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In situ synthesis of volatile carbonyl complexes with short-lived nuclides

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Abstract

Rapid in situ formation of metal carbonyl complexes with short-lived nuclides has been demonstrated to be feasible with recoiling ions formed in nuclear fusion and fission reactions. These carbonyl complexes are highly volatile and can be transported rapidly in a gas-stream to counting or chemistry devices. This method was already successfully applied in the chemical investigation of the superheavy element seaborgium (Z = 106) and appears promising for various fields of nuclear research. In this article, we give an overview on the current status of metal carbonyl complex studies with short-lived d-element isotopes.

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Acknowledgments

Parts of this work were performed at the RI Beam Factory operated by RIKEN Nishina Center and CNS, University of Tokyo.We thank the ion source and accelerator staff at the RIKEN Nishina Center for accelerator based research and the operators of the ion source and UNILAC at GSI, Helmholtzzentrum für Schwerionenfroschung GmbH, Darmstadt, Germany, for providing intense and stable ion beams. The present work is partially supported by the Reimei Research Program (Japan Atomic Energy Agency), the German Federal Ministry for Education and Research contract No. 06MZ7164, the Helmholtz association contract-No.VH-NG-723, the Ministry of Education, Culture, Sports, Science, and Technology, Japan, Grant-in-Aids No. 19002005 and No. 23750072, the Swiss National Science Foundation contract No. 200020 144511, the Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, Heavy Element Chemistry Program of the U.S. Department of Energy at Lawrence Berkeley National Laboratory under Contract No. DE-AC02-05CH11231, and the National Natural Science Foundation of China (Grant No. 11079006)

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Authors and Affiliations

  1. Helmholtz Institute Mainz, 55099, Mainz, Germany

    Julia Even, Christoph E. Düllmann, Jadambaa Khuyagbaatar & Mustapha Laatiaoui

  2. GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291, Darmstadt, Germany

    Dieter Ackermann, Michael Block, Holger Brand, Christoph E. Düllmann, Willi Hartmann, Annett Hübner, Fritz P. Heßberger, Egon Jäger, Jadambaa Khuyagbaatar, Birgit Kindler, Jörg Krier, Nikolaus Kurz, Bettina Lommel, Joachim Maurer, Jutta Steiner & Alexander Yakushev

  3. Johannes Gutenberg University Mainz, 55099, Mainz, Germany

    Antonio Di Nitto, Christoph E. Düllmann, Jens V. Kratz & Norbert Wiehl

  4. Nishina Center, RIKEN, Wako, Saitama, 351-0198, Japan

    Hiromitsu Haba, Minqhiu Huang, Daiya Kaji, Jumpei Kanaya, Yuki Kudou, Kouji Morimoto, Kosuke Morita, Masashi Murakami, Takayuki Sumita, Mirei Takeyama, Kengo Tanaka, Yasuo Wakabayashi & Sayaka Yamaki

  5. Advanced Science Research Center, JAEA, Tokai, Ibaraki, 319-1195, Japan

    Masato Asai, Yusuke Kaneya, Sunao Miyashita, Yuichiro Nagame, Tetsuya K. Sato, Matthias Schädel, Atsushi Toyoshima & Kazuaki Tsukada

  6. University of Berne, 3012, Berne, Switzerland

    Robert Eichler, Andreas Türler & Ilya Usoltsev

  7. Paul Scherrer Institute, 5232, Villigen, Switzerland

    Robert Eichler, Andreas Türler & Ilya Usoltsev

  8. Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou, 730000, China

    Fangli Fan, Zhi Qin & Yang Wang

  9. Hiroshima University, Higashi-Hiroshima, 739-8526, Japan

    Sunao Miyashita

  10. Kyushu University, Higashi-Ku, Fukuoka, 812-8581, Japan

    Kosuke Morita

  11. Niigata University, Niigata, 950-2181, Japan

    Masashi Murakami & Kazuhiro Ooe

  12. University of California, Berkeley, CA, 94720-1460, USA

    Heino Nitsche

  13. Lawrence Berkeley National Laboratory, Berkeley, CA, 94720-8169, USA

    Heino Nitsche

  14. Saitama University, Saitama, 338-8570, Japan

    Sayaka Yamaki

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  1. Julia Even
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Correspondence to Julia Even.

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Even, J., Ackermann, D., Asai, M. et al. In situ synthesis of volatile carbonyl complexes with short-lived nuclides. J Radioanal Nucl Chem 303, 2457–2466 (2015). https://doi.org/10.1007/s10967-014-3793-7

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  • DOI: https://doi.org/10.1007/s10967-014-3793-7

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