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Effect of p-aminobenzoic acid on synthesizing ordered mesoporous alumina via the sol–gel method

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Abstract

Ordered mesoporous alumina (OMA) samples were prepared via the sol–gel method. The triblock copolymer P123 and aluminum isopropoxide were chose as the template and aluminum source, respectively. The p-aminobenzoic acid (PABA) worked as both the interfacial protector and the assisted template. Different techniques, including X-ray diffractions, N2 physisorption measurement and transmission electron microscope, were employed to study the structural properties of the prepared samples. The results showed that the mesostructure ordering and specific surface area of the samples highly depend on the quantity of the added PABA. The samples after calcinated at 800 °C with the n(PABA)/n(Al3+) molar ratio lying in 0.30 exhibited high specific surface areas (301 m2 g−1) and retained an ordered mesostructures. It was indicated that the carboxyl groups of PABA have multiple functions in the formation of OMA with a long-range ordering and high specific surface area. The carboxyl groups of PABA can slow down the hydrolysis-condensation reaction of aluminum isopropoxide, reduce the influence of chloride ions on self-assembly process. The amino groups of PABA can also react with the hydrogen ions to form quaternary ammonium salt, which can neutralize the charges of the chloride ions, protect the balance of inorganic–organic interface, further to improve the mesostructure ordering and specific surface area of the prepared OMA.

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References

  1. C.M.A. Parlett, L.J. Durndell, K. Wilson, D.W. Bruce, N.S. Hondow, A.F. Lee, Selective oxidation of allylic alcohols over highly ordered Pd/meso-Al2O3 catalysts. Catal. Commun. 44(10), 40–45 (2014)

    Article  CAS  Google Scholar 

  2. S. Ghosh, M.K. Naskar, Understanding the role of triblock copolymers for the synthesis of mesoporous alumina, and its adsorption efficiency for Congo red. J. Am. Ceram. Soc. 97(1), 100–106 (2014)

    Article  CAS  Google Scholar 

  3. T. Niu, L.M. Shen, Y. Liu, Preparation of meso-macroporous a-alumina using carbon nanotube as the template for the mesopore and their application to the preferential oxidation of CO in H2-rich gases. J. Porous Mater. 20, 789–798 (2013)

    Article  CAS  Google Scholar 

  4. J. Moreau, O. Delpoux, E. Devers, M. Digne, S. Loridant, Impregnation of decamolybdocobaltate heteropolyanions over gamma-Alumina: detailed description of the physico-chemical phenomena. Langmuir 29(1), 207–215 (2013)

    Article  CAS  Google Scholar 

  5. Q. Yuan, H.H. Duan, L.L. Li, Z.X. Li, W.T. Duan, L.S. Zhang, W.G. Song, C.H. Yan, Homogeneously dispersed ceria nanocatalyst stabilized with ordered mesoporous alumina. Adv. Mater. 22(13), 1475–1478 (2010)

    Article  CAS  Google Scholar 

  6. Z.X. Li, F.B. Shi, L.L. Li, T. Zhang, C.H. Yan, A facile route to ordered mesoporous-alumina-supported catalysts, and their catalytic activities for CO oxidation. Phys. Chem. Chem. Phys. 13(7), 2488–2491 (2011)

    Article  CAS  Google Scholar 

  7. A.R. Passos, L. Martins, S.H. Pulcinelli, C.V. Santilli, Design of hierarchical porous aluminas by using one-pot synthesis and different calcination temperatures. J. Sol–Gel Sci. Technol. 63(2), 242–250 (2012)

    Article  CAS  Google Scholar 

  8. D. Gu, F. Schuth, Synthesis of non-siliceous mesoporous oxides. Chem. Soc. Rev. 43(1), 313–344 (2014)

    Article  CAS  Google Scholar 

  9. Q. Liu, A.Q. Wang, X.D. Wang, T. Zhang, Ordered crystalline alumina molecular sieves synthesized via a nanocasting route. Chem. Mater. 18(22), 5153–5155 (2006)

    Article  CAS  Google Scholar 

  10. Q. Liu, A.Q. Wang, J.M. Xu, Y.H. Zhang, X.D. Wang, T. Zhang, Preparation of ordered mesoporous crystalline alumina replicated by mesoporous carbon. Microporous Mesoporous Mater. 116(1–3), 461–468 (2008)

    Article  CAS  Google Scholar 

  11. Z.X. Wu, Q. Li, D. Feng, P.A. Webley, D.Y. Zhao, Ordered mesoporous crystalline gamma-Al2O3 with variable architecture and porosity from a single hard template. J. Am. Chem. Soc. 132(34), 12042–12050 (2010)

    Article  CAS  Google Scholar 

  12. S. Haffer, C. Weinberger, M. Tiemann, Mesoporous Al2O3 by nanocasting: relationship between crystallinity and mesoscopic order. Eur. J. Inorg. Chem. 20, 3283–3288 (2012)

    Article  Google Scholar 

  13. K. Niesz, P.D. Yang, G.A. Somorjai, Sol–gel synthesis of ordered mesoporous alumina. Chem. Commun. 15, 1986–1987 (2005)

    Article  Google Scholar 

  14. Q. Yuan, A.X. Yin, C. Luo, L.D. Sun, Y.W. Zhang, W.T. Duan, H.C. Liu, C.H. Yan, Facile synthesis for ordered mesoporous gamma-aluminas with high thermal stability. J. Am. Chem. Soc. 130(11), 3465–3472 (2008)

    Article  CAS  Google Scholar 

  15. W.Q. Cai, J.G. Yu, M. Jaroniec, Effect of nonionic structure-directing agents on adsorption and structural properties of mesoporous alumina. J. Mater. Chem. 21(25), 9066–9072 (2011)

    Article  CAS  Google Scholar 

  16. B. Naik, V.S. Prasad, N.N. Ghosh, Development of a simple aqueous solution based chemical method for synthesis of mesoporous c-alumina powders with disordered pore structure. J. Porous Mater. 17, 115–121 (2010)

    Article  CAS  Google Scholar 

  17. K.S. Choudhari, P. Sudheendra, N.K. Udayashankar, Fabrication and high-temperature structural characterization study of porous anodic alumina membranes. J. Porous Mater. 19, 1053–1062 (2012)

    Article  CAS  Google Scholar 

  18. Z. Hajdúchová, L. Pach, J. Kozánková, J. Lokaj, Polyhedral alumina foam. J. Porous Mater. 20, 595–600 (2013)

    Article  Google Scholar 

  19. X.Y. Yuan, S. Xu, J.W. Lue, X.B. Yan, L.T. Hu, Q.J. Xue, Facile synthesis of ordered mesoporous gamma-alumina monoliths via polymerization-based gel-casting. Microporous Mesoporous Mater. 138(1–3), 40–44 (2011)

    Article  CAS  Google Scholar 

  20. S.M. Morris, P.F. Fulvio, M. Jaroniec, Ordered mesoporous alumina-supported metal oxides. J. Am. Chem. Soc. 130(45), 15210–15216 (2008)

    Article  CAS  Google Scholar 

  21. L.B. Sun, X.L. Wu, W.J. Jiang, X.Q. Liu, Generalized syntheses of mesoporous c-Al2O3 functionalized with metal oxides by a one-pot, two-step strategy. J. Porous Mater. 19, 969–977 (2012)

    Article  CAS  Google Scholar 

  22. S.M. Grant, M. Jaroniec, Effect of acid concentration on pore size in polymer-templated mesoporous alumina. J. Mater. Chem. 22(1), 86–92 (2012)

    Article  CAS  Google Scholar 

  23. K.L. Martena, S.M. Grant, M. Jaroniec, Poly(ethylene oxide)–poly(butylene oxide)–poly(ethylene oxide)-templated synthesis of mesoporous alumina: effect of triblock copolymer and acid concentration. ACS Appl. Mater. Interfaces 4, 3738–3744 (2012)

    Article  Google Scholar 

  24. G.L. Teoh, K.Y. Liew, W.A.K. Mahmood, Synthesis and characterization of sol–gel alumina nanofibers. J. Sol–Gel Sci. Technol. 44(3), 177–186 (2007)

    Article  CAS  Google Scholar 

  25. V.V. Vinogradov, A.V. Agafonov, A.V. Vinogradov, T.I. Gulyaeva, V.A. Drozdov, V.A. Likholobov, Sol–gel synthesis, characterization and catalytic activity of mesoporous gamma-alumina prepared from boehmite sol by different methods. J. Sol–Gel Sci. Technol. 56(3), 333–339 (2010)

    Article  CAS  Google Scholar 

  26. Q.L. Wu, F. Zhang, J.P. Yang, Q. Li, B. Tu, D.Y. Zhao, Synthesis of ordered mesoporous alumina with large pore sizes and hierarchical structure. Microporous Mesoporous Mater. 143(2–3), 406–412 (2011)

    Article  CAS  Google Scholar 

  27. A. Mitra, D. Jana, G. De, Facile synthesis of hexagonally ordered mesoporous aluminum oxide thin films with high catalytic activity. Microporous Mesoporous Mater. 158, 187–194 (2012)

    Article  CAS  Google Scholar 

  28. W.Q. Cai, J.G. Yu, C. Anand, A. Vinu, M. Jaroniec, Facile synthesis of ordered mesoporous alumina and alumina-supported metal oxides with tailored adsorption and framework properties. Chem. Mater. 23(5), 1147–1157 (2011)

    Article  CAS  Google Scholar 

  29. L.L. Pérez, S. Perdriau, G. Brink, B.J. Kooi, H.J. Heeres, I. Melián-Cabrera, Stabilization of self-assembled alumina mesophases. Chem. Mater. 25(6), 848–855 (2013)

    Article  Google Scholar 

  30. D.H. Pan, P. Yuan, L.Z. Zhao, N. Liu, L. Zhou, G.F. Wei, J. Zhang, Y.C. Ling, Y. Fan, B.Y. Wei, H.Y. Liu, C.Z. Yu, X.J. Bao, New understanding and simple approach to synthesize highly hydrothermally stable and ordered mesoporous materials. Chem. Mater. 21(22), 5413–5425 (2009)

    Article  CAS  Google Scholar 

  31. F. Huang, Y. Zheng, G.H. Cai, Y. Zheng, Y.H. Xiao, K.M. Wei, A new synthetic procedure for ordered mesoporous gamma-alumina with a large surface area. Scr. Mater. 63(3), 339–342 (2010)

    Article  CAS  Google Scholar 

  32. F. Huang, Y. Zheng, Y.H. Xiao, Y. Zheng, G.H. Cai, K.M. Wei, A new synthetic procedure for ordered mesoporous gamma-alumina using phthalic acid as an interfacial protector. Mater. Lett. 65(2), 244–246 (2011)

    Article  CAS  Google Scholar 

  33. F. Huang, Y. Zheng, Z.H. Li, Y.H. Xiao, Y. Zheng, G.H. Cai, K.M. Wei, Synthesis of highly dispersed ceria–zirconia supported on ordered mesoporous alumina. Chem. Commun. 47, 5247–5249 (2011)

    Article  CAS  Google Scholar 

  34. Q.P. Sun, Y. Zheng, Z.H. Li, Y. Zheng, Y.H. Xiao, G.H. Cai, Synthesis of ordered mesoporous gamma-alumina influenced by the interfacial protector. Mater. Lett. 84, 44–47 (2012)

    Article  CAS  Google Scholar 

  35. S.J. Gregg, K.S.W. Sing, Adsorption, surface area and porosity, 2nd edn. (Academic Press, London, 1997)

    Google Scholar 

  36. X.F. Shang, X.G. Wang, W.X. Nie, X.F. Guo, X.J. Zou, W.Z. Ding, X.G. Lu, Facile strategy for synthesis of mesoporous crystalline gamma-alumina by partially hydrolyzing aluminum nitrate solution. J. Mater. Chem. 22(45), 23806–23814 (2012)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is supported by the National Natural Science Foundation of China (51103025), the Natural Science Foundation of Fujian Province of China (No. 2014J01032, 2014J01031), the foundation of Fujian Normal University for excellent young teacher (fjsdky2012006).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Fujian Normal University, Fuzhou, 350007, China

    Xue-Lin Zheng, Qian-Ping Sun, Fang Liu, Ying Zheng & Jia-Bao Weng

  2. Fujian Key Laboratory of Polymer Materials, Fuzhou, 350007, China

    Xue-Lin Zheng

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  1. Xue-Lin Zheng
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  2. Qian-Ping Sun
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Correspondence to Ying Zheng.

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Zheng, XL., Sun, QP., Liu, F. et al. Effect of p-aminobenzoic acid on synthesizing ordered mesoporous alumina via the sol–gel method. J Porous Mater 21, 819–825 (2014). https://doi.org/10.1007/s10934-014-9830-7

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