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Structural characterization of by-product lignins from organosolv rapeseed straw pulping and their application as biosorbents

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Abstract

The feasibility of the pulping technology depends on the efficiency of by-products and solvent recovery. In this regard, the development of an environmentally friendly peracetic method of delignification should be accompanied by the development of an effective method of lignin disposal. Usually, delignification methods are characterized without a detailed study of the by-products. Herein, let’s describe the structural and chemical characteristics of lignin, as well as its sorption properties. Pulping liquors after peracetic delignification of rapeseed straw were used in this work. The application of sodium tungstate and sodium molybdate as catalysts gave a significant effect on the dissolution of lignin during pulping. The composition, structure and functional groups of lignins were investigated. Application of catalysts in organosolv pulping resulted in small amounts of carbohydrates in lignins if compare to lignins after non-catalytic pulping. As catalysts, Na2WO4 and Na2MoO4 exhibited no obvious differences in carbohydrate contents and in molecular weights of organosolv lignin (Mw = 4910–5640 g/mol, Mn = 2350–2500 g/mol). The obtained lignin was successfully used for Methylene Blue adsorption due to high content of functional groups (R-OH = 1.72 mmol/g, Ph-OH = 5.72 mmol/g, R-COOH = 0.88 mmol/g) despite the poorly developed porous structure (11.03 ± 0.35 m2/g). Lignin has potential applicability as a biosorbent for wastewater treatment to solve environmental problems of water pollution.

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Acknowledgements

The contribution of COST Action LignoCOST (CA17128), supported by COST (European Cooperation in Science and Technology), in promoting interaction, exchange of knowledge and collaborations in the field of lignin valorization is gratefully acknowledged. This publication is also based on work supported by the grant FSA3-20-66700 from the U.S. Civilian Research & Development Foundation (CRDF Global) with funding from the United States Department of State. This research was also supported in part by the Ministry of education and science of Ukraine (grant number 21/190490, 2019–2021) and program European Union (Harmonizing water-related graduate education /WaterH, www.waterh.net).

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Authors and Affiliations

  1. Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Ave. 37/4, Kiev, 03056, Ukraine

    Vita Halysh

  2. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, General Naumov Str, 17, Kiev, 03164, Ukraine

    Vita Halysh, Tetiana Kulik & Borys Palianytsia

  3. Ukrainian State University of Chemical Technology, Gagarina Ave., 8, Dnipro, 49005, Ukraine

    Margarita Skiba

  4. TIMR (Integrated Transformations of Renewable Matter), Université de Technologie de Compiègne, ESCOM, Centre de Recherche Royallieu - CS 60 319, 60203, Compiègne Cedex, France

    Alla Nesterenko

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  1. Vita Halysh
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Vita Halysh, Margarita Skiba, Alla Nesterenko, Tetiana Kulik and Borys Palianytsia have contributed equally to this work.

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Halysh, V., Skiba, M., Nesterenko, A. et al. Structural characterization of by-product lignins from organosolv rapeseed straw pulping and their application as biosorbents. J Polym Res 29, 510 (2022). https://doi.org/10.1007/s10965-022-03368-w

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