Abstract
Ni-Mn-based metamagnetic shape memory alloys (MSMAs) have excellent properties such as magnetic shape memory effect, giant magnetocaloric and barocaloric effects, magneto resistance, and exchange bias effects. These properties introduce them as potential novel materials for technological applications. Therefore, understanding and controlling the wear behavior of NiMn-based MSMAs is an important consideration for mechanical properties. In terms of technological applications, detailed tribological studies clarify the robustness in the harsh environment. In this study, we have performed the tribological behaviors of NiMnX (X = In and Sn) MSMAs. Additionally, the specified alloys are fabricated by two different methods to measure the effects of the fabrication method. The results showed that the wear testing and track depths are affected by fabrication methods, the contribution of X element, and wearing methods. The effect of the load is less significant for reciprocal sliding unlike to pin-on disk. For the pin-on disk, 5 N load presents a clear decrease by means of friction coefficient. Through the experiments, temperature changes from 24.3 to 48.6 °C. Microstructural evaluations highlighted that the alloys fabricated by induction furnace have lower width of wear track. Lastly, the NiMnSn alloy fabricated by using the arc melter comparatively has the widest wear track, 1303 µm.
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Bachaga, T., Zhang, J., Khitouni, M., Sunol, J. J.: NiMn-based Heusler magnetic shape memory alloys: a review. Intern. J. Adva. Manufact. Technol. 103(5), 2761–2772, 2019/08/01 (2019). https://doi.org/10.1007/s00170-019-03534-3
González-Legarreta, L., et al.: Heusler alloy ribbons: structure, martensitic transformation, magnetic transitions, and exchange bias effect. In: Zhukov, A. (ed.) Novel functional magnetic materials: fundamentals and applications, pp. 83–114. Springer International Publishing, Cham (2016)
Umetsu, R., Xu, X., Kainuma, R.: NiMn-based metamagnetic shape memory alloys, Scripta. Mater. 116, 1–6, 04/01 (2016). https://doi.org/10.1016/j.scriptamat.2016.01.006
Ullakko, K., Huang, J.K., Kantner, C., O’Handley, R.C., Kokorin, V.V.: Large magnetic-field-induced strains in Ni2MnGa single crystals. Appl. Phys. Lett. 69(13), 1966–1968 (1996). https://doi.org/10.1063/1.117637
Sutou, Y., et al.: Magnetic and martensitic transformations of NiMnX (X=In, Sn, Sb) ferromagnetic shape memory alloys. Appl. Phys. Lett. 85(19), 4358–4360 (2004). https://doi.org/10.1063/1.1808879
Lázpita, P., Sasmaz, M., Cesari, E., Barandiarán, J. M., Gutiérrez, J., Chernenko, V. A.: Martensitic transformation and magnetic field induced effects in Ni42Co8Mn39Sn11 metamagnetic shape memory alloy. Acta Mater. 109
Planes, A., Mañosa, L.: Ferromagnetic Shape-Memory Alloys. Materials Science Forum 512, 145-152, (2006). https://doi.org/10.4028/www.scientific.net/MSF.512.145
Sokolovskiy, V. V., Zagrebin, M. A., Buchelnikov, V. D.: Novel Achievements in the Research Field of Multifunctional Shape Memory Ni-Mn-In and Ni-Mn-In-Z Heusler Alloys, Materials Science Foundations, vol. 81-82, 38-76 (2015). https://doi.org/10.4028/www.scientific.net/MSFo.81-82.38
Şaşmaz, M., Bayri, A., Aydoğdu Y.: The magnetic behavior and physical characterization of Cu–Mn–Al ferromagnetic shape memory alloy. J. Superconduct. Novel Magnet. 24(1), 757–762, 2011/01/01 (2011). https://doi.org/10.1007/s10948-010-0934-2
Şaşmaz, M.: The effect of Mn content on thermal and magnetic properties of Mn50-xNi41+xSn9 (x = 0, 2, 4) magnetic shape memory alloys, Süleyman Demirel Univ. J. Nat. Appl. Sci. 23(1)
Bachagha, T., Ren, W., Sunol, J. J., Jing, C.: Microstructure characterization, structure and magnetic properties of Ni–Mn–Sn shape memory alloys. J. Thermal Analysis Calorimet. 2021/02/25 (2021). https://doi.org/10.1007/s10973-021-10625-5
Sasmaz, M., et al.: Structure and magnetic-field ınduced effects in Mn-Ni(Fe)-Sn metamagnetic shape memory alloys. Materials Today: Proceedings. 2
Planes, A. et al.: Magnetocaloric and Shape-Memory Properties in Magnetic Heusler Alloys. Advanced Materials Research, vol. 52, 221-228, (2008). https://doi.org/10.4028/www.scientific.net/AMR.52.221
Lázpita, P., Sasmaz, M., Barandiarán, J. M., Chernenko, V. A.: Effect of Fe doping and magnetic field on martensitic transformation of Mn-Ni(Fe)-Sn metamagnetic shape memory alloys. Acta Materialia, vol. 155, 95-103, 2018/08/15/ (2018). https://doi.org/10.1016/j.actamat.2018.05.052
Turabi, A. S., Lázpita, P., Sasmaz, M., Karaca, H. E., Chernenko, V. A.: Magnetic and conventional shape memory behavior of Mn–Ni–Sn and Mn–Ni–Sn(Fe) alloys. J. Phys. D: Appl. Phys. 49(20), 205002. 2016/04/18 (2016). https://doi.org/10.1088/0022-3727/49/20/205002
Şaşmaz, M.: Metamagnetic transition and magnetocaloric properties of Ni45Mn42In13 Heusler alloy. Phase Transitions. 94(5), 289–297. 2021/05/04. (2021). https://doi.org/10.1080/01411594.2021.1931691
Wu, S., et al.: Wear mechanism and tribological characteristics of porous NiTi shape memory alloy for bone scaffold, (in eng). J Biomed Mater Res A 101(9), 2586–2601 (2013). https://doi.org/10.1002/jbm.a.34568
Mokashi, M. S., Dhanal, S. V.: Tribological studies of NiMnAl and NiMnSn magnetic shape memory alloys. Intern. J. Current. Eng. Technol. 7(3), 943–945 (2017)
Yan L., Liu, Y.: Wear behavior of austenitic NiTi shape memory alloy. Shape Memory Superelastic. 1(1), 58–68 (2015). https://doi.org/10.1007/s40830-015-0008-1
Yan, L., Liu, Y.: Effect of temperature on the wear behavior of NiTi shape memory alloy. J. Mater. Res. 30(2), 186–196 (2015). https://doi.org/10.1557/jmr.2014.381
Chowdhurya, S.K.R., Malhotra, K., Padmawar, H.: Effect of contact temperature rise during sliding on the wear resistance of TiNi shape memory alloys. Tribology in Industry 35(1), 84–94 (2013)
Tillmann, W., Momeni, S.: Tribological performance of near equiatomic and Ti-rich NiTi shape memory alloy thin films. Acta Mater. 92
Yang, R., et al.: Tribologically induced amorphization in the subsurface of aged Ni-rich TiNi alloy during dry sliding. Intermetallics 113, 106574 (2019). https://doi.org/10.1016/j.intermet.2019.106574
Figueroa, C. G., Garcia-Castillo, F. N., Jacobo, V. H., Cortés-Pérez, J., Schouwenaars, R.: Microstructural and superficial modification in a Cu-Al-Be shape memory alloy due to superficial severe plastic deformation under sliding wear conditions. IOP Conf. Series: Mater. Sci. Eng. 194, 012011 (2017). https://doi.org/10.1088/1757-899x/194/1/012011
Sharma, P.: NiTi shape memory alloy: physical and tribological characterization. J. Mech. Behav. Mater. 27(1–2) (2018) https://doi.org/10.1515/jmbm-2018-0009
Wang, H., Ren, K., Xie, J., Zhang, C., Tang, W.: Friction and wear behavior of single-phase high-entropy alloy FeCoNiCrMn under MoS2-oil lubrication. Industrial Lubrication and Tribology 72(5), 665–672 (2020). https://doi.org/10.1108/ilt-08-2019-0303
Şaşmaz, S.: The effect of X element on magnetic properties of NiMnX11 (X = In, Sn) Heusler alloys. J. Superconduct. Novel Magnet, 33(10), 3059–3064. 2020/10/01 (2020). https://doi.org/10.1007/s10948-020-05552-9
Vahdettin, K., ÇAY, V. V.: Investigation of wear behavior of Ti6Al4V/B4C composites produced by powder metallurgy. Euro. J. Techn. 10(2), 444–453, (2020)
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Highlights
• The tribological behaviors of NiMnX (X = In and Sn) metamagnetic shape memory alloys which are rarely studied and important issue for their potential of technological applications.
• Microstructural evaluations are highlighted that the alloys fabricated by induction furnace have lower width of the wear track.
• NiMnIn has more resistivity against wearing than NiMnSn.
• Fabrication of the alloys, whether induction furnace or arc melter, changes wear behavior.
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Şaşmaz, M., Koç, V. & Güldal, S. Tribological Studies of NiMnIn and NiMnSn Magnetic Shape Memory Alloys. J Supercond Nov Magn 34, 2923–2931 (2021). https://doi.org/10.1007/s10948-021-06006-6
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DOI: https://doi.org/10.1007/s10948-021-06006-6