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Introduction of Ni into mesoporous MCM-41: A new recyclable catalyst for the synthesis of 5-substituted 1H-tetrazoles and the selective oxidation of sulfides

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Abstract

The surface of the MCM-41 has been functionalized with 3-chloropropyltrimethoxysilane, which undergoes an SN2 substitution reaction of the chloro group with the nitrogen of ligand (quinoline-2-4-dicarboxylic acid), offering the MCM-41-quinoline-2-4-dicarboxylic acid (MCM-41-QDC’s). A new recyclable Ni attached functionalized mesoporous MCM-41 (MCM-41-QDC’s-Ni) has been produced through a post-synthetic method. This catalyst displays high catalytic performance in the synthesis of 5-substituted 1H-tetrazoles and the selective oxidation of sulfides. This protocol is a greener way toward the synthesis of 5-substituted 1H-tetrazoles and the selective oxidation of sulfides. The main aspects of this economical Ni-catalyzed procedure are green synthesis, slighter experimental conditions, and lesser reaction time with no additives. Further benefits comprise experimental comfort of handling, securer replacement to dangerous, damaging, and poisoning regular Lewis’s acid catalysts. The catalyst can be simply separated by simple recovery and reused for several periods without any remarkable decrease in the catalyst activity and selectivity.

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Acknowledgements

The authors are deeply grateful to the University of Kurdistan for the financial support this research project.

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  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Somayeh Molaei & Mohammad Ghadermazi

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  1. Somayeh Molaei
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  2. Mohammad Ghadermazi
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Correspondence to Mohammad Ghadermazi.

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Molaei, S., Ghadermazi, M. Introduction of Ni into mesoporous MCM-41: A new recyclable catalyst for the synthesis of 5-substituted 1H-tetrazoles and the selective oxidation of sulfides. J Porous Mater 29, 1929–1945 (2022). https://doi.org/10.1007/s10934-022-01270-w

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