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Synthesis and Properties of Manganese(II) and Nickel(II) 1-D Coordination Polymers Based on 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone

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Abstract

New manganese(II) and nickel(II) 1-D zigzag coordination polymers [M2+(pQ2−)·2(solv)]n (M2+ = Mn2+, solv = N,N’-dimethylacetamide (1) and M = Ni2+, solv = N,N’-dimethylformamide (2); pQ2− - dianionic form of 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone) have been synthesized and characterized. Both compounds 1 and 2 are isomorphic. Their physicochemical properties such as thermal stability, gas sorption, redox and magnetic properties are described.

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Acknowledgements

The studies were carried out using the equipment of the center for collective use “Analytical Center of the IOMC RAS” with the financial support of the grant “Ensuring the development of the material and technical infrastructure of the centers for collective use of scientific equipment” (Unique identifier RF----2296.61321Х0017, Agreement Number 075-15-2021-670). Mikhail Khrizanforov acknowledge the support of the Government assignment for FRC Kazan Scientific Center of RAS for conducting electrochemical measurements.

Funding

This research was funded by Russian Science Foundation, grant number 22-23-00750.

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, Tropinina str. 49, Nizhny Novgorod, 603950, Russia

    Olesya Yu. Trofimova, Irina V. Ershova, Arina V. Maleeva, Anton V. Cherkasov & Alexandr V. Piskunov

  2. Aleksander Butlerov Institute of Chemistry, Kazan Federal University, Lobachevskogo str. 1/29, Kazan, 420008, Russian Federation

    Mikhail N. Khrizanforov

  3. A.E. Arbuzov Institute of Organic and Physical Chemistry Subdivision, Federal State Budgetary Institution of Science “Kazan Scientific Center of Russian Academy of Sciences”, Arbuzov str. 8, Kazan, 420088, Russia

    Mikhail N. Khrizanforov

  4. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, Novosibirsk, 630090, Russia

    Konstantin A. Kovalenko

  5. International Tomography Center Siberian Branch of Russian Academy of Sciences Institutskaya, Novosibirsk, 3a, 630090, Russia

    Artem S. Bogomyakov

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  1. Olesya Yu. Trofimova
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Contributions

Author Contributions - Conceptualization: A.V.P., Methodology: O.Y.T., Formal analysis and investigation: O.Y.T., I.V.E., A.V.M., A.V.Ch., M.N.Kh., K.A.K., A.S.B., Writing-original draft preparation: O.Y.T., Writing-review and editing: A.V.P.

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Correspondence to Alexandr V. Piskunov.

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Trofimova, O.Y., Ershova, I.V., Maleeva, A.V. et al. Synthesis and Properties of Manganese(II) and Nickel(II) 1-D Coordination Polymers Based on 2,5-di-hydroxy-3,6-di-tert-butyl-para-quinone. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-024-03013-7

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