Abstract
Samarium acetylacetonate (Sm-Acac) was added to catalyze interchange reactions between poly(lactic acid) (PLA) and polycarbonate (PC) in order to promote compatibilization and enhance the performances of the PLA/PC blend. The effects of the composition and catalyzed transesterification reactions were investigated using differential scanning calorimetry (DSC), thermogravimetry (TG), dynamic mechanical thermal analysis (DMTA) and scanning electron microscopy (SEM). DMTA and DSC analysis revealed the immiscibility of the uncatalyzed PLA/PC blends for the studied compositions because the glass transition temperatures of PC and PLA were unchanged after blending. In the PLA glassy region, PLA/PC blends exhibited lower storage moduli which increased upon heating due to the cold crystallization process. During melt mixing with Sm-Acac catalyst, PLA/PC blends were submitted to two competing processes. In one hand, Sm-Acac acted as a plasticizer and contributed in decreasing significantly the glass transition, crystallization and melting temperatures of PLA phase. In the other hand, Sm-Acac proved its efficiency in catalyzing the transesterification reactions that were evidenced by the decrease of the PLA aptitude to crystallization due to the hindering effect of the PC units inserted into the PLA chains. PLA/PC blends melt mixed with 0.25% of Sm-Acac showed a significant strengthening effect, corresponding to an increase in the storage modulus in the temperature range comprised between 70 and 90 °C. This indicated the formation of a copolymer at the interface and the promotion of adhesion as it is confirmed from the decrease in the height of the PLA Tan δ peak. At 0.5% of Sm-Acac, (90/10) PLA/PC blend revealed a new peak assigned to the glass transition of the PLA-PC copolymer, whereas the (50/50) PLA/PC blend was converted into a new random copolymer. TG analysis proved the presence of a copolymer structure presenting an intermediate thermal stability in both the catalyzed and uncatalyzed blends.
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Molinaro S, Cruz Romer M, Boaro M, Sensidoni A, Lagazio C, Morris M, Kerry J (2013) J Food Eng 117:113
Lai SM, Wu SH, Lin GG, Don TM (2014) Eur Polym J 52:193
Okamoto K, Toshima K, Matsumura S (2005) Macromol Biosci 5:813
Chang JH, An YU, G. Sur (2003) J Polym Sci 41:94
Ray SS, Okamoto M (2003) J Polym Sci 28:1539
Frone AN, Berlioz S, Chailan JF, Panaitescus DM (2013) Carbohydr Polym 91:377
Armentano I, Bitinis N, Fortunati E, Mattioli S, Rescignano N, Verdejo R, Lopez-Manchado MA, Kenny JM (2013) Prog Polym Sci 38:1720
Fortunati E, Luzi F, Puglia D, Dominici F, Santulli C, Kenny JM, Torre L (2014) Eur Polym J 56:77
Fortunati E, Armentano I, Zhou Q, Puglia D, Terenzi A, Berglund LA, Kenny JM (2012) Polym Degrad Stab 97:2027
Nan Wang Y, Xuan Weng Y, Wang L (2014) Polym Test 36:119
Araújo A, Botelho G, Oliveira M, Machado AV (2014) Appl Clay Sci 88–89:144
Rasal RM, Janorkar AV, Hirt DE (2010) Prog Polym Sci 35:338
Torres-Huerta AM, Palma-Ramírez D, Domínguez-Crespo MA, Del Angel-López D, de la Fuente D (2014) Eur Polym J 61:285
H. Chen, M. Pyda, P. Cebe (2009) Thermochim Acta 492:61.
Khankrua R, Piva-Art S, Hiroyuki H, Suttiruengwong S (2014) Polym Degrad Stab 108:232
G Biresaw, CJ Carriere (2004) Compos Part A 35:313.
Brito GF, Agrawal P, Araújo EM, de Mélo TJA (2012) Polímeros 22:427.
Jiang L, Wolcott MP, Zhang JW (2006) Biomacromolecules 7:199
Meaurio E, Zuza E, Sarasua JR (2005) Macromolecules 38:9221
Ayana B, Suin S, Khatua BB (2014) Carbohydr Polym 110:430
Malwela T, Ray SS (2012) Polymer 53:2705
T. J.A. Mélo, Araújo EM, Brito GF, Agrawal P (2013) J Alloys Compd 615:389
Hashima K, Nishitsuji S, Inoue T (2010) Polymer 51:3934
H. Zhao, Z. Cui, X. Wang, L.S. Turng, X. Peng (2013) Compos Part B 51:79.
Yang SL, Wu ZH, Yang W, Yang MB (2008) Polym Test 27:957
Jiang L, Zhang J, Wolcott MP (2007) Polymer 48:7632
Fukishima K, Tabuani D, Areana M, Gennari M, Camino G (2013) React Funct Polym 73:540
Hong N, Song L, Hu W, Hu Y (2013) Procedia Eng 62:366
Badrinarayanan P, Ko FK, Wang C, Richard BA, Kessler MR (2014) Polym Test 35:1
Cele HM, Ojijo V, Chen H, Kumar S, K. Land T, Joubert T, de Villiers MFR, Ray SS (2014) Polym Test 36:24
Żenkiewicz M, Richert J, Różański A (2010) Appl Clay Sci 29:251
Picard E, Espuche E, Fulchiron R (2011) Appl Clay Sci 53:58
R. Liu, S. Luo, J. Cao, Y. Peng (2013) Compos Part A 51:33.
Rahman MA, Santis DD, Spagnoli G, Ramorino G, Penco M, Phuong VT, Lazzeri A (2012) J Appl Polym Sci 10:38705
Gordobil O, Egués I, Llano-Ponte R, Labidi J (2014) Polym Degrad Stab 108:1
Shi Q, Zhoub C, Yueb Y, Guoa W, Wuc Y, Wub Q (2012) Carbohydr Polym 90:301
Abdulkhani A, Hosseinzideh J, Ashori A, Dadashi S, Takzare Z (2014) Polym Test 35:73
Koutsomitopoulou AF, Bénézet JC, Bergeret A, Papanicolaou GC (2014) Powder Technol 255:10
Pantani R, Gorrasi G, Vigliotta G, Murariu M, Dubois P (2013) Eur Polym J 49:3471
Nakayama N, Hayashi T (2007) Polym Degrad Stab 92:1255
Lee JB, Lee YK, Choi GD, Na SW, Park TS, Kim WN (2011) Polym Degrad Stab 96:553
Phuong VT, Coltelli MB, Cinelli P, Cifelli M, Verstichel S, Lazzeri A (2014) Polymer 55:4498
Liu C, Lin S, Zhou C, Yu W (2013) Polymer 53:313
Guessoum M, Haddaoui N (2006) Intern J Polym Mater 55:715.
Guessoum M, Fenouillot-Rimilinger F, Haddaoui N (2008) Intern J Polym Mater 57:657.
Guessoum M, Nekkaa S, Haddaoui N (2008) Intern J Polym Mater 57:759.
Ignatov VN, Carraro C, Tartari V, Pippa R, Scapin M, Pilati F, Berti C, Toselli M, Fiorini M (1997) Polymer 38:195
Ignatov VN, Carraro C, Tartari V, Pippa R, Scapin M, Pilati F, Berti C, Toselli M, Fiorini M (1997) Polymer 38:201
Berti C, Bonora V, Pilati F, Fiorini M (2002) Makromol Chem 193:1665.
Fiorini M, Berti C, Ignatov VN, Toselli M, Pilati F (1995) J Appl Polym 55:1157
Fiorini M, Pilati F, Berti C, Toselli M, Ignatov VN (1997) Polymer 38:413
Ignatov VN, Carraro C, Tartari V, Pippa R, Pilati F, Berti C, Toselli M, Fiorini M (1996) Polymer 37:5883
Marchese P, Celli A, Fiorini M (2002) Macromol Chem Phys 203:695
Zhang JM, Tashiro K, Tsuji H, Domb JA (2008) Macromolecules 41:1352
Zhang J, Duan Y, Sato H, Tsuji H, Noda I, Yan S, Ozaki Y (2005) Macromolecules 38:8012
Djellali S, Sadoun T, Haddaoui N (2015) Polym Bull 72:1177.
Pluta M (2014) Polymer 45:8239
Pluta M, Murariu M, Alexandre M, Galeski A, Dubois P (2008) Polym Degrad Stab 93:925
Silverajah VS, Ibrahim AN, Yunus WZW, Hassan HA, Woei CB (2012) Intern J Molecul Sci 13:5878.
Chen HM, Chen J, Yang LN, Huang T, Zhang N, Wang Y (2013) J Polym Sci Part B 51:183.
Martınez-Hernandez AL, Velasco-Santos C, de-Icaza M, Castano VM (2007) Compos Part B 38:405.
Keusch S, Haessler R (1999) Compos Part A 30:997.
Shieh YT, Lin YS, Twu YK, Tsai HB, Lin RH (2010) J Appl Polym Sci 116:1334
Ismail HM (1995) Colloids Surf A 97:247.
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Chelghoum, N., Guessoum, M., Fois, M. et al. Contribution of Catalytic Transesterification Reactions to the Compatibilization of Poly(lactic acid)/Polycarbonate Blends: Thermal, Morphological and Viscoelastic Characterization. J Polym Environ 26, 342–354 (2018). https://doi.org/10.1007/s10924-017-0950-4
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DOI: https://doi.org/10.1007/s10924-017-0950-4