Skip to main content
SpringerLink
Log in

Crystal structure and properties of [M(NH3)5Cl](NO3)2, (M = Ir, Rh, Ru)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structures of compounds from the series [M(NH3)5Cl](NO3)2, (M = Ir, Rh, Ru) were described. The compounds crystallized in the tetragonal crystal system, space group I4, Z = 2. Crystal data for [Ir(NH3)5Cl](NO3)2 (I): a = 7.6061(1) Å, b = 7.6061(1) Å, c = 10.4039(2) Å, V = 601.894(16) Å3, ρcalc = 2.410 g/cm3, R = 0.0087; [Rh(NH3)5Cl](NO3)2 (II): a = 7.5858(5) Å, b = 7.5858(5) Å, c = 10.41357(7) Å, V = 599.24(7) Å3, ρcalc = 1.926 g/cm3, R = 0.0255; [Ru(NH3)5Cl](NO3)2 (III): a = 7.5811(6) Å, b = 7.5811(6) Å, c = 10.5352(14) Å, V = 605.49(11) Å3, ρcalc = 1.896 g/cm3, R = 0.0266. The compounds were defined by IR spectroscopy and XRPA and thermal analyses.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Hambley and P. A. Lay, Inorg. Chem., 25, 4553 (1986).

    Article  CAS  Google Scholar 

  2. I. A. Fedorov, Rhodium [in Russian], Nauka, Moscow (1966).

    Google Scholar 

  3. Yu. V. Shubin, S. V. Korenev, K. V. Yusenko, et al., Izv. Akad. Nauk, Ser. Khim., No. 1, 39 (2002).

  4. S. V. Korenev, A. B. Venediktov, K. V. Yusenko, et al., Koordinats. Khim., 26, No. 7, 541 (2000).

    Google Scholar 

  5. S. A. Martynova, K. V. Yusenko, I. V. Korolkov, and S. A. Gromilov, ibid., 33, No. 5, 381 (2007).

    Google Scholar 

  6. G. M. Sheldrick, SHELX-97, Release 97-1, Univ. Göttingen, Germany (1997).

    Google Scholar 

  7. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York (1997).

    Google Scholar 

  8. M. W. Bee, S. F. A. Kettle, and D. B. Powell, Spectrochim. Acta, 30A, 139 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    P. E. Plyusnin, I. A. Baidina, L. A. Sheludyakova & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    E. Yu. Semitut

Authors
  1. P. E. Plyusnin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Yu. Semitut
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Sheludyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. V. Korenev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. E. Plyusnin.

Additional information

Original Russian Text Copyright © 2009 by P. E. Plyusnin, E. Yu. Semitut, I. A. Baidina, L. A. Sheludyakova, and S. V. Korenev

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 502–507, May–June, 2009.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Plyusnin, P.E., Semitut, E.Y., Baidina, I.A. et al. Crystal structure and properties of [M(NH3)5Cl](NO3)2, (M = Ir, Rh, Ru). J Struct Chem 50, 479–484 (2009). https://doi.org/10.1007/s10947-009-0072-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-009-0072-5

Keywords

Search

Navigation