Abstract
The pressure-dependence photomodulation spectrum of a semiconducting conjugated polymer, phenyl-substituted ladder-type poly(para-phenylene) (Ph-LPPP) with trace-concentrations of metallic impurities, was studied. The so called photo-induced absorption gave the information about the triplet-triplet (TT) transitions and bleaching (PB) of the singlet state in this material. Planarization, therefore, stronger interchain interaction, under pressure was observed. The photo-modulation spectra coupled with Raman scattering and photoluminescence spectra of Ph-LPPP revealed the influence of electronic structure due to pressure on singlet and triplet excitons. As a result, the localized character of triplet state could be changed. The lifetimes of the triplet excitions and the photobleaching were also observed. It was found that the triplet state was less stable than the singlet state.
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So F, Kondakov D (2010) Adv Mater 22:3762–3777
Xie RJ, Hirosaki N, Mitomo M, Sakuma K, Kimura N (2006) Appl Phys Lett 89:241103
Reineke S, Lindner F, Schwartz G, Seidler N, Walzer K, Lussem B, Leo K (2009) Nature 459:234–238
Chen L-M, Hong Z, Li G, Yang Y (2009) Adv Mater 21:1434–1449
Grimsdale AC, Müllen K (2006) Emissive materials nanomaterials, advanced in polymer science, vol 199. Springer, Verlag Berlin Heidelberg
Köhler A, Bässler H (2009) Mater Sci Eng R Rep 66:71–109
Arif M, Yang K, Li L, Yu P, Guha S, Gangopadhyay S, Förster M, Scherf U (2009) Appl Phys Lett 94:063307
Luhman WA, Holmes RJ (2009) Appl Phys Lett 94:153304
Yam VW-W, Wong KM-C, Zhu N (2003) Angew Chem 115:1438–1441
Che C-M, Chao H-Y, Miskowski VM, Li Y, Cheung K-K (2001) J Am Chem Soc 123:4985–4991
Hoofman RJOM, De Haas MP, Siebbeles LDA, Warman JM (1998) Nature 392:54–56
Hemley RJ (2000) Annu Rev Phys Chem 51:763–800
Guha S, Graupner W, Yang S, Chandrasekhar M, Chandrasekhar HR (2001) In: Glaser R, Kaszynski P (eds) Approaches to polar order, ACS symposium series, vol 798. American Chemical Society, Washington DC
Mao HK, Xu J, Bell PM (1986) J Geophys Res Solid Earth 91:4673–4676
Che-Hung H, Chia-Yuan C, Shu-Chun Y (2014) J Appl Sci Eng 17:253–258
Monkman AP, Burrows HD, da Miguel MG, Hamblett I, Navaratnam S (1999) Chem Phys Lett 307:303–309
Burrows HD, da Miguel MG, Monkman AP, Hamblett I, Navaratnam S (2001) J Mol Struct 563–564:41–50
Yang S-C, Graupner W, Guha S, Puschnig P, Martin C, Chandrasekhar HR, Chandrasekhar M, Leising G, Ambrosch-Draxl C, Scherf U (2000) Phys Rev Lett 85:2388
Nguyen TQ, Doan V, Schwartz BJ (1999) J Chem Phys 110:4068
Li Y, Winkel RW, Weisbach N, Gladysz JA, Schanze KS (2014) J Phys Chem A 118:10333–10339
Guha S, Graupner W, Yang S, Chandrasekhar M, Chandrasekhar HR, Leising G (1999) Phys Status Solidi B 211:177–188
Guha S, Chandrasekhar M, Knaapila M, Scherf U (2011) Phys Status Solidi B 248:1083
Paudel K, Moghe D, Chandrasekhar M, Yu P, Ramasesha S, Scherf U, Guha S (2013) Europhys Lett 104:27008
Guha S, Graupner W, Resel R, Chandrasekhar M, Chandrasekhar HR, Glaser R, Leising G (1999) Phys Rev Lett 82:3625
Mulazzi E, Ripamonti A, Wéry J, Dulieu B, Lefrant S (1999) Phys Rev B 60:16519
Wéry J, Aarab H, Lefrant S, Faulques E, Mulazzi E, Perego R (2003) Phys Rev B 67:115202
Hsu Che-Hung, Yang Shu-Chun, Pressure dependence of Raman scattering spectrum of ladder-type poly(para-phenylene) (submitted to J Appl Sci Eng)
Graupner W, Partee J, Shinar J, Leising G, Scherf U (1996) Phys Rev Lett 77:2033
Acknowledgments
The authors acknowledge Prof. U. Scherf in Bergische Universität Wuppertal, German for providing the sample. We are also thankful to Ministry of Science and Technology, Taiwan, R.O.C. for the financial support.
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Hsu, CH., Yang, SC. Photomodulation spectrum of phenyl-substituted ladder-type poly(para-phenylene) under hydrostatic pressure. J Polym Res 22, 105 (2015). https://doi.org/10.1007/s10965-015-0752-0
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DOI: https://doi.org/10.1007/s10965-015-0752-0