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Structural, Spectral, and Magnetic Properties of Praseodymium–Aluminum-Co-doped M-Type Barium Hexaferrites

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Abstract

Praseodymium (Pr)–aluminum (Al)-co-doped M-type barium ferrite with Ba0.85Pr0.15Fe12-xAlxO19 (x = 0.0–1.0) was prepared by combining solid-phase sintering with high-energy ball milling. The samples were characterized using a thermogravimetric analyzer, X-ray diffractometer, field emission scanning electron microscopy, Fourier transform infrared spectroscopy, and vibrating sample magnetometer. Thermogravimetric analysis indicated that M-type barium ferrite was formed at 1250 °C. X-ray diffraction patterns showed that Al doping did not destroy the crystal structure of barium ferrite. Field emission scanning electron microscopy showed that the samples had a hexagonal crystal structure. The wave numbers of Fourier transform infrared spectroscopy in the 597–607 and 452–459 cm−1 bands represent tetrahedral and octahedral clusters, respectively. With the increase in the amount of Al doping (x) from 0.0 to 1.0, the saturation magnetization (Ms) and residual magnetization (Mr) decreased continuously, and the magnetic anisotropy field (Ha) and coercivity (Hc) increased significantly.

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Funding

The study received funding support from the National Natural Science Foundation of China (grant no. 51764045), Inner Mongolia Autonomous Region Science and Technology Plan Project (grant no. 2021GG0438), and Inner Mongolia Natural Science Foundation (2020MS05048, 2020BS05029).

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Authors and Affiliations

  1. College of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China

    Jie Li & Xing Suo

  2. School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China

    Pengwei Li, Jie Li, Yonglun Wang, Kai Yao, Shuo Shan, Xing Suo & Saisai Ma

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  1. Pengwei Li
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Contributions

Pengwei Li: conceptualization, methodology, software, investigation, writing—original draft, writing—review and editing. Ji Li: resources, supervision. Yonglun Wang: methodology, software. Kai Yao: investigation, validation. Shuo Shan: validation. Xing Suo: validation. Saiai Ma: validation.

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Correspondence to Pengwei Li or Jie Li.

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Li, P., Li, J., Wang, Y. et al. Structural, Spectral, and Magnetic Properties of Praseodymium–Aluminum-Co-doped M-Type Barium Hexaferrites. J Supercond Nov Magn 36, 327–341 (2023). https://doi.org/10.1007/s10948-022-06445-9

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