Abstract
A novel salt-tolerant macromonomer, allyl-capped octylphenoxy poly(ethylene oxide) (AOP) with the degree of polymerization equal to 20, was synthesized, and then a novel acrylamide(AM)-based tetra-polymer (PSAA) containing sodium 2-acrylamido-2-methylpropane sulphonate (NaAMPS), AOP, and vinyl biphenyl (VP) was synthesized by aqueous free-radical copolymerization. Static light scattering measurement shows that the weight-average molecular weight of PSAA is only 6.75 × 106 g/mol, but the z-average radius of gyration in 30 g/L NaCl is up to 189 nm. The apparent viscosities of aqueous PSAA solutions are very low at all polymer concentrations. However, for PSAA in 70 g/L NaCl, the critical association concentration (C p *) decreases from 0.4 g/L in water to 0.3 g/L, and the apparent viscosity increases sharply with an increase in polymer concentration and is higher surprisingly than that in water above C p *. The influences of NaCl and CaCl2 concentrations on solution viscosities of PSAA were measured, and the brine solutions display the strong salt-thickening effect in a wide range of salt concentration. This is different from hydrophobically associating polymers reported in the literature. Moreover, the thickening mechanisms of PSAA in water and brine solutions were investigated by a fluorescent probe and atomic force microscope (AFM).
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We acknowledge the financial supports of the Specialized Research Fund for the Doctoral Program of Higher Education (contract grant number: 20135122110017) and Freedom Innovation Foundations of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (contract grant number: 2014–192).
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Zhong, C., Zhang, H. & Feng, L. Solution behavior and associating structures of a salt-tolerant tetra-polymer containing an allyl-capped macromonomer. J Polym Res 21, 604 (2014). https://doi.org/10.1007/s10965-014-0604-3
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DOI: https://doi.org/10.1007/s10965-014-0604-3