Skip to main content
SpringerLink
Log in

Optimized Removal of Acid Blue 62 from Textile Waste Water by SBA-15/PAMAM Dendrimer Hybrid Using Response Surface Methodology

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

SBA-15/PAMAM Nano adsorbent was synthesized by the proficiency of SBA-15 as an original compound, 3-chloropropyltrimethoxysilane as a bridge chemical compound and polyamidoamine dendrimer (PAMAM) in the role of a multifunctional amine end group for adsorption of acid blue 62 (AB62) from aqueous media. The synthesized adsorbent was characterized by transmission electron microscope, field emission scanning electron microscope and Fourier-transform infrared spectroscope. A response surface methodology was employed to evaluate the simple and amalgamated factors of the operating variables subtending initial pH (2–12), adsorbent dosage(0.01–0.03 g), contact time (5–120 min), initial dye concentration (40–600 ppm) and temperature (25–45 °C) to optimize the operating statues of the treatment method. These parameters were altered at five levels pursuant to the central composite design to appraise their effects on AB62 removal through analysis of variance. Analysis of variance represented a high coefficient of definition amount (R2 = 0.9999) and acceptable prediction quadratic polynomial model was concluded which ascertain the suitability of the model and a high correlation among the predicted and empirical amounts. Utmost color removal efficiency was auspicated and empirically accredited. The optimum conditions relied on acquired results for AB62 removal were at an initial pH of 2, adsorbent dosage of 0.03 g SBA-15/PAMAM, dye concentration of 40 mg l−1, time contact of 60 min and temperature of 25 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. Verma AK, Dash R, Bhunia P (2012) Review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J Environ Manage 93: 154–168

    Article  CAS  Google Scholar 

  2. Huang CH, Chang KP, Ou HD, et.al (2011) Adsorption of cationic dyes onto mesoporous silica. Microporous Mesoporous Mater 14: 102–109

    Article  Google Scholar 

  3. Orfao JJM, Silva AIM, Pereira JCV, et al (2006) Adsorption of a reactive dye on chemically modified activated carbons—influence of pH. J Colloid Interface Sci 296:480–489

    Article  CAS  Google Scholar 

  4. Demirbas A (2009) Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review. J Hazard Mater 167:1–9

    Article  CAS  Google Scholar 

  5. Kannan C, Muthuraja K, Devi MR (2013) Hazardous dyes removal from aqueous solution over mesoporous alumina phosphate with textural porosity by adsorption. J Hazard Mater 10:244–245

    Google Scholar 

  6. Ngai EWT, To CKM, Ching VSM, et al (2012) Development of the conceptual model of energy and utility management in textile processing: a soft systems approach. Int J Prod Econ 135:607–617

    Article  Google Scholar 

  7. Huang CH, Chang KP, Ou HD, et al (2011) Characterization and application of Ti-containing mesoporous silica for dye removal with synergistic effect of coupled adsorption and photo catalytic oxidation. J Hazard Mater 186:174–1182

    Google Scholar 

  8. Faria P, Orfao J, Pereira M (2004) Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res 38:2043–2052

    Article  CAS  Google Scholar 

  9. Baskaralingam P, Pulikesi M, Ramamurthi V, et al (2006) Equilibrium studies for the adsorption of Acid dye onto modified hectorite. J Hazard Mater 136:989–992

    Article  CAS  Google Scholar 

  10. Bechtold T, Burtscher E, Turcanu A (2001) Cathodic decolourisation of textile waste water containing reactive dyes using a multi-cathode electrolyser. J Chem Technol Biotechnol 76:303–311

    Article  CAS  Google Scholar 

  11. Hachem C, Bocquillon F, Zahraa O, et al (2001) Decolourization of textile industry wastewater by the photocatalytic degradation process. Dyes and Pigments 49: 117–125

    Article  CAS  Google Scholar 

  12. Papic S, Koprivanac N, Bozic AL, et al (2004) Removal of some reactive dyes from synthetic wastewater by combined Al(III) coagulation/carbon adsorption process. Dyes and Pigments 62:291–298

    Article  CAS  Google Scholar 

  13. Mahmoodi NM (2013) Photocatalytic ozonation of dyes using multiwalled carbon nanotube. J Mol Catal A Chem 366:254–260

    Article  CAS  Google Scholar 

  14. Ali l, Gupta VK (2006) Advances in water treatment by adsorption technology. Nat Protoc 1:2661–2667

    Article  CAS  Google Scholar 

  15. Ali l (2010) The quest for active carbon adsorbent substitutes: inexpensive adsorbents for toxic metal ions removal from wastewater. Sepn Purif Rev 39:95–171

    Article  CAS  Google Scholar 

  16. Ali l (2012) New generation adsorbents for water treatment. Chem Rev 112:5073–5091

    Article  CAS  Google Scholar 

  17. Ali l (2012) Low cost adsorbents for removal of organic pollutants from wastewater. J Environ Manag 113:170–183

    Article  CAS  Google Scholar 

  18. Ali l (2014) Water treatment by adsorption columns: evaluation at ground level. Sepn Purif Rev 43:175–205

    Article  CAS  Google Scholar 

  19. Sadeghi-Kiakhani M, Arami M, Gharanjig K (2013) Dye removal from colored-textile wastewater using chitosan-PPI dendrimer hybrid as a biopolymer: optimization, kinetic, and isotherm studies. J Appl Polym Sci 127:2607–2619

    Article  CAS  Google Scholar 

  20. Zarezadeh-Mehrizi M, Badiei A (2014) Highly efficient removal of basic blue 41 with nano porous silica. Water Res Ind 5:49–57

    Article  Google Scholar 

  21. Kresge CT, Leonowicz ME, Roth WJ, et al (1992) Ordered mesoporous molecular sieves tailored using different synthesis conditions. Nature 359:710–713

    Article  CAS  Google Scholar 

  22. Taguchi A, Schuth F (2005) Ordered mesoporous materials in catalysis. Microporous Mesoporous Mater 77:1–45

    Article  CAS  Google Scholar 

  23. Stein A, Melde BJ, Schroden RC (2000) Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age. Adv Mater 12:1403–1419

    Article  CAS  Google Scholar 

  24. Vinu A, Hossain KZ, Ariga K (2005) Recent advances in functionalization of mesoporous silica. J Nanosci Nanotechnol 5:347–371

    Article  CAS  Google Scholar 

  25. Blencowe A, Tan JF, Goh TK, et al (2009) Core crosslinked star polymers via controlled radical polymerization. Polymer 50:5–32

    Article  CAS  Google Scholar 

  26. Jiang Y, Gao Q (2006) Heterogeneous hydrogenation catalyses over recyclable Pd(0) nanoparticle catalysts stabilized by PAMAM-SBA-15 organic–inorganic hybrid composites. J Am Chem Soc 128:716–717

    Article  CAS  Google Scholar 

  27. Pisal D, Yellepeddi V, Kumar A, et al (2008) Permeability of surface-modified polyamidoamine (PAMAM) dendrimers across Caco-2 cell monolayers. Int J Pharm 350:113–121

    Article  CAS  Google Scholar 

  28. Kovvali S, Sirkar K (2001) Dendrimer liquid membranes: CO2 separation from gas mixture. Ind Eng Chem Res 40:2502–2511

    Article  CAS  Google Scholar 

  29. Kouketsu T, Duan S, Kai T, et al (2007) PAMAM dendrimer composite membrane for CO2 separation: formation of a chitosan gutter layer. J Membr Sci 287:51–59

    Article  CAS  Google Scholar 

  30. Zhang W, Simanek EE (2000) Dendrimers based on melamine, divergent and orthogonal, convergent syntheses of a G3 dendrimer. Org Lett 2:843–845

    Article  CAS  Google Scholar 

  31. Aguado J, Arsuaga JM, Arencibia A, et al (2009) Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica. J Hazard Mater 163:213–221

    Article  CAS  Google Scholar 

  32. Vasiliev AN, Golovko LV, Trachevsky GS, et al (2009) Adsorption of heavy metal cations by organic ligands grafted on porous materials. Microporous Mesoporous Mater 118:251–257

    Article  CAS  Google Scholar 

  33. Zhang L, Yu C, Zhao W, et al (2007) Preparation of multiamine-grafted mesoporous silicas and their application to heavy metal ions adsorption. J Non-Cryst Solids 353:4055–4061

    Article  CAS  Google Scholar 

  34. Jiang Y, Gao Q, Yu H, et al (2007) Intensively competitive adsorption for heavy metal ions by PAMAM-SBA-15 and EDTA–PAMAM–SBA-15 inorganic-organic hybrid materials. Microporous Mesoporous Mater 103:316–324

    Article  CAS  Google Scholar 

  35. Bouchemal N, Azoudj Y, Merzougui Z, et al (2012) Adsorption modeling of orange G dye on mesoporous activated carbon prepared from Algerian date pits using experimental designs. Desalination Water Treat 45:284–290

    Article  CAS  Google Scholar 

  36. Zhao D, Huo Q, Stucky G, et al (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036

    Article  CAS  Google Scholar 

  37. Bagheryan Z, Jahan-Bakhsh R, Ojani R, et al (2014) Development of a new biosensor based on functionalized SBA-15 modified screen-printed graphite electrode as a nano-reactor for Gquadruplex recognition. Talanta 119:24–38

    Article  CAS  Google Scholar 

  38. Bhagiyalakshmi M, Yun LJ, Anuradha R, et al (2010) Utilization of rice husk ash as silica source for the synthesis of mesoporoussilicas and their application to CO2 adsorption through TREN/TEPA grafting. J Hazard Mater 175:928–938

    Article  CAS  Google Scholar 

  39. Cheng Q, Pavlinek V, Li C, et al (2006) Synthesis and characterization of new mesoporous material with conducting polypyrrole confined in mesoporous silica. Mater Chem Phys 98:504–508

    Article  CAS  Google Scholar 

  40. Cao J, Wu Y, Jin Y, et al (2014) Response surface methodology approach for optimization of the removal of chromium(VI) by NH2-MCM-41. J Taiwan Inst Chem Eng 45:860–868

    Article  CAS  Google Scholar 

  41. Lim CL, Morad N, Teng TT, et al (2011) Chemical oxygen demand (COD) reduction of a reactive dye wastewater using H2O2/pyridine/Cu(II) system. Desalination Water Treat 278:26–30

    CAS  Google Scholar 

  42. Moghaddam SS, Alavi Moghaddam MR, Arami M (2011) Response surface optimization of acid red 119 dye from simulated wastewater using Al based waterworks sludge and polyaluminium chloride as coagulant. J Environ Manag 92:1284–1291

    Article  Google Scholar 

  43. Rauf MA, Marzouki N, Körbahti BK (2008) Photolytic decolorization of Rose Bengal by UV/H2O2 and data optimization using response surface method. J Hazard Mater 159:602–609

    Article  CAS  Google Scholar 

  44. Brereton RG (2003) Chemometrics: data analysis for the laboratory and chemical plant. Wiley, New York

    Book  Google Scholar 

  45. Hamzeh Y, Azadeh E, Izadyar S (2011) Removal of reactive Remazol Black B from contaminated water by lignocellulose waste of canola stalks. J Color Sci Technol 5:77–85

    Google Scholar 

  46. Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465

    Article  CAS  Google Scholar 

  47. Guaracho VV, Kaminari NMS, Ponte MJJS, et al (2009) Central composite experimental design applied to removal of lead and nickel from sand. J Hazard Mater 172:1087–1092

    Article  CAS  Google Scholar 

  48. Olmez-Hanci T, Kartal Z, Arslan-Alaton I (2012) Electrocoagulation of commercial naphthalene sulfonates: process optimization and assessment of implementation potential. J Environ Manag 99:44–51

    Article  CAS  Google Scholar 

  49. Zhang Z, Zheng H (2009) Optimization for decolorization of azo dye acid green 20 by ultrasound and H2O2 using response surface methodology. J Hazard Mater 172:1388–1393

    Article  CAS  Google Scholar 

  50. Kayan B, Gözmen B (2012) Degradation of Acid red 274 using H2O2 in subcritical water: application of response surface methodology. J Hazard Mater 201–202:100–106

    Article  Google Scholar 

  51. Annadurai G (2002) Adsorption of basic dye on strongly chelating polymer: batch kinetics studies. Iran Polym J 11:237–244

    CAS  Google Scholar 

  52. Crini G, Gimbert F, Robert C, et al (2008) The removal of Basic blue 3 from aqueous solutions by chitosan-based adsorbent: batch studies. J Hazard Mater 153:96–106

    Article  CAS  Google Scholar 

  53. Zonoozi MH, Alavi Moghaddam MR, Arami M (2008) Removal of acid red 398 dye from aqueous solutions by coagulation/flocculation process. Environ Eng Manag J 7:695–699

    CAS  Google Scholar 

  54. Chiou MS, Li HY (2003) Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads. Chemosphere 50:1095–1105

    Article  CAS  Google Scholar 

  55. Alley ER (2000) Water quality control handbook. McGraw-Hill, London

    Google Scholar 

  56. Yoshida H, Okamoto A, Kataoka T (1993) Adsorption of acid dye on cross-linked chitosan fibers: equilibria. Chem Eng Sci 48:2267–2272

    Article  CAS  Google Scholar 

  57. Wang S, Ng CW, Wang W, et al (2012) A comparative study on the adsorption of acid and reactive dyes on multiwall carbon nanotubes in single and binary dye systems. J Chem Eng Data 57:1563–1569

    Article  CAS  Google Scholar 

  58. Sun D, Zhang X, Wu Y, et al (2010) Adsorption of anionic dyes from aqueous solution on fly ash. J Hazard Mater 181:335–342

    Article  CAS  Google Scholar 

  59. Santhi T, Manonmani S, Smitha T (2010) Removal of malachite green from aqueous solution by activated carbon prepared from the epicarp of Ricinus communis by adsorption. J Hazard Mater 179:178–186

    Article  CAS  Google Scholar 

  60. Shirmardi M, Mesdaghinia A, Mahvi AH, et al (2012) Kinetics and equilibrium studies on adsorption of Acid Red 18 (Azo-Dye) using multiwall carbon nanotubes (MWCNTs) from aqueous solution. Euro J Chem 9:2371–2383

    CAS  Google Scholar 

  61. Wang S, Ng CW, Wang W, et al (2012) Synergistic and competitive adsorption of organic dyes on multiwalled carbon. Chem Eng J 197:34–40

    Article  CAS  Google Scholar 

  62. Anbia M, Salehi S (2012) Removal of acid dyes from aqueous media by adsorption onto amino-functionalized nanoporous silica SBA-3. Dyes and Pigments 94:1–9

    Article  CAS  Google Scholar 

  63. Ho KY, Mckay G, Yeung KL (2003) Selective adsorbents from ordered mesoporous silica. Langmuir 19:3019–3024

    Article  CAS  Google Scholar 

  64. Qin Q, Ma J, Liu K (2009) Adsorption of anionic dyes on ammonium-functionalized MCM-41. J Hazard Mater 162:133–139

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Textile Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Maryam Mirzaie & Abosaeed Rashidi

  2. Department of Textile Engineering, Islamic Azad University, Qaemshahr Branch, Qaemshahr, Iran

    Habib Allah Tayebi

  3. Department of Textile Engineering, Islamic Azad University, Yazd Branch, Yazd, Iran

    Mohammad Esmail Yazdanshenas

Authors
  1. Maryam Mirzaie
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Abosaeed Rashidi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Habib Allah Tayebi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mohammad Esmail Yazdanshenas
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Habib Allah Tayebi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mirzaie, M., Rashidi, A., Tayebi, H.A. et al. Optimized Removal of Acid Blue 62 from Textile Waste Water by SBA-15/PAMAM Dendrimer Hybrid Using Response Surface Methodology. J Polym Environ 26, 1831–1843 (2018). https://doi.org/10.1007/s10924-017-1083-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-017-1083-5

Keywords

Search

Navigation