Skip to main content
SpringerLink
Log in

Study on the Critical Behavior and Magnetocaloric Effect of La0.7−xEuxBa0.15Ca0.15MnO3 (0 ≤ x ≤ 0.08)

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

The structure, magnetic properties, critical behavior, and magnetocaloric effect (MCE) of La0.7−xEuxBa0.15Ca0.15MnO3 (x = 0, 0.02, 0.04, 0.06, and 0.08) samples have been investigated in the paper. The samples have a rhombohedral crystal structure with the R-3C space group. The magnetic entropy change (− ∆SM) of the samples increases from 2.8 to 3.43 J/kg K (μ0H = 5 T) with increasing Eu3+ content. The Curie temperature (TC) decreases from 228 to 187 K; however, the relative cooling power (RCP) increases from 308 to 340 J/kg due to the weakness of the double-exchange interaction with the Eu3+ content. The samples undergo the second-order magnetic phase transitions with the critical parameters of TC = 191 K, β = 0.849, γ = 1.078, and δ = 2.242. The exponents are close to the mean-field values, which means large disorder of spin magnetic moments in the sample. Our work provides a method to tailor the working temperature of MCE in magnetic refrigeration while maintaining or even increasing the magnetic entropy change.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Pecharsky, V.K., Gschneidner, K.A., Jr.: J. Magn. Magn. Mater. 200, 44 (1999)

    Article  ADS  Google Scholar 

  2. Yang, H.F., Hua, S.H., Pan, M.X., Yu, Y.D., Wu, Q., Ge, H.L.: J. Supercond. Nov. Magn. 32, 4021 (2019)

    Article  Google Scholar 

  3. Kharrat, A.B.J., Hlil, E.K., Boujelben, W.: J. Alloys Compd. 739, 101 (2018)

  4. Cheng, J.P., Liao, Z.M., Shi, D., Liu, F., Zhang, X.B.: J. Alloys Compd. 480, 741 (2009)

    Article  Google Scholar 

  5. Fan, J.Y., Pi, L., Zhang, L., Tong, W., Ling, L.S.: Phys. B. 406, 2289 (2011)

    Article  ADS  Google Scholar 

  6. Krenke, T., Duman, E., Acet, M., Wassermann, E.F., Moya, X., Mañosa, L., Planes, A.: Nat. Mater. 4, 450 (2005)

  7. Turcaud, J.A., Pereira, A.M., Sandeman, K.G.: Phys. Rev. B. 90, 024410 (2014)

    Article  ADS  Google Scholar 

  8. Ayadi, F., Regaieg, Y., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A., Lecoq, H., Nowak, S., Ammar, S., Sicard, L.: J. Magn. Magn. Mater. 381, 215 (2015)

    Article  ADS  Google Scholar 

  9. Phan, T.-L., Dang, N.T., Ho, T.A., Manh, T.V., Thanh, T.D., Jung, C.U., Lee, B.W., Le, A.T., Phan, A.D., Yu, S.C.: J. Alloys Compd. 657, 818 (2016)

    Article  Google Scholar 

  10. Tripathi, R., Awana, V.P.S., Panwar, N., Bhalla, G.L., Habermier, H.U., Agarwal, S.K., & Kishan, H.: J. Phys. D: Appl. Phys. 42, 175002 (2009)

  11. Chen, H.Y., Lin, C., Dai, D.S.: J. Magn. Magn. Mater. 257, 254 (2003)

    Article  ADS  Google Scholar 

  12. Anwar, M.S., Ahmed, F., Lee, S.R., Danish, R., Koo, B.H.: Jpn. J. Appl. Phys. 52, 10MC12 (2013)

  13. Ji, Q., Lv, B., Wang, P.F., Cai, H.L., Wu, X.S., Liu, G.H., Luo, G.S.: J. Appl. Phys. 105, 07D713 (2009)

    Article  Google Scholar 

  14. Yang, H.F., Huang, X.N., Wu, Q., Luo, X.Y., Wang, Q.W., Fang, J.Y., Yu, N.J., Pan, M.Y., Ge, H.L.: Mater. Chem. Phys. 267, 124676 (2021)

    Article  Google Scholar 

  15. Dang, N.T., Kozlenkoc, D.P., Kimd, G., Shond, W., Rhyeed, J.S., Petrove, D.N., Manhf, T.V., Phan, T.L.: Curr. Appl. Phys. 20, 794 (2020)

    Article  ADS  Google Scholar 

  16. Dhahri, J., Dhahri, A., Dhahri, E.: J. Magn. Magn. Mater. 321, 4128 (2009)

    Article  ADS  Google Scholar 

  17. Ezaami, A., Sellami-Jmal, E., Cheikhrouhou-Koubaa, W., Koubaa, M., Cheikhrouhou, A.: J. Supercond. Nov. Magn. 30, 911 (2017)

    Article  Google Scholar 

  18. Zghal, E., Koubaa, M., Cheikhrouhou Koubaa, W., Cheikhrouhou, A., Sicard, L., Ammar-Merah, S.: J. Alloys Compd. 627, 211 (2015)

    Article  Google Scholar 

  19. Ezaami, A., Sellami-Jmal, E., Cheikhrouhou-Koubaa, W., Cheikhrouhou, A., Hlil, E.K.: J. Phys. Chem. Solids. 109, 109 (2017)

    Article  ADS  Google Scholar 

  20. Hcini, S., Hsini, M., Robei, H.A., Bouazizi, M.L., Boudard, M.: J. Supercond. Nov. Magn. 33, 1597 (2020)

    Article  Google Scholar 

  21. Ben Hassine, A., Dhahri, A., Bouazizi, M.L., Oumezzine, M., Hlil, E.K.: Ceram. Int. 43, 1390 (2017)

    Article  Google Scholar 

  22. Zarifi, M., Kameli, P., Raoufi, T., Ghotbi Varzaneh, A., Salazar, D., Nouraddini, M.I., Kotsedi, L., Maaza, M.: J. Magn. Magn. Mater. 494, (2020)

  23. Gayathri, N., Raychaudhuri, A., Tiwary, S., Gundakaram, R., Arulraj, A., Rao, C.: Phys. Rev. B. 56, 1345 (1997)

    Article  ADS  Google Scholar 

  24. Motome, Y., Furukawa, N., Nagaosa, N.: Phys. Rev. Lett. 91, 167204 (2003)

    Article  ADS  Google Scholar 

  25. Banerjee, S.K.: Phys. Lett. 12, 16 (1964)

    Article  ADS  Google Scholar 

  26. Pramanik, A.K., Banerjee, A.: Phys. Rev. B 79, 214426 (2009)

    Article  ADS  Google Scholar 

  27. Fisher, M.E.: Rep Prog Phys. 30, 615 (1967)

    Article  ADS  Google Scholar 

  28. Widom, B., Chem, J.: Phys. 43, 3892 (1965)

    Google Scholar 

  29. Kouvel, J.S., Fisher, M.E.: Phys. Rev. 136, A1626 (1964)

    Article  ADS  Google Scholar 

  30. Zhang, L., Menze, D., Jin, C.M., Du, H.F., Ge, M., Zhang, C.J., Li Pi, Tian, M.L., Zhang, Y.H.: Phys. Rev. B. 91, 024403 (2015)

  31. Radaelli, P.G., Cox, D.E., Marezio, M., Cheong, S.-W., Schiffer, P.E., Ramirez, A.P.: Phys. Rev. Lett. 75, 4488 (1995)

    Article  ADS  Google Scholar 

  32. Phan, M.H., Tho, N.D., Chau, N., Yu, S.C., Kurisu, M.: J. Appl. Phys. 97, 103901 (2005)

    Article  ADS  Google Scholar 

  33. Guo, Z.B., Du, Y.W., Zhu, J.S., Huang, H., Ding, W.P., Feng, D.: Phys. Rev. Lett. 78, 1142 (1997)

    Article  ADS  Google Scholar 

  34. Gschneidner, K.A., Pecharsky, V.K.: Annu. Rev. Mater. Sci. 30, 387 (2000)

    Article  ADS  Google Scholar 

  35. Arora, P., Chattopadhyay, M.K., Roy, S.B.: Appl. Phys. Lett. 91, 062508 (2007)

    Article  ADS  Google Scholar 

Download references

Funding

This paper is supported by the National Natural Science Foundation of China (No. 11904343 and No. 51771176) and Zhejiang Provincial Natural Science Foundation of China (Nos. LY21A040006 and LGC21E010002).

Author information

Authors and Affiliations

  1. Magnetism Key Laboratory of Zhejiang Province, China Jiliang University, Hangzhou, 310018, China

    Jieyang Fang, Xinyao Luo, Binlong Pan, Qingwei Wang, Nengjun Yu, Qiong Wu, Minxiang Pan, Hongliang Ge & Hangfu Yang

Authors
  1. Jieyang Fang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xinyao Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Binlong Pan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qingwei Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Nengjun Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Qiong Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Minxiang Pan
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Hongliang Ge
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Hangfu Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hangfu Yang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fang, J., Luo, X., Pan, B. et al. Study on the Critical Behavior and Magnetocaloric Effect of La0.7−xEuxBa0.15Ca0.15MnO3 (0 ≤ x ≤ 0.08). J Supercond Nov Magn 35, 2933–2941 (2022). https://doi.org/10.1007/s10948-022-06349-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-022-06349-8

Keywords

Search

Navigation