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Self-oscillating soluble-insoluble changes of polymer chain induced by the BZ reaction with Fe(phen)3 catalyst

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Abstract

A novel self-oscillation polymer was successfully synthesized by covalently bonding the Fe(phen)3 catalyst for the BZ reaction onto the poly(N-isopropylacrylamide) polymer chain. The lower critical solution temperatures (LCST) of the polymer chain in the reduced and oxidized states were 37 and 32 °C, respectively. The prepared polymer solution can undergo soluble-insoluble self-oscillation induced by the BZ reaction at constant temperature.

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Acknowledgments

This work was supported in part by the Basic Project of Science and Research of Colleges and Universities of Gansu Province (5001-109), the Project for Young Teacher of Northwest Normal University (NWNU-LKQN-13-6).

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Authors and Affiliations

  1. School of Natural and Applied Science, Northwestern Polytechnical University, Xi’an, 710072, People’s Republic of China

    Jie Ren & Guangcheng Zhang

  2. Chemistry & Chemical Engineering College, Northwest Normal University, Key Lab of Bioelectrochemtry & Environmental Analysis of Gansu, Lanzhou, 730070, People’s Republic of China

    Jie Ren, Mengqi Yao, Xiaoci Yang, Jinfen Gu & Wu Yang

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  1. Jie Ren
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  2. Mengqi Yao
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  3. Guangcheng Zhang
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  4. Xiaoci Yang
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  5. Jinfen Gu
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  6. Wu Yang
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Correspondence to Jie Ren or Guangcheng Zhang.

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Ren, J., Yao, M., Zhang, G. et al. Self-oscillating soluble-insoluble changes of polymer chain induced by the BZ reaction with Fe(phen)3 catalyst. J Polym Res 22, 44 (2015). https://doi.org/10.1007/s10965-015-0686-6

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  • DOI: https://doi.org/10.1007/s10965-015-0686-6

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