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Phase Equilibria for Three Ternary Systems (Water + n-Propanol + n-Butyl Acetate, Ethyl Butyrate or n-Pentyl Acetate) at T = (293.15, 303.15, 313.15) K

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Abstract

The experimental liquid phase compositions of the ternary systems (water + n-propanol + n-butyl acetate, ethyl butyrate or n-pentyl acetate) were measured at T = (293.15, 303.15 and 313.15) K under atmospheric pressure. The thermodynamic modified and extended UNIQUAC models were applied to correlate and analyze the experimental values. Ternary phase diagrams at the experimental temperatures were plotted and compared. The linear trend of the measured liquid–liquid equilibrium data was confirmed by using the Bachman equation. Distribution coefficients and separation factors were applied to evaluate extracting capability of n-butyl acetate, ethyl butyrate and n-pentyl acetate to separate n-propanol from (n-propanol + water) solutions.

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References

  1. Cháfer, A., de la Torre, J., Cumplido, M.P., Monton, J.B.: Measurement and correlation of liquid–liquid equilibria at different temperatures in water + 1-propanol + 1-ethyl-3- methylimidazolium bis(trifluoromethylsulfonyl) imide or 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ternary systems. Fluid Phase Equilib. 429, 76–83 (2016)

    Article  Google Scholar 

  2. Çehreli, S., Özmen, D., Dramur, U.: (Liquid+ liquid) equilibria of (water+ 1-propanol+ solvent) at T= 298.2 K. Fluid Phase Equilib. 239, 156–160 (2006)

    Article  Google Scholar 

  3. Özmen, D., Çehreli, S.: Phase equilibria of water+ 1-propanol+ solvent (n-amyl acetate, cyclohexanol, and cyclohexyl acetate) at T= 298.2 K. Fluid Phase Equilib. 253, 61–66 (2007)

    Article  Google Scholar 

  4. Susial Badajoz, P., García-Vera, D., Montesdeoca, I., Santiago, D.E., López-Beltrán, J.: Measurements and modeling of VLE data for butyl acetate with 2-propanol or 2-butanol binary systems at 015 and 06 MPa. J. Chem. Eng. Data 62, 2296–2306 (2017)

    Article  CAS  Google Scholar 

  5. Bajić, D.M., Živković, E.M., Šerbanović, S.S., Kijevčanin, M.L.: Volumetric and viscometric study of binary systems of ethyl butyrate with alcohols. J. Chem. Eng. Data 59, 3677–3690 (2014)

    Article  Google Scholar 

  6. Chang, W., Guan, G., Li, X., Yao, H.: Isobaric vapor−liquid equilibria for water + acetic acid + (n-pentyl acetate or isopropyl acetate). J. Chem. Eng. Data 50, 1129–1133 (2005)

    Article  CAS  Google Scholar 

  7. Wang, C., Chen, Y., Cheng, K., Wen, C.Y.: Phase equilibria of the ternary systems of (water + diethyl carbonate) with acetone, or 2-butanone at four temperatures. J. Chem. Thermodyn. 102, 147–154 (2016)

    Article  CAS  Google Scholar 

  8. Johnson, I., Costa, H.F., Ferreira, A.G.M., Fonseca, I.M.A.: Density, viscosity, and surface and interfacial tensions of mixtures of water + n-butyl acetate + 1-propanol at 303.15 K and atmospheric pressure. Int. J. Thermophys. 29, 619–633 (2008)

    Article  CAS  Google Scholar 

  9. Costa, H.F., Lourenço, H., Johnson, I., Gonçalves, F.A., Ferreira, A.G., Fonseca, I.M.: Liquid−liquid equilibria, density, viscosity, and surface and interfacial tension of the system water + n-butyl acetate + 1-propanol at 323.15 K and atmospheric pressure. J. Chem. Eng. Data 54, 2845–2854 (2009)

    Article  CAS  Google Scholar 

  10. Tamura, K., Chen, Y., Tada, K., Yamada, T., Nagata, I.: Representation of multicomponent liquid–liquid equilibria for aqueous and organic solutions using a modified UNIQUAC Model. J. Solution Chem. 29, 463–488 (2000)

    Article  CAS  Google Scholar 

  11. Nagata, I.: Modification of the extended UNIQUAC model for correlating quaternary liquid–liquid equilibrium data. Fluid Phase Equilib. 54, 191–206 (1990)

    Article  CAS  Google Scholar 

  12. Bachman, I.: Tie lines in ternary liquid systems. Ind. Eng. Chem. 14, 38–39 (1940)

    Google Scholar 

  13. Donahue, D.J., Bartell, F.E.: The boundary tension at water–organic liquid interfaces. J. Phys. Chem. 56, 480–484 (1952)

    Article  CAS  Google Scholar 

  14. Stephenson, R., Stuart, J.: Mutual binary solubilities: water–alcohols and water–esters. J. Chem. Eng. Data 31, 56–70 (1986)

    Article  CAS  Google Scholar 

  15. Grande, M.D.C., Marschoff, C.M.: Liquid-liquid equilibria for water + benzonitrile + ethyl acetate or butyl acetate. J. Chem. Eng. Data 50, 1324–1327 (2005)

    Article  CAS  Google Scholar 

  16. Wang, L., Cheng, Y., Xiao, X., Li, X.: Liquid–liquid equilibria for the ternary systems acetic acid + water + butyl acetate and acetic acid + water + 2-methyl propyl acetate at 304.15 K, 332.15 K, and 366.15 K. J. Chem. Eng. Data 52, 1255–1257 (2007)

    Article  CAS  Google Scholar 

  17. Sørensen, J.M., Arlt, W.: Liquid−Liquid Equilibrium Data Collection, Vol. V, Part 1. DECHEMA, Frankfurt/Main (1980)

  18. Prausnitz, J.M., Anderson, T.F., Grens, E.A., Eckert, C.A., Hsieh, R., O’Connell, J.P.: Computer Calculations for Multicomponent Vapor−Liquid and Liquid−Liquid Equilibria. Prentice Hall, Englewood Cliffs (1980)

    Google Scholar 

  19. Poling, B.E., Prausnitz, J.M., O’Connell, J.P.: The Properties of Gases and Liquids, 5th edn., McGraw-Hill Inc (2001)

  20. Nelder, J.A., Mead, R.A.: Simplex method for function minimization. Comput. J. 7, 308–313 (1965)

    Article  Google Scholar 

  21. Orchillés, A.V., Miguel, P.J., Vercher, E., Martínez-Andreu, A.: Isobaric vapor–liquid equilibria for 1-propanol + water + 1-ethyl-3-methylimidazolium trifluoromethanesulfonate at 100 kPa. J. Chem. Eng. Data 53, 2426–2431 (2008)

    Article  Google Scholar 

  22. Peng, W.F., Li, H.L., Zhang, Q.Z., Chen, Y.: (Liquid + liquid) extraction of 2-propanol from aqueous solutions using extracting agents ethyl butyrate and n-pentyl acetate at three temperatures. J. Chem. Thermodyn. 144, 105975 (2020)

    Article  CAS  Google Scholar 

  23. Chen, Y., Wang, H., Tang, Y.Y., Zeng, J.: Ternary (liquid + liquid) equilibria for (water + 2-propanol + α-pinene, or β-pinene) mixtures at four temperatures. J. Chem. Thermodyn. 51, 144–149 (2012)

    Article  CAS  Google Scholar 

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Funding

The authors thank the financial support from National Scientific Research Found of China (21271088).

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Authors and Affiliations

  1. Department of Chemistry, Jinan University, Guangzhou, 510632, People’s Republic of China

    Wenfeng Peng, Chaoqing Mo, Honglin Li & Yao Chen

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  1. Wenfeng Peng
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  2. Chaoqing Mo
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  4. Yao Chen
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Correspondence to Yao Chen.

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Peng, W., Mo, C., Li, H. et al. Phase Equilibria for Three Ternary Systems (Water + n-Propanol + n-Butyl Acetate, Ethyl Butyrate or n-Pentyl Acetate) at T = (293.15, 303.15, 313.15) K. J Solution Chem 50, 31–48 (2021). https://doi.org/10.1007/s10953-020-01030-x

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