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Composite cellulose-inorganic sorbents for 137Cs recovery

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Abstract

In this study, cellulose-inorganic sorbents based on bleached cotton fibres and ferrocyanides of different d-metals have been prepared and used for separation of 137Cs from simulated aqueous solutions. Comparative analysis has been carried out of the sorption properties of obtained sorption materials towards to micro- and macroquantities of caesium at different liquid to solid phases ratios. Various characterization methods including X-ray analysis, IR spectroscopy, and differential thermal analysis were used to determine the structural properties of the obtained composite sorbents. It has been confirmed that the sorbents obtained at approximately the same content of the inorganic component are characterized by different values of the recovery rate and 137Cs distribution coefficient.

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Acknowledgments

This research was supported by a Marie Curie International Research Staff Exchange Scheme Fellowship within the 7th European Community Framework Programme, project PIRSES-GA-2011-295260, “ECONANOSORB” and Programme of National Academy of Sciences of Ukraine “Fine Chemicals”.

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Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine, General Naumov street 17, Kyiv, 03164, Ukraine

    V. V. Galysh, M. T. Кartel, E. M. Pakhlov, O. I. Oranska & Y. I. Gornikov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskiy avenue 31, 119071, Moscow, Russia

    V. V. Milyutin

  3. Technical University in Zvolen, G. Masaryk street 24, 96053, Zvolen, Slovak Republic

    J. Sedliacik & R. Lagana

Authors
  1. V. V. Galysh
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  2. M. T. Кartel
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  3. V. V. Milyutin
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  4. E. M. Pakhlov
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  5. O. I. Oranska
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  6. Y. I. Gornikov
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  7. J. Sedliacik
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  8. R. Lagana
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Correspondence to V. V. Galysh.

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Galysh, V.V., Кartel, M.T., Milyutin, V.V. et al. Composite cellulose-inorganic sorbents for 137Cs recovery. J Radioanal Nucl Chem 301, 315–321 (2014). https://doi.org/10.1007/s10967-014-3179-x

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  • DOI: https://doi.org/10.1007/s10967-014-3179-x

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