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Compatibility between aliphatic polyketone terpolymer and Nylon6 polymer blend

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A Correction to this article was published on 01 September 2023

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Abstract

The compatibility of polyketone (PK)/polyamide 6 (PA) polymer blends was studied to expand the use of PK polymers with polyamide 6 blends. Tensile strength showed negative deviation, but flexural modulus and Izod impact strength showed positive deviation with composition according to the linear mixing law. Differential scanning calorimetry and X-ray diffraction analyses showed that little shift in the glass transition temperature (Tg) and diffraction angles of the blends. Tg shifts were observed in the PK-rich and PA-rich compositions in dynamic mechanical tests, but a broadened bandwidth of tanδ peak and shoulder peaks were present in the PK30/PA70 and PK50/PA50 ranges. The blend morphology showed good interfacial adhesion and appeared as submicron domains in the PK-rich and PA-rich blends. Interfacial adhesion and the domain sizes larger than the critical size of the blend contributed to the improved impact strength of the PK/PA blend. Infrared spectroscopy showed that the hydrogen bonds in each polymer chain were reduced in blending, indicating a certain level of molecular blending between the PK and PA polymers. The results of this study suggest that PK/PA blends are partially miscible.

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References

  1. Zuiderduin WCJ, Homminga DS, Hue´tink J, Gaymans RJ (2003) Polym 44:6361–6370

    Article  CAS  Google Scholar 

  2. Zuiderduin WCJ, Homminga DS, Hue´tink J, Gaymans RJ (2003) Polym 46:1921–1934

    Article  Google Scholar 

  3. Technical Bulletin, Housung Corporation, South Korea

  4. Lagaron JM, Vickers ME, Powell AK (2002) Polym 43:1866–1877

    Article  Google Scholar 

  5. Cho HS, Chung JS, Shim J, Kim JJ, Choi WJ, Lee JC (2012) Macromol Res 20:732–738

    Article  CAS  Google Scholar 

  6. Shkolnik S, Weil ED (1988) J Appl Polym Sci 69:1691–1704

    Article  Google Scholar 

  7. Chiantore O, Lazzari M, Ciardelli F, Vito SD (1997) Macromol 30:2589–2597

    Article  CAS  Google Scholar 

  8. Zhang Y, Broekhuis AA, Picchioni F (2009) Macromol 42:1906–1912

    Article  CAS  Google Scholar 

  9. Yang Y, Li SY, Bao RY, Liu ZY, Yang MB, Tan CB, Yanga W (2018) Polym Int 67:1478–1487

    Article  CAS  Google Scholar 

  10. Xu FY, Chein JCW (1994) Macromol 27:6589–6593

    Article  CAS  Google Scholar 

  11. de Vos SC, Huhn W, Rieger B, Moller M (1999) Polym Bull 42:611–618

    Article  Google Scholar 

  12. Marklund E, Gedde UW, Hedenqvist MS, Wiberg G (2001) Polym 42:3153–3160

    Article  CAS  Google Scholar 

  13. Zuiderduin WCJ, Vlasveld DPN, Hue´tink J, Gaymans RJ (2004) Polym 45:3765–3779

    Article  CAS  Google Scholar 

  14. Lee HC, Son Y, Lee S (2019) J Appl Polym Sci 137:48743

    Article  Google Scholar 

  15. Drent E (1984) Shell Internationale Research Maatschappij BV EP 0121965

  16. Lee J, Lee KH, Kim D, Lim S, Lee SS (2013) Macromol Res 21:1270–1273

    Article  CAS  Google Scholar 

  17. Zuiderduin WCJ, Hue´tink J, Gaymans RJ (2006) Polym 47:5880–5887

    Article  CAS  Google Scholar 

  18. Se´meril D, Passaglia E, Bianchini C, Davies M, Miller H, Ciardelli F (2003) Macromol Mater Eng 288:475–483

    Article  Google Scholar 

  19. Asano A, Nishioka M, Takahashi Y, Kato A, Hikasa S, Iwabuki H, Nagata K, Sato H, Hasegawa T, Sawabe H, Arao M, Suda T, Isoda A, Mukai M, Ishikawa D, Izumi T (2009) Macromol 42:9506–9514

    Article  CAS  Google Scholar 

  20. Kato A, Nishioka M, Takahashi Y, Suda T, Sawabe H, Isoda A, Drozdova O, Hasegawa T, Izumi T, Nagata K, Hikasa S, Iwabuki H, Asano A (2010) J Appl Polym Sci 116:3056–3069

    Article  CAS  Google Scholar 

  21. Gergen WP, Hart WWC, Lutz RG (1989) Shell Internationale Research Maatschappij BV EP 0339745

  22. Gergen WP, Hart WWC (1988) Shell Oil Co US 4960838

  23. Lim MY, Kim HJ, Baek SJ, Kim KY, Lee SS, Lee JC (2014) Carbon 77:366–378

    Article  CAS  Google Scholar 

  24. Kim Y, Bae JW, Lee CS, Kim S, Jung H, Jho JY (2015) Macromol Res 23:971–976

    Article  CAS  Google Scholar 

  25. Sperling LH (1974) In: J F, Kennedy (eds) Recent advances in polymer blends, grafts, and blocks. Plenum press, New York, USA

    Chapter  Google Scholar 

  26. Paul DR, Newman S (1978) In: Macknight WJ, Karaz FE (eds) Polymer blends, 1st edn. Academic Press, New York, USA

    Google Scholar 

  27. Olabisi O, Robeson LM, Shaw MT (1979) Polymer-polymer miscibility, 1st edn. Academic Press, New York, USA

    Google Scholar 

  28. Merz EH, Claver GC, Baer M (1956) J Polym Sci 22:325–341

    Article  CAS  Google Scholar 

  29. Farias-Aguilar JC, Moreno MJR, Téllez-Jurado L, Balmori-Ramírez H (2014) Mater Lett 136:388–392

    Article  CAS  Google Scholar 

  30. Kwon HG, Hwang T, Kim DH, Son Y (2021) Polym Korea 45:748–756

    Article  CAS  Google Scholar 

  31. Li Y, Goddard WA (2002) Macromol 35:8440–8455

    Article  CAS  Google Scholar 

  32. Vasanthan N, Salem DR (2001) J Appl Polym Sci 39:536–547

    Article  CAS  Google Scholar 

  33. Li S, Yang Y, Zha X, Zhou Y, Yang W, Yang M (2018) Nanomaterials 8:932–948

    Article  PubMed  PubMed Central  Google Scholar 

  34. Ohsawa O, Lee KH, Kim BS, Lee S, Kim IS (2010) Polym 51:2007–2012

    Article  CAS  Google Scholar 

  35. Kaplan DS (1979) J Appl Polym Sci 20:2615–2629

    Article  Google Scholar 

  36. Moussaif N, Jerome R (1999) Polym 40:3919–3932

    Article  CAS  Google Scholar 

  37. Wetton RE, Moore JD, Ingram P (1973) Polym 14:161–166

    Article  CAS  Google Scholar 

  38. Imken RL, Paul DR, Balow JW (1976) Polym Eng Sci 16:593–601

    Article  CAS  Google Scholar 

  39. Chen H, Yang B, Zhang H (2000) J Appl Polym Sci 77:928–933

    Article  CAS  Google Scholar 

  40. Phan TTM, DeNicola AJ, Schadler LS (1998) J Appl Polym Sci 68:1451–1472

    Article  CAS  Google Scholar 

  41. Oshinski AJ, Keskkula H, Paul DR (1992) Polym 33:268–283

    Article  CAS  Google Scholar 

  42. Huang JJ, Paul DR (2006) Polym 47:3505–3519

    Article  CAS  Google Scholar 

  43. Mehrabanian M, Nasr M (2011) Int J Nanomed 6:1651–1659

    CAS  Google Scholar 

  44. Skrovanek DJ, Painter PC, Coleman MM (1986) Macromol 19:699–705

    Article  CAS  Google Scholar 

  45. Zhang S, Ma J (2019) e-Polymers 19:23–31

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Jungwon University Research Grant [Grant No. 2021-023].

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Authors and Affiliations

  1. Department of Advanced Materials Science and Engineering, College of Engineering, Kongju National University, Cheonan, Chungnam, 31080, Republic of Korea

    Younggon Son

  2. Department of Materials Science and Engineering, Jungwon University, 85 Munmu-ro Goesan-eup, Chung-buk, 28024, Republic of Korea

    Shichoon Lee

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  1. Younggon Son
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Correspondence to Shichoon Lee.

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Son, Y., Lee, S. Compatibility between aliphatic polyketone terpolymer and Nylon6 polymer blend. J Polym Res 30, 33 (2023). https://doi.org/10.1007/s10965-022-03414-7

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  • DOI: https://doi.org/10.1007/s10965-022-03414-7

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