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Preparation, characterization, and application of ordered mesoporous S2O82−/ZrO2–SiO2 with high specific surface area

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Abstract

A series of ordered mesoporous S2O82−/ZrO2–SiO2 (OMSZS) solid superacids with different calcination temperatures (400–650 °C) was synthesized using zirconium n-propoxide and tetraethyl orthosilicate as the raw materials and P123 as a structure-directing agent by solvent evaporation-post-dipping method. Transmission electron microscopy and small-angle X-ray diffraction results showed that the OMSZS were all ordered. The nitrogen adsorption results indicated that the specific surface area of OMSZS could reach up to 331–385 m2/g, whereas the average pore diameters were in the range of 3.1–3.2 nm. The pyridine infrared results mainly displayed Lewis acids, and the ammonia (NH3)-temperature programmed desorption characterization showed that the NH3 desorption of the OMSZS calcined at 550 °C was 61 cm3/g STP. The catalytic performance of the OMSZS was investigated by the transesterification reaction of waste frying oil and methanol. The yield of fatty acid methyl ester could reach up to 94% at 200 °C reaction temperature for 6 h. After repeated use for four times, the catalyst still featured good activity and the yield was 78%.

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References

  1. Y. Liu, R. Li, H.J. Sun, R.S. Hua, J. Mol. Catal. A-Chem. 398, 133–139 (2015)

    CAS  Google Scholar 

  2. J.S. Chen, L.B. Yang, W.B. Zhou, L.J. Zhu, Y.L. Zhou, Y.Z. Xiang, D.H. Xia, Energy Fuel 32, 5518–5526 (2018)

    CAS  Google Scholar 

  3. J.Y. Fu, L.G. Chen, P.M. Lv, L.M. Yang, Z.H. Yuan, Fuel 154, 1–8 (2015)

    Google Scholar 

  4. M.Y. Yao, Y.B. Huang, X. Niu, H. Pan, A.C.S. Sustain, Chem. Eng. 4(7), 3840–3849 (2016)

    CAS  Google Scholar 

  5. Q. Zhao, S.M. Meng, J.L. Wang, Z.P. Li, J.H. Liu, Y. Guo, Ceram. Int. 40(10), 16183–16187 (2014)

    CAS  Google Scholar 

  6. Y.H. Gao, Adv. Mater. Res. 919–921, 2105–2108 (2014)

    Google Scholar 

  7. P.A. Alaba, Y.M. Sani, W.M.A.W. Daud, RSC Adv. 6(82), 78351–87836 (2016)

    CAS  Google Scholar 

  8. Y.C. Du, Y.Y. Sun, Y. Di, L. Zhao, S. Liu, F.S. Xiao, J. Porous Mater. 13(2), 163–171 (2006)

    CAS  Google Scholar 

  9. A.A. Kiss, J.G. Segovia-Hernández, C.S. Bildea, E.Y. Miranda-Galindo, S. Hernández, Fuel 95, 352–359 (2012)

    CAS  Google Scholar 

  10. X.M. Luo, P.N. Li, D.Q. Wu, H.J. Ren, Adv. Mater. Res. 291–294, 3311–3317 (2011)

    Google Scholar 

  11. J.H. Wang, C.Y. Mou, Micropor. Mesopor. Mater. 110(2), 260–270 (2008)

    CAS  Google Scholar 

  12. V. Degirmenci, O.F. Erdem, A. Yilmaz, D. Michel, D. Uner, Catal. Lett. 115(1–2), 79–85 (2007)

    CAS  Google Scholar 

  13. C.K. Krishnan, T. Hayashi, M. Ogura, Adv. Mater. 20(11), 2131–2136 (2010)

    Google Scholar 

  14. B.B. Chang, J. Fu, Y.L. Tian, X.P. Dong, Appl. Catal. A Gen. 437–438, 149–154 (2012)

    Google Scholar 

  15. M. Signoretto, A. Breda, F. Somma, F. Pinna, G. Cruciani, Micropor. Mesopor. Mater. 91, 23–32 (2006)

    CAS  Google Scholar 

  16. J.H. Wang, C.Y. Mou, Appl. Catal. A Gen. 286(1), 128–136 (2005)

    CAS  Google Scholar 

  17. H. Pu, L. Zhang, D. Du, C. Han, H. Li, J. Li, Y. Luo, Korean J. Chem. Eng. 29(10), 1285–1288 (2012)

    CAS  Google Scholar 

  18. K.K. Cheralathan, T. Hayashi, M. Ogura, Micropor. Mesopor. Mater. 116(1–3), 406–415 (2008)

    CAS  Google Scholar 

  19. F. Yu, M. Guo, X. Wang, D.H. Pan, R.F. Li, J. Fuel Chem. Technol. 41(4), 456–461 (2013)

    CAS  Google Scholar 

  20. S.J. Liao, L.F. Wang, Z.X. Yang, W.W. Yu, Z.T. Huang, J. South China Univ. Technol. 29(1), 56–60 (2001)

    CAS  Google Scholar 

  21. R. Li, F. Yu, F. Li, M. Zhou, B. Xu, K. Xie, ChemInform. 40(30), 991–994 (2010)

    Google Scholar 

  22. H.Z. Wang, W.Z. Li, J.D. Wang, H.M. Chang, H. Jameel, Q. Zhang, S. Li, L. Jin, RSC Adv. 7(79), 50027–50034 (2017)

    CAS  Google Scholar 

  23. Y.D. Xia, W.M. Hua, Y. Tang, Z. Gao, Chem. Commun. 18, 1899–1900 (1999)

    Google Scholar 

  24. Q.Y. Chu, J. Chen, W.H. Hou, H.X. Yu, P. Wang, R. Liu, G.L. Song, H.J. Zhu, P.P. Zhao, Chin. J. Catal. 39(5), 955–963 (2018)

    CAS  Google Scholar 

  25. Y. Bie, J. Lehtonen, J. Kanervo, Appl. Catal. A Gen. 526, 183–190 (2016)

    CAS  Google Scholar 

  26. H. Tulathammakit, B. Kitiyanan, J. Biotechnol. 185(38), 120–121 (2014)

    Google Scholar 

  27. M.K. Lam, K.T. Lee, Fuel Process Technol. 92, 1639–1645 (2011)

    CAS  Google Scholar 

  28. J. Kansedo, K.T. Lee, Biomass Bioenergy. 40(5), 96–104 (2012)

    CAS  Google Scholar 

  29. Y.J. Wang, H. Yuan, H. Zhang, Res. Chem. Intermed. 45, 1073–1086 (2019)

    CAS  Google Scholar 

  30. P.D. Yang, D.Y. Zhao, D.I. Margolese, B.F. Chmelka, G.D. Stucky, Chem. Mater. 11, 2813–2826 (1999)

    CAS  Google Scholar 

  31. S.A. Bagshaw, E. Prouzet, T.J. Pinnavaia, Science 269(5228), 1242–1244 (1995)

    PubMed  Google Scholar 

  32. Y. Wang, J.H. Ma, D. Liang, M.M. Zhou, F.X. Li, R.F. Li, Mater. Sci. 44(24), 6736–6740 (2009)

    CAS  Google Scholar 

  33. Y. Feng, Z.W. Dong, H.J. Zhang, Catal. Commun. 10(15), 2056–2059 (2009)

    Google Scholar 

  34. A.A. Taromi, S. Kaliaguine, Micropor. Mesopor. Mater. 248, 179–191 (2017)

    Google Scholar 

  35. J. Zhao, Y. Yue, W. Hua, Z. Gao, Catal. Lett. 116(1–2), 27–34 (2007)

    CAS  Google Scholar 

  36. Q.X. Liu, W.C. Xu, Adv. Mater. Res. 512–515, 2428–2433 (2012)

    Google Scholar 

  37. Y.M. Luo, Z.Q. Mei, N.S. Liu, H. Wang, C.Y. Han, S.F. He, Catal. Today. 298, 99–108 (2017)

    CAS  Google Scholar 

  38. Q.H. Xia, K. Hidajat, S. Kawi, J. Catal. 205(2), 318–331 (2002)

    CAS  Google Scholar 

  39. S. Dehghani, M. Haghighi, Ultrason. Sonochem. 35, 142–151 (2017)

    PubMed  CAS  Google Scholar 

  40. M.S.A. Salam, M.A. Betiha, S.A. Shaban, A.M. Elsabagh, R.M.A. El-Aal, F.Y. Elkady, Egypt. J. Petrol. 24(1), 49–57 (2015)

    Google Scholar 

  41. S.M. Sajjadi, M. Haghighi, A.A. Eslami, F. Rahmani, J. Sol-Gel Sci. Technol. 67(3), 601–617 (2013)

    CAS  Google Scholar 

  42. Y. Vafaeian, M. Haghighi, S. Aghamohammadi, Energy Convers. Manag. 76, 1093–1103 (2013)

    CAS  Google Scholar 

  43. L. Y.i Zhang, C. Y. Han, H. Wang, H. P. Pu, D. Q. Du, J. Y. Li , Y. M. Luo, Mater. Res. Bull. 47, 3931–3936 (2012).

  44. S. Allahyari, M. Haghighi, A. Ebadi, Ultrason. Sonochem. 21(2), 663–673 (2014)

    PubMed  CAS  Google Scholar 

  45. J.L. Ropero-Vega, A. Aldana-Pérez, R. Gómez, M.E. Nino-Gómez, Appl. Catal. A Gen. 379(1–2), 24–29 (2010)

    CAS  Google Scholar 

  46. Y.M. Sani, P.A. Alaba, A.O. Raji-Yahya, A.R.A. Aziz, W.M.A.W. Daud, J. Taiwan Inst. Chem. E 60, 247–257 (2016)

    CAS  Google Scholar 

  47. B.T. Loveless, A. Gyanani, D.S. Muggli, Appl. Catal. B Environ. 84(3–4), 591 (2008)

    CAS  Google Scholar 

  48. Y.Y. Sun, L.N. Yuan, W. Wang, C.L. Chen, F.S. Xiao, Catal. Lett. 87(1–2), 57–61 (2003)

    CAS  Google Scholar 

  49. G. Wang, L. Tao, X. Hou, H. Cao, C. Dong, W. Nie, J. Xu, L.Q. Zhang, J. WuHan Univ. Technol. 29(5), 895–899 (2014)

    Google Scholar 

  50. Y. Chen, B.H. Wang, X. Sun, H. Liu, Adv. Mater. Res. 287–290, 1375–1378 (2011)

    Google Scholar 

  51. G.L. Shi, F. Yu, Y. Wang, D.H. Pan, H.G. Wang, R.F. Li, Renew. Energy. 92, 22–29 (2016)

    CAS  Google Scholar 

  52. R.Z. Raia, L.S. da Silva, S.M.P. Marcucci, P.A. Arroyo, Catal. Today. 289(1), 105–114 (2017)

    CAS  Google Scholar 

  53. N. Katada, T. Hatanaka, M. Ota, K. Yamada, K. Okumura, M. Niwa, Appl. Catal. A Gen. 363(1–2), 164–168 (2009)

    CAS  Google Scholar 

  54. C. Cannilla, G. Bonura, E. Rombi, F. Arena, F. Frusteri, Appl. Catal. A Gen. 382(2), 158–166 (2010)

    CAS  Google Scholar 

  55. W. Xie, T. Wang, Fuel Process. Technol. 109, 150–155 (2013)

    CAS  Google Scholar 

  56. Y.M. Sani, P.A. Alaba, A.O. Raji-Yahya, A.R.A. Aziz, W.M.A.W. Daud, J. Taiwan Inst. Chem. E 59(000), 195–204 (2016)

    CAS  Google Scholar 

  57. S.Y. Kim, J.G.G. Jr, D. Galloway, Catal. Today. 63(1), 21–32 (2000)

    CAS  Google Scholar 

Download references

Funding

Financial support for this work from National Natural Science Foundation of China (21962001), Ningxia Scientific and Technological Innovation Leading Personnel Training (KJT2017006), the Key Scientific Research Projects in 2017 at North Minzu University (Grant No. 2017KJ15), Ningxia low-grade resource high value utilization and environmental chemical integration technology innovation team project are gratefully acknowledged, New Catalytic Process in Clean Energy Production (ZDZX201803).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan, 750021, China

    Yunjie Wang, Hong Yuan, Zhi Zhang & Yihu Ke

  2. State Key Laboratory of National Ethnic Affairs Commission Chemical Technology, North Minzu University, Yinchuan, 750021, China

    Hong Yuan & Yihu Ke

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  1. Yunjie Wang
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  2. Hong Yuan
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Correspondence to Hong Yuan or Yihu Ke.

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Wang, Y., Yuan, H., Zhang, Z. et al. Preparation, characterization, and application of ordered mesoporous S2O82−/ZrO2–SiO2 with high specific surface area. J Porous Mater 27, 429–440 (2020). https://doi.org/10.1007/s10934-019-00822-x

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