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Co(II) and Zn(II) coordination polymers: selective detection of Fe(III) ion and treatment activity on renal calculus

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Abstract

In the current study, via applying a mixed-ligand method, two transition metal coordination polymers (CPs) {Co(Br-isa)(bpe)·0.5H2O}n (1) and {Zn(Br-isa)(bpe)1.5·0.5H2O}n (2) have been constructed at room temperature, applying 5-bromo isophthalic acid (Br-H2isa) and 1,2-bis-(4-pyridyl)ethylene (bpe) under distinct transition metal ions. The structural analysis results show that complex 1 features a 2D layered network with a 4-connected sql-type topology and complex 2 shows a 2D layered network with an unprecedented 5-connected topology. Luminescence studies revealed that the Zn-based complex 2 can be utilized as a sensitive luminescent sensor for detection of Fe3+ ions in H2O. Moreover, the sensing performance of 2 toward Fe(III) ion was not influenced by the co-existence of other metal ions. The treatment activity of compounds on renal calculus was further detected and the mechanism of action was researched at the same time. At first, the white blood cells and red blood cells percentages were evaluated with urine routine detection. In addition to this, the blood calcium concentration was next conducted to detect the relevance between the calcium concentration and compound treatment on renal calculus.

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Data availability

The photoluminescence spectra for 2 in aqueous solution before and after the addition of Fe3+ ion (Fig. S1), Liquid UV–Vis spectra of various anions and emission spectra of 2 in aqueous solution (Fig. S2), the information could be found in the supporting information file.

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  1. Xiuguo Gan and Rui Liu authors contributed equally to this work.

Authors and Affiliations

  1. Department of Urology, First Affiliated Hospital of Harbin Medical University, Harbin Medical University, Harbin, Heilongjiang, China

    Xiuguo Gan & Haitao Xu

  2. Department of General Surgery, First Affiliated Hospital of Harbin Medical University, Harbin, Heilongjiang, China

    Rui Liu

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  1. Xiuguo Gan
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  2. Rui Liu
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  3. Haitao Xu
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Correspondence to Xiuguo Gan.

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Gan, X., Liu, R. & Xu, H. Co(II) and Zn(II) coordination polymers: selective detection of Fe(III) ion and treatment activity on renal calculus. J Polym Res 28, 261 (2021). https://doi.org/10.1007/s10965-021-02625-8

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