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Modification of metal organic framework HKUST-1 with CuCl for selective separation of CO/H2 and CO/N2

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Abstract

Separation and recovery of CO from CO, H2, and N2 mixtures is quite imperative, due to the huge demands in chemical industry, aims of human health, and regulations of hydrogen fuel cell techniques. Cu(I) π complexation adsorbents show great potentials for CO adsorption. In this work, the typical MOF, HKUST-1 was modified with CuCl by the monolayer dispersion method for preparation of π complexation adsorbents. The resultant adsorbents were well characterized with XRD, and N2 adsorption−desorption isotherms (− 196 °C). These results suggest that CuCl has been successfully modified on HKUST-1. The CO, H2, and N2 adsorption performance of the adsorbents at 25 °C was tested as well. In addition, CO/H2 and CO/N2 selectivity was predicted by the ideal adsorbed solution theory (IAST). In general, the adsorbents modified with CuCl show better performance than pristine HKUST-1 on the CO separation from CO, H2, and N2 mixtures, including the CO adsorption capacity and the CO/H2, CO/N2 selectivity.

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References

  1. D. Saha, S. Deng, J. Chem. Eng. Data 54, 2245 (2009)

    Article  CAS  Google Scholar 

  2. L. Wang, J.J. Zhao, L.L. Wang, T.Y. Yan, Y.Y. Sun, S.B.B. Zhang, Phys. Chem. Chem. Phys. 13, 21126 (2011)

    Article  CAS  PubMed  Google Scholar 

  3. Y. Huang, Y. Tao, L. He, Y. Duan, J. Xiao, Z. Li, Adsorption 21, 373 (2015)

    Article  CAS  Google Scholar 

  4. S.J. Geier, J.A. Mason, E.D. Bloch, W.L. Queen, M.R. Hudson, C.M. Brown, J.R. Long, Chem. Sci. 4, 2054 (2013)

    Article  CAS  Google Scholar 

  5. Y.B. He, R. Krishna, B.L. Chen, Energy Environ. Sci. 5, 9107 (2012)

    Article  CAS  Google Scholar 

  6. Y. Yin, J. Zhu, X.Q. Liu, P. Tan, D.M. Xue, Z.M. Xing, L.B. Sun, Rsc Adv. 6, 70446 (2016)

    Article  CAS  Google Scholar 

  7. V.F.D. Martins, A.M. Ribeiro, A. Ferreira, U.H. Lee, Y.K. Hwang, J.S. Chang, J.M. Loureiro, A.E. Rodrigues, Sep. Purif. Technol. 149, 445 (2015)

    Article  CAS  Google Scholar 

  8. H.Y. Huang, J. Padin, R.T. Yang, Ind. Eng. Chem. Res. 38, 2720 (1999)

    Article  CAS  Google Scholar 

  9. F. Gao, Y.Q. Wang, X. Wang, S.H. Wang, Rsc Adv. 6, 34439 (2016)

    Article  CAS  Google Scholar 

  10. Y. Xie, N. Bu, J. Liu, G. Yang, J. Qiu, N. Yang, Y. Tang, US 4917711, (1990)

  11. T.C. Golden, W.C. Kratz, F.C. Wilhelm, R. Pierantozzi, A. Rokicki, US 5258571, (1993)

  12. T. Nishida, K. Tajima, Y. Osada, O. Shigyo, H. Taniguchi, US 4743276, (1988)

  13. F. Gao, Y.Q. Wang, S.H. Wang, Chem. Eng. J. 290, 418 (2016)

    Article  CAS  Google Scholar 

  14. J.H. Ma, L. Li, J. Ren, R.F. Li, Sep. Purif. Technol. 76, 89 (2010)

    Article  CAS  Google Scholar 

  15. Y. Yin, P. Tan, X.Q. Liu, J. Zhu, L.B. Sun, J. Mater. Chem. A. 2, 3399 (2014)

    Article  CAS  Google Scholar 

  16. H. Furukawa, K.E. Cordova, M. O’Keeffe, O.M. Yaghi, Science. 341, 974 (2013)

    Article  CAS  Google Scholar 

  17. L.Q. Ma, C. Abney, W.B. Lin, Chem. Soc. Rev. 38, 1248 (2009)

    Article  CAS  PubMed  Google Scholar 

  18. A. Cadiau, K. Adil, P.M. Bhatt, Y. Belmabkhout, M. Eddaoudi, Science. 353, 137 (2016)

    Article  CAS  PubMed  Google Scholar 

  19. X.L. Cui, K.J. Chen, H.B. Xing, Q.W. Yang, R. Krishna, Z.B. Bao, H. Wu, W. Zhou, X.L. Dong, Y. Han, B. Li, Q.L. Ren, M.J. Zaworotko, B.L. Chen, Science. 353, 141 (2016)

    Article  CAS  PubMed  Google Scholar 

  20. J. Zhang, X.Q. Liu, H. Zhou, X.F. Yan, Y.J. Liu, A.H. Yuan, Rsc Adv. 4, 28908 (2014)

    Article  CAS  Google Scholar 

  21. R. Ananthoji, J.F. Eubank, F. Nouar, H. Mouttaki, M. Eddaoudi, J.P. Harmon, J. Mater. Chem. 21, 9587 (2011)

    Article  CAS  Google Scholar 

  22. J. Della Rocca, D.M. Liu, W.B. Lin, Acc. Chem. Res. 44, 957 (2011)

    Article  CAS  PubMed  Google Scholar 

  23. X. Shen, B. Yan, Dalton Trans. 44, 1875 (2015)

    Article  CAS  PubMed  Google Scholar 

  24. J.R. Long, O.M. Yaghi, Chem. Soc. Rev. 38, 1213 (2009)

    Article  CAS  PubMed  Google Scholar 

  25. T. Uemura, N. Yanai, S. Kitagawa, Chem. Soc. Rev. 38, 1228 (2009)

    Article  CAS  PubMed  Google Scholar 

  26. G.G. Chang, Z.B. Bao, Q.L. Ren, S.G. Deng, Z.G. Zhang, B.G. Su, H.B. Xing, Y.W. Yang, Rsc Adv. 4, 20230 (2014)

    Article  CAS  Google Scholar 

  27. Y.M. Zhang, B.Y. Li, R. Krishna, Z.L. Wu, D.X. Ma, Z. Shi, T. Pham, K. Forrest, B. Space, S.Q. Ma, Chem. Commun. 51, 2714 (2015)

    Article  CAS  Google Scholar 

  28. I. Ahmed, S.H. Jhung, Chem. Eng. J. 251, 35 (2014)

    Article  CAS  Google Scholar 

  29. J.X. Qin, P. Tan, Y. Jiang, X.Q. Liu, Q.X. He, L.B. Sun, Green Chem. 18, 3210 (2016)

    Article  CAS  Google Scholar 

  30. N.A. Khan, S.H. Jhung, Angew. Chem. Int. Ed. 51, 1198 (2012)

    Article  CAS  Google Scholar 

  31. J.J. Peng, S.K. Xian, J. Xiao, Y. Huang, Q.B. Xia, H.H. Wang, Z. Li, Chem. Eng. J. 270, 282 (2015)

    Article  CAS  Google Scholar 

  32. Y.C. Xie, Y.Q. Tang, Adv. Catal. 37, 1 (1990)

    CAS  Google Scholar 

  33. Y. Yin, Z.F. Yang, Z.H. Wen, A.H. Yuan, X.Q. Liu, Z.Z. Zhang, H. Zhou, Sci. Rep. 7, 4509 (2017)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  34. W. Zhu, J.M. van de Graaf, L.J.P. van den Broeke, F. Kapteijn, J.A. Moulijn, Ind. Eng. Chem. Res. 37, 1934 (1998)

    Article  CAS  Google Scholar 

  35. J. Chen, L.S. Loo, K. Wang, J. Chem. Eng. Data 56, 1209 (2011)

    Article  CAS  Google Scholar 

  36. Z. Zhang, Z. Li, J. Li, Langmuir. 28, 12122 (2012)

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This work was supported by National Natural Science Foundation of China (51602133), Natural Science Foundation of Jiangsu Province (BK20160555), China Postdoctoral Science Foundation (2015M581750), Jiangsu Planned Projects for Postdoctoral Research Funds (1501114B), Qing Lan Project of Jiangsu Province, State Key Laboratory of Materials-Oriented Chemical Engineering (KL15-13).

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Authors and Affiliations

  1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, China

    Yu Yin, Zhi-Hao Wen & Ai-Hua Yuan

  2. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China

    Xiao-Qin Liu

  3. State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing, 210008, China

    Lei Shi

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  1. Yu Yin
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  2. Zhi-Hao Wen
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Correspondence to Yu Yin, Xiao-Qin Liu or Ai-Hua Yuan.

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Yin, Y., Wen, ZH., Liu, XQ. et al. Modification of metal organic framework HKUST-1 with CuCl for selective separation of CO/H2 and CO/N2. J Porous Mater 25, 1513–1519 (2018). https://doi.org/10.1007/s10934-018-0564-9

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  • DOI: https://doi.org/10.1007/s10934-018-0564-9

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