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Enhanced Catalytic Reduction and Electrochemical Sensing Properties of Magnetic Fe3O4@benzothiazole-Cu(II) Nanoparticles

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Abstract

The preparation of a magnetically recoverable and reusable Fe3O4@benzothiazole-Cu(II) nanoparticles with their catalytic and electrochemical sensing properties are reported in this manuscript. The prepared Fe3O4@benzothiazole-Cu(II) nanoparticles are characterized using various analytical techniques, including XRD, FTIR, SEM, TEM, XPS, TGA and VSM analysis. The prepared system has shown good catalytic activity in the reduction of 2-NBA, achieving a reaction rate constant of 0.093 min−¹ in 2 min with a low catalyst loading. The synthesized catalyst also showed very high efficiency in the reduction of 4-nitro-phenol and methylene blue within 13 min and 4 min, respectively. The prepared material demonstrated good recovery yield and could be reused as a catalyst for multiple cycles without a significant loss in catalytic activity. It also exhibited a remarkable electrochemical sensing capability for the detection of ascorbic acid, H2O2, and paracetamol at various concentrations, as determined through cyclic voltammetry and impedance measurements. They exhibited clear redox transformations, indicating the electrochemical sensing ability of the prepared materials.

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References

  1. C. Santhosh, V. Velmurugan, G. Jacob, S.K. Jeong, A.N. Grace, A. Bhatnagar, Chem. Eng. J. 306, (2016)

  2. R.O. Yahya, J. Inorg. Organomet. Polym. Mater. 32, (2022)

  3. K.K. Singh, Int. J. New. Chem. 9, (2022)

  4. M. Bano, D. Ahirwar, M. Thomas, G.A. Naikoo, M.U.D. Sheikh, F. Khan, New J. Chem. 40, (2016)

  5. M. Atarod, M. Nasrollahzadeh, S. Mohammad Sajadi, J. Colloid Interface Sci. 465, (2016)

  6. A. Di Paola, G. Marcì, L. Palmisano, M. Schiavello, K. Uosaki, S. Ikeda, B. Ohtani, J. Phys. Chem. B 106, (2002)

  7. R. Mudike, C. Sabbanahalli, J.B. Sriramoju, A. Bheemaraju, G. Halligudra, M. Muniyappa, M.P. Narayanaswamy, A.K. CS, P.D. Shivaramu, D. Rangappa, Mater. Res. Bull. 146, 111606 (2022)

    Article  CAS  Google Scholar 

  8. N. Modirshahla, M.A. Behnajady, S. Mohammadi-Aghdam, J. Hazard. Mater. 154, (2008)

  9. M.C. Tomei, M.C. Annesini, Environ. Sci. Technol. 39, (2005)

  10. G. Halligudra, C.C. Paramesh, R. Gururaj, A. Giridasappa, C. Sabbanahalli, A.K. Channapillekoppalu, A.K. Siddegowda, D. Madikere Raghunathareddy, Rangappa, and P. Doddakunche Shivaramu, Ceram Int 48, (2022)

  11. C.C. Paramesh, G. Halligudra, M. Muniyappa, M. Shetty, K.K. Somashekharappa, D. Rangappa, K.S. Rangappa, P.D. Shivaramu, Ceram. Int. 47, 14750 (2021)

    Article  CAS  Google Scholar 

  12. C. Chikkanayakanahalli Paramesh, G. Halligudra, V. Gangaraju, J.B. Sriramoju, M. Shastri, H. Kachigere, B.P. Habbanakuppe, D.D. Rangappa, R. Kanchugarakoppal, Subbegowda, and P. Doddakunche Shivaramu, Results in Surfaces and Interfaces 3, 100005 (2021)

  13. K. Lv, G. Yan, G. Wang, Z. Chen, J. Hu, Catal. Lett. 153, (2023)

  14. C.V. Rode, M.J. Vaidya, R. Jaganathan, R.V. Chaudhari, Chem. Eng. Sci. 56, (2001)

  15. Y. Liu, Y. Sheng, Y. Yin, J. Ren, X. Lin, X. Zou, X. Wang, X. Lu, ACS Omega 7, (2022)

  16. S. Kudaibergenov, M. Dauletbekova, G. Toleutay, S. Kabdrakhmanova, T. Seilkhanov, K. Abdullin, J. Inorg. Organomet. Polym. Mater. 28, (2018)

  17. A.D. Stergiou, D.H. Broadhurst, M.D. Symes, STAR. Protoc. 3, (2022)

  18. K. Polat, M.L. Aksu, A.T. Pekel, J. Appl. Electrochem. 32, (2002)

  19. K.M. Lee, C.W. Lai, K.S. Ngai, J.C. Juan, Water Res. 88, (2016)

  20. M.M. Khin, A.S. Nair, V.J. Babu, R. Murugan, S. Ramakrishna, Energy Environ. Sci. 5, (2012)

  21. B. Li, Y. Hao, B. Zhang, X. Shao, L. Hu, Appl. Catal. Gen. 531, (2017)

  22. S. Saha, A. Pal, S. Kundu, S. Basu, T. Pal, Langmuir 26, (2010)

  23. Z. Wu, S. Yang, W. Wu, Nanoscale 8, (2016)

  24. J.J. Lv, A.J. Wang, X. Ma, R.Y. Xiang, J.R. Chen, J.J. Feng, J. Mater. Chem. Mater. 3, (2015)

  25. J. Xia, G. He, L. Zhang, X. Sun, X. Wang, Appl. Catal. B 180, (2016)

  26. S.K. Ghosh, M. Mandal, S. Kundu, S. Nath, T. Pal, Appl. Catal. Gen. 268, 61 (2004)

    Article  CAS  Google Scholar 

  27. H. Saikia, B.J. Borah, Y. Yamada, P. Bharali, J. Colloid Interface Sci. 486, (2017)

  28. J. Liu, Q. Wu, F. Huang, H. Zhang, S. Xu, W. Huang, Z. Li, RSC Adv. 3, (2013)

  29. C. Tamuly, I. Saikia, M. Hazarika, M.R. Das, RSC Adv. 4, (2014)

  30. Z. Zhou, C. Lu, X. Wu, X. Zhang, RSC Adv. 3, (2013)

  31. Z. Zhu, Z. Liu, S. Liu, H. Niu, T. Hu, T. Liu, Y. Xie, Appl. Catal. B 26, (2000)

  32. J.B. Sriramoju, C.C. Paramesh, G. Halligudra, D. Rangappa, P.D. Shivaramu, Photocatalytic Systems by Design (Elsevier, 2021), pp. 503–536

  33. M. Miceli, P. Frontera, A. Macario, A. Malara, Catalysts. 11, 591 (2021)

    Article  CAS  Google Scholar 

  34. S. Chetana, H. Guddappa, V.N. Thakur, N. Kumar, N.C. Joshi, V. Mirle, M. Shetty, J. Mater. Sci.: Mater. Electron. 35, 595 (2024)

    CAS  Google Scholar 

  35. H. Daneshafruz, P. Mohammadi, H. Barani, H. Sheibani, J. Inorg. Organomet. Polym. Mater. 33, (2023)

  36. M. Amini, M.H. Kafshdouzsani, A. Akbari, S. Gautam, C.H. Shim, K.H. Chae, Appl. Organomet. Chem. 32, (2018)

  37. P. Rai, D. Gupta, Synth. Commun. 51, (2021)

  38. G. Halligudra, C. Chikkanayakanahalli Paramesh, M. Shetty, H. Kachigere Bhadraiah, V. Kambappa, A.K. Channapillekoppalu Siddegowda, D. Rangappa, R. Kanchugarakoppal, Subbegowda, P. Doddakunche, Shivaramu, J. Iran. Chem. Soc. 19, 3697 (2022)

    Article  CAS  Google Scholar 

  39. G. Halligudra, C.C. Paramesh, R. Mudike, M. Ningegowda, D. Rangappa, P.D. Shivaramu, ACS Omega. 6, 34416 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  40. Y. Yang, H. Niu, W. Zhao, L. Xu, H. Zhang, Y. Cai, RSC Adv. 10, 29402 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  41. R.S. Keri, M.R. Patil, S.A. Patil, S. Budagumpi, Eur. J. Med. Chem. 89, 207 (2015)

    Article  CAS  PubMed  Google Scholar 

  42. M. Kumar, B.E. Kumara Swamy, S. Reddy, W. Zhao, S. Chetana, and V. Gowrav Kumar, Journal of Electroanalytical Chemistry 835, (2019)

  43. S. Chetana, N. Kuma, P. Choudhary, G. Amulya, A. Kumar, K.B. Kumar, D. Rangappa, Mater. Chem. Phys. 126869 (2022)

  44. I. Chopra, M. Roberts, Microbiol. Mol. Biol. Rev. 65, 232 (2001)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  45. M. Derbali, A. Othmani, S. Kouass, F. Touati, H. Dhaouadi, Mater. Res. Bull. 125, 110771 (2020)

    Article  CAS  Google Scholar 

  46. D.M. Fernandes, N. Silva, C. Pereira, C. Moura, J.M.C.S. Magalhães, B. Bachiller-Baeza, I. Rodríguez-Ramos, A. Guerrero-Ruiz, C. Delerue-Matos, C. Freire, Sens. Actuators B Chem. 218, 128 (2015)

    Article  CAS  Google Scholar 

  47. S. Chetana, M. Shetty, K. Roy, J.B. Sriramoju, G. Halligudra, P.D. Shivaramu, C.S.A. Kumar, K.G. Basavakumar, D. Rangappa, J. Mater. Sci.: Mater. Electron. 33, 19937 (2022)

    CAS  Google Scholar 

  48. K.K. Harish, A.R. Nesaragi, N.K. Kalagatur, P. Naik, M. Madegowda, A. Pandith, K.A. Dahlous, S. Mohammad, H.P. Shivarudrappa, T.M. Sharanakumar, H. Guddappa, J. Photochem. Photobiol Chem. 115565 (2024)

  49. J. Wang, J. Yang, X. Li, B. Wei, D. Wang, H. Song, H. Zhai, X. Li, J. Mol. Catal. Chem. 406, 97 (2015)

    Article  CAS  Google Scholar 

  50. M.A. Nasseri, Z. Rezazadeh, M. Kazemnejadi, A. Allahresani, Catal. Lett. 151, (2021)

  51. M. Nasrollahzadeh, M. Sajjadi, H.A. Khonakdar, J. Mol. Struct. 1161, 453 (2018)

    Article  CAS  Google Scholar 

  52. B. Atashkar, A. Rostami, B. Tahmasbi, Catal. Sci. Technol. 3, 2140 (2013)

    Article  CAS  Google Scholar 

  53. F.D. Firuzabadi, Z. Asadi, F. Panahi, RSC Adv. 6, 101061 (2016)

    Article  Google Scholar 

  54. A.P. Grosvenor, B.A. Kobe, M.C. Biesinger, N.S. McIntyre, Surf. Interface Anal. 36, 1564 (2004)

    Article  CAS  Google Scholar 

  55. S. Sobhani, F.O. Chahkamali, J.M. Sansano, RSC Adv. 9, 1362 (2019)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  56. J.D. Menczel, R.B. Prime, Therm. Anal. Polymers: Fundamentals Appl. (2008)

  57. E.C.S. Santos, T.C. dos Santos, R.B. Guimarães, L. Ishida, R.S. Freitas, C.M. Ronconi, RSC Adv. 5, 48031 (2015)

    Article  CAS  Google Scholar 

  58. S. Jana, S. Pande, S. Panigrahi, S. Praharaj, S. Basu, A. Pal, T. Pal, Langmuir 22, (2006)

  59. J.F. de Souza, G.T. da Silva, A.R. Fajardo, Carbohydr. Polym. 161, (2017)

  60. P. Zhou, D. Li, S. Jin, S. Chen, Z. Zhang, Int. J. Hydrogen Energy. 41, 15218 (2016)

    Article  CAS  Google Scholar 

  61. C. Qiao, W. Jia, Q. Zhong, B. Liu, Y. Zhang, C. Meng, F. Tian, Catal. Lett. 150, (2020)

  62. Z.H. Farooqi, Z. Butt, R. Begum, S.R. Khan, A. Sharif, E. Ahmed, Mater. Science- Pol. 33, (2015)

  63. M. Rajabzadeh, H. Eshghi, R. Khalifeh, M. Bakavoli, RSC Adv. 6, 19331 (2016)

    Article  CAS  Google Scholar 

  64. M. Yaghmaei, A.E. Lanterna, J.C. Scaiano, IScience 24, (2021)

  65. S. Jayabal, R. Ramaraj, Appl. Catal. Gen. 470, (2014)

  66. P. Kotteeswaran, V.B. Raju, A. Murugan, M.S. Santosh, H.P. Nagaswarupa, S.C. Prashantha, M.R.A. Kumar, M.S. Shivakumar, J. Energy Storage. 9, 12 (2017)

    Article  Google Scholar 

  67. M.A.S. Amulya, H.P. Nagaswarupa, M.R.A. Kumar, C.R. Ravikumar, K.B. Kusuma, S.C. Prashantha, J. Phys. Chem. Solids. 148, 109756 (2021)

    Article  CAS  Google Scholar 

  68. J. Shen, P.T. Griffiths, S.J. Campbell, B. Utinger, M. Kalberer, S.E. Paulson, Sci. Rep. 11, 7417 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  69. M.R.A. Kumar, H.P. Nagaswarupa, C.R. Ravikumar, S.C. Prashantha, H. Nagabhushana, A.S. Bhatt, J. Phys. Chem. Solids. 127, 127 (2019)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors thank the Department of Science and Technology (DST), Ministry of Science and Technology, Government of India for providing financial support to Mr. Halligudra Guddappa through the INSPIRE Fellowship (Sanction No. DST/INSPIRE/03/2015/003933, Registration No: IF160537).

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Authors and Affiliations

  1. Department of Applied Sciences, Visvesvaraya Technological University, Muddenahalli Campus, Chikkaballapur, 562 101, India

    Guddappa Halligudra, Prasanna D. Shivaramu, Chitrabanu C. Paramesh, Kunal Roy, Chetana Sabbanahalli, Manikanta P. N., Ananda Kumar C. S. & Dinesh Rangappa

  2. Department of Chemistry, ATME College of Engineering, Mysuru, Karnataka, India

    Guddappa Halligudra

  3. Department of Chemistry, Indian Academy Degree College, Hennur Cross, Bengaluru, Karnataka, India

    Chitrabanu C. Paramesh

  4. Department of Mechanical Engineering, ATME College of Engineering, Mysuru, Karnataka, India

    Chetana Sabbanahalli

  5. Department of Chemistry, I.D.S.G Government College, Chikkamagaluru, 577 102, India

    Vinaya K.

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  1. Guddappa Halligudra
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Contributions

HG carried out the experiments and prepared a draft. PDS designed the experiments and monitored and corrected the draft. CCP conducted experiments. KR analyzed the results.CS performed SEM and XRD analysis and analyzed results. MPN performed sensor application experiments. CSA and DR monitored the experiments, helped to analyze the results, and reviewed the manuscript.

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Correspondence to Prasanna D. Shivaramu or Dinesh Rangappa.

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Supporting Information

: EDX spectra of Fe3O4@benzothiazole-Cu(II) (Fig. S1); hot filtration and leaching test of Fe3O4@benzothiazole-Cu(II) in the o-NBA reduction reaction (Fig. S2); 1H NMR spectra of anthranilic acid (Fig. S3); effect of NaBH4 concentration on the reduction of 2-NBA (Fig. S4); a plausible mechanism for the reduction of 2-NBA (Fig. S5); XRD patterns of (a) fresh and (b) recycled Fe3O4@benzothiazole-Cu(II) (Fig. S6); SEM images of (a, b and c) fresh and (d, e and f) recycled Fe3O4@benzothiazole-Cu(II) (Fig. S7)

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Halligudra, G., Shivaramu, P.D., Paramesh, C.C. et al. Enhanced Catalytic Reduction and Electrochemical Sensing Properties of Magnetic Fe3O4@benzothiazole-Cu(II) Nanoparticles. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03091-7

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