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Evaluation of piperazine/MIL-101 sorbents for enhanced low-temperature CO2 removal

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Abstract

In the present work, the metal-organic framework MIL-101(Cr) was modified by grafting with piperazine (Pz) in order to enhance the low-temperature CO2 adsorption characteristics. The effect of piperazine loading was studied by varying the percentage of piperazine (0%, 20%, 50%, and 80%). The adsorbent materials were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), N2 adsorption-desorption, and thermogravimetric analysis (TGA). The characterization studies confirmed the successful incorporation of piperazine on MIL-101. The CO2 adsorption kinetics and adsorption isotherms model were investigated at three different temperatures (30 °C, 40 °C, and 50 °C) to better understand the behavior of CO2 adsorption on the synthesized adsorbents. It was found that 50%pz/MIL-101 can enhance CO2 capacity up to 67% compared to bare MIL-101. Furthermore, piperazine grafted on MIL-101 can increase the rate constant and improve the binding energy between CO2 molecules and the surface of adsorbents. The regenerability for CO2 adsorption of pz/MIL-101 had nearly no drop after eight adsorption-desorption cycles. Thus, the pz/MIL-101 provides an excellent opportunity to capture CO2 in industrial applications.

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Acknowledgements

The authors would like to acknowledge financial support through the Canadian Queen Elizabeth II Diamond Jubilee Scholarships (QES), Canada Foundation for Innovation (CFI JELF: 37758), Natrual Sciences and Engineering Research Council of Canada (NSERC DG: RGPIN-2018-03955), and the VPR Curiosity Fund and Engineering ROF at the University of Regina. The authors also extend their gratitude to the Clean Energy Technologies Research Institute (CETRI) for allowing access to their research infrastructure. The views expressed herein are those of the writers and not necessarily those of our research and funding partners.

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Authors and Affiliations

  1. Program for Petrochemical and Polymer Science, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand

    Rachatawan Yaisamlee

  2. Energy and Environment Research Group (EERG), Department of Chemical and Petroleum Engineering, University of Calgary EEEL, 455D 2500 University Drive NW, Calgary, AB, T2N 1N4, Canada

    Mohanned Mohamedali

  3. Process Systems Engineering, Faculty of Engineering and Applied Science, Clean Energy Technologies Research Institute (CETRI), University of Regina, 3737 Wascana Parkway, Regina, S4S 0A2, Canada

    Feysal M. Ali & Hussameldin Ibrahim

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Conceptualization: HI; methodology: RY, MM, HI; software: RY; validation: RY, FA; formal analysis: RY, MM; investigation: RY, FA; resources: HI; data curation: RY, FA, HI; writing—original draft preparation: RY, MM; writing—review and editing: FA, HI; visualization: RY, MM, FA; supervision: HI; project administration: HI; funding acquisition: HI. All authors have read and agreed to the published version of the manuscript.

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Yaisamlee, R., Ali, F.M., Mohamedali, M. et al. Evaluation of piperazine/MIL-101 sorbents for enhanced low-temperature CO2 removal. J Porous Mater 31, 237–249 (2024). https://doi.org/10.1007/s10934-023-01512-5

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