Abstract
Three C8 alkanes (n-octane, iso-octane and ethyl cyclohexane) as additives were blended with methyl laurate to prepare binary systems of fuel blends for density, viscosity and refractive index measurement. The excess properties of volumes and viscosity of the three binary systems (methyl laurate + n-octane), (methyl laurate + iso-octane) and (methyl laurate + ethyl cyclohexane) were obtained and compared, which were also fitted to Redlich–Kister equation. The correlated values from Redlich–Kister equation are in good agreement with those from experimental data. The results can be used for the research of the mixture behaviors and development of biodiesel-diesel fuel blends.
Similar content being viewed by others
References
Das, M., Sarkar, M., Datta, A., Santra, A.K.: Study on viscosity and surface tension properties of biodiesel-diesel blends and their effects on spray parameters for CI engines. Fuel 220, 769–779 (2018)
Xue, J., Grift, T.E., Hansen, A.C.: Effect of biodiesel on engine performances and emissions. Renew. Sustain. Energy Rev. 15, 1098–1116 (2011)
Mahmudul, H.M., Hagos, F.Y., Mamat, R., Abdul Adam, A., Ishak, W.F.W., Alenezi, R.: Production, characterization and performance of biodiesel as an alternative fuel in diesel engines—a review. Renew. Sustain. Energy Rev. 72, 497–509 (2017)
Choi, S.H., Oh, Y.: The emission effects by the use of biodiesel fuel. Int. J. Mod. Phys. B 20, 4481–4486 (2006)
Sharp, C.A., Howell, S.A., Jobe, J.: The effect of biodiesel fuels on transient emissions from modern diesel engines, Part II: Unregulated emissions and chemical characterization. SAE paper 2000-01-1968 (2000)
Ismail, H.M., Ng, H.K., Gan, S., Cheng, X., Lucchini, T.: Investigation of biodiesel−diesel fuel blends on combustion characteristics in a light-duty diesel engine using open FOAM. Energy Fuels 27, 208–219 (2013)
Pourhoseini, S.H., Namvar-Mahboub, M., Hosseini, E., Alimoradi, A.: A comparative exploration of thermal, radiative and pollutant emission characteristics of oil burner flame using palm oil biodiesel-diesel blend fuel and diesel fuel. Energy 217, 119338 (2021)
Jaichandar, S., Annamalai, K.: The status of biodiesel as an alternative fuel for Diesel engine an overview. J. Sustain. Energy Environ. 2, 71–75 (2011)
Yoon, S.H., Park, S.H., Lee, C.S.: Experimental investigation on the fuel properties of Biodiesel and its blends at various temperatures. Energy Fuels 22, 652–656 (2008)
Payri, R., Salvador, F.J., Gimeno, J., Bracho, G.: The effect of temperature and pressure on thermodynamic properties of diesel and Biodiesel fuels. Fuel 90, 1172–1180 (2011)
Pratas, M.J., Freitas, S.V.D., Oliveira, M.B., Monteiro, S.C., Lima, A.S., Coutinho, J.A.P.: Biodiesel density: experimental measurements and prediction models. Energy Fuels 25(5), 2333–2340 (2011)
Ramírez-Verduzco, L.F., García-Flores, B.E., Rodríguez-Rodríguez, J.E., Jaramillo-Jacob, A.R.: Prediction of the density and viscosity in biodiesel blends at various temperatures. Fuel 90, 1751–1761 (2011)
Demirbas, A.: Relationships derived from physical properties of vegetable oil and biodiesel fuels. Fuel 87, 1743–1748 (2008)
NguyenThi, T.X., Bazile, J.P., Bessières, D.: Density measurements of waste cooking oil biodiesel and diesel blends over extended pressure and temperature ranges. Energies 11, 1212 (2018)
Wang, X., Wang, X., Chen, J.: Experimental investigations of density and dynamic viscosity of n-hexadecane with three fatty acid methyl esters. Fuel 166, 553–559 (2016)
Wang, X., Kang, K., Lang, H.: High-pressure liquid densities and derived thermodynamic properties for methyl laurate and ethyl laurate. J. Chem. Thermodyn. 103, 310–315 (2016)
Aissa, M.A., Ivanis, G.R., Radovic, I.R., Kijevcanin, M.L.: Experimental Investigation and Modeling of thermophysical properties of pure methyl and ethyl esters at high pressures. Energy Fuels 31, 7110–7122 (2017)
Liew, K.Y., Seng, C.E., Oh, L.L.: Viscosities and densities of the methyl esters of some n-alkanoic acids. J. Am. Oil Chem. Soc. 69, 155–158 (1992)
Althouse, P.M., Hunter, G.W., Triebold, H.O.: Refractive Indexes of the methyl, propyl and isopropyl esters of the C6–C18 saturated fatty acids for various temperatures between 20 and 45 °C. J. Am. Oil Chem. Soc. 24, 257 (1947)
Gouw, T.H., Vlugter, J.C.: Physical properties of fatty acid methyl esters. II. Refractive index and molar refraction. J. Am. Oil Chem. Soc. 41, 426–429 (1964)
Yue, L., Qin, X., Wu, X., Xu, L., Guo, Y., Fang, W.: Excess molar volume along with viscosity, refractive index and relative permittivity for binary mixtures of exo-tetrahydrodicyclopentadiene with four octane isomers. J. Chem. Thermodyn. 81, 26–33 (2015)
Yang, F., Guo, Y., Xing, Y., Li, D., Fang, W., Lin, R.: Densities and viscosities of binary mixtures of JP-10 with n-octane or n-decane at several temperatures. J. Chem. Eng. Data 53, 2237–2240 (2008)
Gonzalez, B., Dominguez, A., Tojo, J.: Viscosities, densities and speeds of sound of the binary systems: 2-propanol with octane, or decane, or dodecane at T = (293.15, 298.15, and 303.15)K. J. Chem. Thermodyn. 35, 939–953 (2003)
Landaverde-Cortes, D.C., Estrada-Baltazar, A., Iglesias-Silva, G.A., Hall, K.R.: Densities and viscosities of MTBE + heptane or octane at p = 0.1 MPa from (273.15 to 363.15) K. J. Chem. Eng. Data 52, 1226–1232 (2007)
Cai, M., Liu, Z., Sun, H., Guo, Y., Fang, W.: Densities and viscosities for the ternary system of cyclopropanemethanol (1) + 2,2,4-trimethylpentane (2) + decalin (3) and corresponding binaries at T = 293.15–323.15 K. Phys. Chem. Liq. 57(4), 491–503 (2019)
Gomez-Diaz, D., Mejuto, J.C., Navaza, J.M.: Physicochemical properties of liquid mixtures. 1. Viscosity, density, surface tension and refractive index of cyclohexane+2,2,4-trimethylpentane binary liquid systems from 25 to 50 degrees C. J Chem Eng Data. 46, 720–724 (2001)
Zhang, C., Li, G., Yue, L., Guo, Y., Fang, W.: Densities, viscosities, refractive indices, and surface tensions of binary mixtures of 2,2,4-trimethylpentane with several alkylated cyclohexanes from (293.15 to 343.15) K. J. Chem. Eng. Data 60, 2541–2548 (2015)
Li, G., Chi, H., Guo, Y., Fang, W., Hu, S.: Excess molar volume along with viscosity and refractive index for binary systems of tricyclo[5.2.1.0(2.6)]decane with five cycloalkanes. J. Chem. Eng. Data 58, 3078–3086 (2013)
Li, D., Wang, J., Gao, Y., Zhan, X., Li, M., Wang, Y.: Density, viscosity, and refractive index of binary mixtures of fatty acid ethyl esters with ethylcyclohexane. J. Chem. Eng. Data. 64, 5324–5331 (2019)
Zhao, J., Wu, J., Dai, Y., Cheng, X., Sun, H., Guo, Y., Fang, W.: Density, viscosity, and freezing point for four binary systems of n-dodecane or methylcyclohexane mixed with 1-heptanol or cyclohexylmethanol. J. Chem. Eng. Data 62, 643–652 (2017)
Gahlyan, S., Maken, S., Park, S.J.: Measurement and modelling of solid–liquid equilibria, density and viscosity of fatty acid methyl or ethyl esters. J. Mol. Liq. 314, 113628 (2020)
Liau, W.R., Tang, M., Chen, Y.P.: Densities and viscosities of butyl acrylate + 1-butanol and ethyl laurate + 1-butanol at 293.15, 303.15, and 313.15 K. J. Chem. Eng. Data 43, 826–829 (1998)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Li, D., Pang, Y., Wang, J. et al. Excess Molar Volume, Viscosity and Refractive Index for Binary Mixtures of Methyl Laurate with n-Octane, Iso-Octane or Ethyl Cyclohexane. J Solution Chem 51, 752–767 (2022). https://doi.org/10.1007/s10953-022-01160-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10953-022-01160-4