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CO2 adsorption/regeneration kinetics and regeneration properties of amine functionalized SBA-16

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Abstract

The adsorption/regeneration kinetics of CO2 capture by amine-functionalized SBA-16 was presented to understand the potential mechanism of adsorption of CO2 by adsorption column. Three adsorption kinetic models were used to simulate the isothermal CO2 adsorption data. Based on the value of the correlation coefficient R 2, the fractional order model is considered to be the most suitable model for the CO2 adsorption performance at different temperatures and CO2 concentrations. The results of kinetic analysis show that the adsorption process follows the pseudo second order reaction, and the higher concentration of CO2 or operating temperature will promote the diffusion of CO2 into the adsorbent. Steam stripping and VTSA regeneration were carried out to study the behavior of adsorbent regeneration. Results show that both regeneration methods can achieve rapid regeneration of the adsorbent, and temperature is a major factor in the regeneration of adsorbent due to the chemical bond between CO2 and adsorbents. The Avrami fractional-order models simulates the experimental data well. The absolute value of the activation energy obtained from the Arrhenius equation for CO2 desorption was 59.05 kJ/mol.

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References

  1. M.E. Boot-Handford, J.C. Abanades, E.J. Anthony, M.J. Blunt, S. Brandani, N. Mac Dowell, J.R. Fernández, M.-C. Ferrari, R. Gross, J.P. Hallett, R.S. Haszeldine, P. Heptonstall, A. Lyngfelt, Z. Makuch, E. Mangano, R.T.J. Porter, M. Pourkashanian, G.T. Rochelle, N. Shah, J.G. Yao, P.S. Fennell, Energy Environ. Sci. 7, 130 (2014)

    Article  CAS  Google Scholar 

  2. T.-H. Bae, M.R. Hudson, J.a.. Mason, W.L. Queen, J.J. Dutton, K. Sumida, K.J. Micklash, S.S. Kaye, C.M. Brown, J.R. Long, Energy Environ. Sci. 6, 128 (2013)

    Article  CAS  Google Scholar 

  3. D.M. D’Alessandro, B. Smit, J.R. Long, Angew. Chem. Int. Ed. 49, 6058 (2010)

    Article  CAS  Google Scholar 

  4. Q. Wang, J. Luo, Z. Zhong, A. Borgna, Energy Environ. Sci. 4, 42 (2011)

    Article  CAS  Google Scholar 

  5. A. Zukal, I. Dominguez, J. Mayerová, J. Čejka, Langmuir 25, 10314 (2009)

    Article  CAS  PubMed  Google Scholar 

  6. S. Chen, Y. Fu, Y. Huang, Z. Tao, J. Porous Mater. 23, 713 (2016)

    Article  CAS  Google Scholar 

  7. B. Ma, L. Zhuang, S. Chen, J. Porous Mater. 23, 529 (2016)

    Article  CAS  Google Scholar 

  8. J. Li, M. Hitch, Powder Technol. 291, 408 (2016)

    Article  CAS  Google Scholar 

  9. R. Kishor, A.K. Ghoshal, Ind. Eng. Chem. Res. 56, (2017)

  10. M. Ranjbar, M.A. Taher, A. Sam, J. Porous Mater. 23, 375 (2016)

    Article  CAS  Google Scholar 

  11. K. Sumida, D.L. Rogow, J.A. Mason, T.M. Mcdonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R. Long, Chem. Rev. 112, 724 (2012)

    Article  CAS  PubMed  Google Scholar 

  12. Y. Jing, L. Wei, Y. Wang, Y. Yu, Microporous Mesoporous Mater. 183, 124 (2014)

    Article  CAS  Google Scholar 

  13. C. Chen, Y.R. Lee, W.S. Ahn, J. Nanosci. Nanotechnol. 16, 4291 (2016)

    Article  CAS  PubMed  Google Scholar 

  14. A.E. Creamer, B. Gao, Environ. Sci. Technol. 50, 7276 (2016)

    Article  CAS  PubMed  Google Scholar 

  15. Y.C. Chiang, R.S. Juang, J. Taiwan Inst. Chem. Eng. 71, (2016)

  16. Y. Liu, Y. Chen, L. Tian, R. Hu, J. Porous Mater. 24, 583 (2017)

    Article  Google Scholar 

  17. M.K.R. Reddy, Z.P. Xu, G.Q. Lu, J.C.D. Da Costa, Ind. Eng. Chem. Res. 45, 7504 (2006)

    Article  CAS  Google Scholar 

  18. D.V. Quang, A. Dindi, A.V. Rayer, N. El Hadri, A. Abdulkadir, M.R.M. Abu-Zahra, Greenh. Gases Sci. Technol. 5, 91 (2015)

    Article  CAS  Google Scholar 

  19. D.V. Quang, N. El Hadri, M.R.M. Abu-zahra, Eur. Sci. J. 9, 82 (2013)

    Google Scholar 

  20. G. Evano, Angew. Chem. Int. Ed. 49, 6025 (2010)

    Article  CAS  Google Scholar 

  21. E.E. Ünveren, B.Ö. Monkul, Ş. Sarıoğlan, N. Karademir, E. Alper, Petroleum 3, 37 (2016)

    Article  Google Scholar 

  22. P. Bollini, S.A. Didas, C.W. Jones, J. Mater. Chem. 21, 15100 (2011)

    Article  CAS  Google Scholar 

  23. R. Serna-Guerrero, A. Sayari, Chem. Eng. J. 161, 182 (2010)

    Article  CAS  Google Scholar 

  24. A. Samanta, A. Zhao, G.K.H. Shimizu, P. Sarkar, R. Gupta, Ind. Eng. Chem. Res. 51, 1438 (2012)

    Article  CAS  Google Scholar 

  25. Y. Liu, X. Lin, X. Wu, M. Liu, R. Shi, X. Yu, Powder Technol. 318, 186 (2017)

    Article  CAS  Google Scholar 

  26. W. Li, S. Choi, J. Drese, M. Hornbostel, G. Krishnan, P. Eisenberger, C. Jones, ChemSusChem 3, 899 (2010)

    Article  CAS  PubMed  Google Scholar 

  27. Y. Liu, Q. Ye, M. Shen, J. Shi, J. Chen, H. Pan, Y. Shi, Environ. Sci. Technol. 45, 5710 (2011)

    Article  CAS  PubMed  Google Scholar 

  28. L. Ecn, D.A. Fsc, V. Efs, A.R. Cestari, J. Colloid Interface Sci. 263, 542 (2003)

    Article  CAS  Google Scholar 

  29. I. Kinefuchi, H. Yamaguchi, Y. Sakiyama, S. Takagi, Y. Matsumoto, J. Chem. Phys. 128, 164712 (2008)

    Article  CAS  PubMed  Google Scholar 

  30. Q. Liu, J. Shi, S. Zheng, M. Tao, H. Yi, S. Yao, Ind. Eng. Chem. Res. 53, 11677 (2014)

    Article  CAS  Google Scholar 

  31. S. Sircar, J.R. Hufton, Adsorption 6, 137 (2000)

    Article  CAS  Google Scholar 

  32. A. Heydari-Gorji, A. Sayari, Chem. Eng. J. 173, 72 (2011)

    Article  CAS  Google Scholar 

  33. X. Xu, C. Song, J.M. Andresen, B.G. Miller, A.W. Scaroni, Energy Fuels 16, 1463 (2002)

    Article  CAS  Google Scholar 

  34. X. Xu, C. Song, B.G. Miller, A.W. Scaroni, Ind. Eng. Chem. Res. 44, 8113 (2005)

    Article  CAS  Google Scholar 

  35. J.C. Hicks, J.H. Drese, D.J. Fauth, M.L. Gray, G. Qi, C.W. Jones, J. Am. Chem. Soc. 130, 2902 (2008)

    Article  CAS  PubMed  Google Scholar 

  36. M. Avrami, J. Chem. Phys. 7, 1103 (1939)

    Article  CAS  Google Scholar 

  37. Z. Sun, M. Fan, M. Argyle, Energy Fuels 25, 2988 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We gratefully acknowledge the financial support of the Science Foundation of Fujian Province (Grant Nos. 2015J01033, 2017J01472, 2017 J01568), the Scientific Research Foundation of the Fujian University of Technology (Grant No. GY-Z11045), and the Science Foundation of Fuzhou (Grant No. GY-Z17059).

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Authors and Affiliations

  1. School of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou, 350118, Fujian, People’s Republic of China

    Xiaohang Wu, Minyi Liu, Ronghui Shi, Xiaojing Yu & Yamin Liu

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  1. Xiaohang Wu
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  2. Minyi Liu
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  3. Ronghui Shi
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  4. Xiaojing Yu
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Correspondence to Xiaohang Wu.

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Wu, X., Liu, M., Shi, R. et al. CO2 adsorption/regeneration kinetics and regeneration properties of amine functionalized SBA-16. J Porous Mater 25, 1219–1227 (2018). https://doi.org/10.1007/s10934-017-0532-9

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