on the extraction technology of SNF reprocessing. Abstract of thesis, JSC Khlopin Radium institute, FSUE Mayak, Ozersk, p 33
Obruchnikova YaA (2013) Chemical forms of technetium during its reduction and precipitation in nitric acid solutions, Abstract of thesis, IPCE RAS, Moscow, p 18
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Boytsova, T.A., Lumpov, A.A., Alekseev, I.Y. et al. Influence of precipitation conditions on the composition and structure of ferroin pertechnetate complexes. J Radioanal Nucl Chem 309, 709–716 (2016). https://doi.org/10.1007/s10967-015-4667-3
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DOI: https://doi.org/10.1007/s10967-015-4667-3