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A Comprehensive Review on Synthesis, Phase Transition, and Applications of VO2

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Abstract

The first-order reversible phase transition in vanadium dioxide (VO2), popularly coined as metal-insulator transition (MIT), is a matter of significant interest since its genesis in the late 1950s. VO2 in its bulk form exhibits MIT at a transition temperature (Tt) of 340 K. Below Tt, VO2 crystallizes in the monoclinic insulting phase while above Tt, the crystal structure transforms into a more symmetrical tetragonal-rutile phase which is conducting. Such a structural phase transformation (SPT) draws attention to several oxides of vanadium. Vanadate has been a subject of specific correlated compounds where numerous attempts have been made to develop a single theory that can fully define the peculiar nature of phase transition. Two major models namely Peierls and Mott have been proposed to understand the phase transitions. The structural modification in VO2 is responsible for several applications such as thermochromism, Mott-based transistors, bimorph actuators, hydrogen storage capability, microbolometers, and so on. Ferromagnetism (FM) in the doped VO2 films would enhance the data storage capacity. This review focuses on the systematic advancement in the thin films and nanostructures of VO2 over the past decades and the comprehensive understanding between MIT and SPT for advanced applications. A brief account is also given on various methods of synthesis of these oxides.

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Reproduced with permission from AIP, Jour. Appl. Phys. 122, 235,102 (2017) [28]

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Reproduced with permission from Elsevier, Nano Energy 13, 58-66 (2015) [55]

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Reproduced with permission from Elsevier, Appl. Surf. Sci. 425, 233–240 (2017) [58]

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Reproduced with permission from Taylor & Francis, Phase Transitions 85, 185-194 (2012) [70]

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Reproduced with permission from APS, Phys. Rev. B 84, 094426 (2011) [111]

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Reproduced with permission from Elsevier, Sol. Ener. Mat. & Sol. Cell. 94, 141-151 (2010) [127]

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Reproduced with permission from Nature, Nat. Comm. 6, 10,104 (2015) [136]

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Reproduced with permission from ACS, ACS Nano 7, 2266-2272 (2013) [145]

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Reproduced with permission from IOPP, Adv. Nat. Sci.: Nanosci. Nanotec. 6, 013002 (2015) [151]

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Reproduced with permission from OSA, Opt. Exp. 28, 6433-6442 (2020) [153]

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Acknowledgements

AK would like to acknowledge UGC, New Delhi/CUSB, Gaya, for financial support.

Funding

This work is supported by Science and Engineering Research Board-Department of Science and Technology File No CRG/2022/002052.

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Authors and Affiliations

  1. Department of Physics, Central University of South Bihar, Gaya, 824236, India

    Ashutosh Kumar, Akhilananda Kumar & Vijay Raj Singh

  2. Department of Physics & Centre for Interdisciplinary Research, University of Petroleum and Energy Studies (UPES), Dehradun, Uttarakhand, 248007, India

    Asokan Kandasami

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Contributions

Ashutosh Kumar: investigation, methodology, software, writing—original draft; Akhilananda Kumar: formal analysis, review and editing; Asokan Kandasami: formal analysis, review and editing, validation; Vijay Raj Singh: conceptualization, formal analysis, review and editing, validation, supervision, funding acquisition.

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Kumar, A., Kumar, A., Kandasami, A. et al. A Comprehensive Review on Synthesis, Phase Transition, and Applications of VO2. J Supercond Nov Magn 37, 475–498 (2024). https://doi.org/10.1007/s10948-024-06705-w

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