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Superconductivity in Perovskite Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ

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Abstract

The perovskites Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ (0.0 ≤ x ≤ 0.07) have been synthesized by traditional solid-state method. They crystallize in P1 space group confirmed by x-ray and rotational electron diffraction data. X-ray photoelectron spectroscopy data indicate that the valences of bismuth are + 3 and + 5, while the valences of lead are + 2 and + 4 in this solid solution. They all show superconductivity. The \(T_{c}^{\text {zero}}\) (the highest temperature at which the sample shows zero electrical resistivity) decreases with an increase of La in the sample.

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (Grant 21771007).

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Authors and Affiliations

  1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, People’s Republic of China

    Attia Firdous, Xiaoge Wang, Muhammad Asim Farid, Yan Wang, Jinling Geng, Junliang Sun, Guobao Li, Fuhui Liao & Jianhua Lin

  2. Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing, 100044, People’s Republic of China

    Meng Zhang

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  1. Attia Firdous
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  2. Xiaoge Wang
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  3. Muhammad Asim Farid
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  5. Yan Wang
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  7. Junliang Sun
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Correspondence to Guobao Li or Jianhua Lin.

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Firdous, A., Wang, X., Farid, M.A. et al. Superconductivity in Perovskite Ba0.85−xLaxPr0.15(Bi0.20Pb0.80)O3−δ. J Supercond Nov Magn 32, 167–173 (2019). https://doi.org/10.1007/s10948-018-4708-6

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  • DOI: https://doi.org/10.1007/s10948-018-4708-6

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