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Synthesis and characterization of Copper (II) Schiff base complex containing MCM-41 as robust and clean nano reactor catalyst for the selective oxidation of sulfides to sulfoxides using H2O2

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Abstract

An efficient and versatile procedure has been introduced for the preparation of copper supported on functionalized mesoporous silica (MCM-41) containing chelating Schiff base salen (the structure of this functionalized silica complex was studied by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, thermo gravimetric analysis and N2 adsorption and desorption), which has been applied as catalyst for the conversion of various sulfides into sulfoxides with aqueous hydrogen peroxide. Also this heterogeneous catalyst can be recovered easily and reused many times for the oxidation of sulfides without significant loss of activity and selectivity.

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Acknowledgments

Authors thank the research facilities of Ilam University, Ilam, Iran, for financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, 69315516, Ilam, Iran

    Houri Mahdavi, Mohsen Nikoorazm & Arash Ghorbani-Choghamarani

  2. Payam Noor University, Behshahr Branch, Behshahr, Iran

    Sattar Arshadi

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  1. Houri Mahdavi
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  2. Mohsen Nikoorazm
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  3. Arash Ghorbani-Choghamarani
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  4. Sattar Arshadi
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Correspondence to Mohsen Nikoorazm.

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Mahdavi, H., Nikoorazm, M., Ghorbani-Choghamarani, A. et al. Synthesis and characterization of Copper (II) Schiff base complex containing MCM-41 as robust and clean nano reactor catalyst for the selective oxidation of sulfides to sulfoxides using H2O2 . J Porous Mater 23, 75–82 (2016). https://doi.org/10.1007/s10934-015-0057-z

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