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Rational Design of Two-Step Functionalized Barium Titanate for Improving Dielectric Properties of poly(Arylene Ether Nitrile) Composites

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Abstract

Ceramic/polymer dielectrics with excellent thermal stability and high dielectric performance exhibit great potential in advanced capacitor applications. It is still a major challenge for ceramic/polymer dielectrics to obtain high dielectric constant at low content while maintaining excellent flexibility. To alleviate this issue, here, a flexible polymer dielectric composite consisting of poly(arylene ether nitrile) (PEN) matrix and barium titanate filler coated by Carbon and polypyrone (h-BT@C@PPy) was put forward in this work. The as-prepared composite films displayed high dielectric constant, comparable low loss and favorable interfacial binding due to the hydrogen-bonding interaction between –NH of h-BT@C@PPy and –CN of PEN, effectively promoting the interfacial polarization and remedying the internal interface defects between h-BT and PEN. Consequently, an addition of 8 wt% h-BT@C@PPy into PEN matrix raised the dielectric constant from 3.82 to 13.3 at 1 kHz, while maintaining relatively low dielectric loss (0.05@1 kHz). However, the breakdown strength showed a decreasing trend with the lowest value of 60.37 kV mm−1. Meanwhile, the better flexibility, outstanding thermal stability (the 5% weight loss above 500 °C) as well as excellent permittivity-temperature stability was also delivered by the PEN-based composite films. This strategy furnishes a perspective to design ceramic/polymer dielectrics with high-k achieved at low filler content for the applications of organic film capacitors.

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Data Availability

No datasets were generated or analysed during the current study.

References

  1. M. Yang, Q. Li, X. Zhang, E. Bilotti, C. Zhang, C. Xu, S. Gan, Z.-M. Dang, Prog. Mater. Sci. 128, 100968 (2022)

    Article  Google Scholar 

  2. R. Behera, K. Elanseralathan, J. Energy Storage. 48, 103788 (2022)

    Article  Google Scholar 

  3. H. Chi, W. He, D. Zhao, R. Ma, Y. Zhang, Z. Jiang, Sci. China Mater. 66, 22–34 (2023)

    Article  CAS  Google Scholar 

  4. Q. Yuan, M. Chen, S. Zhan, Y. Li, Y. Lin, H. Yang, Chem. Eng. J. 446, 136315 (2022)

    Article  CAS  Google Scholar 

  5. H.P.P.V. Shanmugasundram, E. Jayamani, K.H. Soon, Renew. Sust Energy Rev. 157, 112075 (2022)

    Article  Google Scholar 

  6. L. Yang, H. Wang, S. Fang, M. Li, J. Alloy Compd. 960, 170831 (2023)

    Article  CAS  Google Scholar 

  7. F. Wu, A. Xie, L. Jiang, S. Mukherjee, H. Gao, J. Shi, J. Wu, H. Shang, Z. Sheng, R. Guo, L. Wu, J. Liu, M.E. Suss, A. Terzis, W. Li, H. Zeng, Adv. Funct. Mater. 33, 2212861 (2023)

    Article  CAS  Google Scholar 

  8. L. Cheng, H. Gao, K. Liu, H. Tan, P. Fan, Y. Liu, Y. Hu, Z. Yan, H. Zhang, Macromol. Mater. Eng. 307, 2100822 (2022)

    Article  CAS  Google Scholar 

  9. J. Peng, T. Cao, Y. You, X. Liu, Y. Huang, Polymer. 283, 126229 (2023)

    Article  CAS  Google Scholar 

  10. D.W. Shin, S.Y. Lee, N.R. Kang, K.H. Lee, M.D. Guiver, Y.M. Lee, Macromolecules. 46, 3452–3460 (2013)

    Article  CAS  Google Scholar 

  11. H. Yin, W. Zhong, M. Yin, C. Kang, L. Shi, H. Tang, C. Yang, J.T. Althakafy, M. Huang, A.K. Alanazi, L. Qu, Y. Li, Adv. Compos. Hybrid. Mater. 5, 2031–2041 (2022)

    Article  CAS  Google Scholar 

  12. S.K. Behera, M. Panda, R.K. Pradhan, Appl. Phys. A 129, 798 (2023)

    Article  CAS  Google Scholar 

  13. S.K. Behera, M. Panda, R.K. Pradhan, Mod. Phys. Lett. B 38, 2350198 (2024)

    Article  CAS  Google Scholar 

  14. M. Panda, Indian J. Phys. 96, 1699–1703 (2022)

    Article  CAS  Google Scholar 

  15. M. Panda, Appl. Phys. Lett. 111, 082901 (2017)

    Article  Google Scholar 

  16. M. Panda, A. Mishra, P. Shukla, SN Appl. Sci. 01, 230 (2019)

    Article  Google Scholar 

  17. M. Panda, A. Trivedi, Ferroelectrics. 572, 236 (2020)

    Google Scholar 

  18. H. Wu, F. Zhuo, H. Qiao, L.K. Venkataraman, M. Zheng, S. Wang, H. Huang, B. Li, X. Mao, Q. Zhang, Energy Environ. Mater. 5, 486–514 (2022)

    Article  CAS  Google Scholar 

  19. H. Zhang, M.A. Marwat, B. Xie, M. Ashtar, K. Liu, Y. Zhu, L. Zhang, P. Fan, C. Samart, Z. Ye, ACS Appl. Mater. Interfaces. 12, 1–37 (2020)

    Article  PubMed  Google Scholar 

  20. Z.-H. Dai, T. Li, Y. Gao, J. Xu, J. He, Y. Weng, B.-H. Guo, Compos. Sci. Technol. 169, 142–150 (2019)

    Article  CAS  Google Scholar 

  21. G. Wang, Y. Deng, Y. Wang, H. Gao, J. Mater. Chem. C 5, 3112–3120 (2017)

    Article  CAS  Google Scholar 

  22. W. Xu, G. Yang, L. Jin, J. Liu, Y. Zhang, Z. Zhang, Z. Jiang, ACS Appl. Mater. Interfaces. 10, 11233–11241 (2018)

    Article  CAS  PubMed  Google Scholar 

  23. L. Xie, X. Huang, C. Wu, P. Jiang, J. Mater. Chem. 21, 5897–5906 (2011)

    Article  CAS  Google Scholar 

  24. Y. Zhang, X. Zhang, H. Ye, L. Xu, J. Mater. Sci. : Mater. Electron. 33, 22899–22912 (2021)

    Google Scholar 

  25. R.W. Sillars, J. Inst. Electr. Eng. 80, 378–394 (2010)

    Google Scholar 

  26. X. Xie, Z. He, X. Qi, J. Yang, Y. Lei, Y. Wang, Chem. Sci. 10, 8224–8235 (2019)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  27. S. Chen, D. Ren, B. Li, M. Xu, X. Liu, Polym Test. 96, 107091 (2021)

    Article  CAS  Google Scholar 

  28. J. Wang, M. Wang, C. Liu, H. Zhou, X. Jian, Polym. Bull. 70, 1467–1481 (2013)

    Article  CAS  Google Scholar 

  29. M. Feng, M. Chen, J. Qiu, M. He, Y. Huang, J. Lin, J. Alloy Compd. 856, 158213 (2021)

    Article  CAS  Google Scholar 

  30. X. Zhang, S. Zhao, F. Wang, Y. Ma, L. Wang, D. Chen, C. Zhao, W. Yang, Appl. Surf. Sci. 403, 71–79 (2017)

    Article  CAS  Google Scholar 

  31. Z. He, X. Yu, J. Yang, N. Zhang, T. Huang, Y. Wang, Z. Zhou, Compos. A 104, 89–100 (2018)

    Article  CAS  Google Scholar 

  32. J. Yang, X. Xie, Z. He, Y. Lu, X. Qi, Y. Wang, Chem. Eng. J. 355, 137–149 (2019)

    Article  CAS  Google Scholar 

  33. J. Li, C. Liu, New. J. Chem. 33, 1474–1477 (2009)

    Article  CAS  Google Scholar 

  34. S. Wang, X. Huang, Y. He, H. Huang, Y. Wu, L. Hou, X. Liu, T. Yang, J. Zou, Carbon. 50, 2119–2125 (2012)

    Article  CAS  Google Scholar 

  35. S. Yan, C. Xu, J. Jiang, D. Liu, Z. Wang, J. Tang, L. Zhen, J. Magn. Magn. Mater. 349, 159–164 (2014)

    Article  CAS  Google Scholar 

  36. X. Zhang, P. Guan, X. Dong, Appl. Phys. Lett. 96, 223111 (2010)

    Article  Google Scholar 

  37. Z. Pan, L. Yao, J. Zhai, D. Fu, B. Shen, H. Wang, ACS Appl. Mater. Interfaces. 9, 4024–4033 (2017)

    Article  CAS  PubMed  Google Scholar 

  38. S. Liu, J. Wang, H. Hao, L. Zhao, J. Zhai, Ceram. Int. 44, 22850–22855 (2018)

    Article  CAS  Google Scholar 

  39. B. Wan, H. Li, Y. Xiao, S. Yue, Y. Liu, Q. Zhang, Appl. Surf. Sci. 501, 144243 (2020)

    Article  CAS  Google Scholar 

  40. Z. Li, F. Liu, G. Yang, H. Li, L. Dong, C. Xiong, Q. Wang, Compos. Sci. Technol. 164, 214–221 (2018)

    Article  CAS  Google Scholar 

  41. C. Baek, J.E. Wang, S. Moon, C.H. Choi, D.K. Kim, J. Am. Ceram. Soc. 99, 3802–3808 (2016)

    Article  CAS  Google Scholar 

  42. Y. Feng, J. Lia, W. Li, M. Li, Q. Chi, T. Zhang, W. Fei, Compos. A 125, 105524 (2019)

    Article  CAS  Google Scholar 

  43. Y. Wang, J. Cui, L. Wang, Q. Yuan, Y. Niu, J. Chen, Q. Wang, H. Wang, J. Mater. Chem. A 5, 4710–4718 (2017)

    Article  CAS  Google Scholar 

  44. K. Bi, M. Bi, Y. Hao, W. Luo, Z. Cai, X. Wang, Y. Huang, Nano Energy. 51, 513–523 (2018)

    Article  CAS  Google Scholar 

  45. P. Hu, S. Gao, Y. Zhang, L. Zhang, C. Wang, Compos. Sci. Technol. 156, 109–116 (2018)

    Article  CAS  Google Scholar 

  46. B. Paul, L. Bailly, D. Begue, C. Lartigau-Dagron, B. Hassoune-Rhabbour, V. Nassiet, Polym. Degrad. Stabil. 208, 110250 (2023)

    Article  CAS  Google Scholar 

  47. Y. You, S. Liu, L. Tu, Y. Wang, C. Zhan, X. Du, R. Wei, X. Liu, Macromolecules. 52, 5850–5859 (2019)

    Article  CAS  Google Scholar 

  48. C. Zhang, B. Anasori, A. Seral-Ascaso, S. Park, N. Mcevoy, A. Shmeliov, G. Duesberg, J. Coleman, Y. Gogotsi, V. Nicolosi, Adv. Mater. 29, 1702678 (2017)

    Article  Google Scholar 

  49. Y. Feng, Q. Deng, C. Peng, Q. Wu, Ceram. Int. 45, 7923–7930 (2019)

    Article  CAS  Google Scholar 

  50. Y. Lu, W.-Y. Wang, F. Xue, J.-H. Yang, X.-D. Qi, Z.-W. Zhou, Y. Wang, Chem. Eng. J. 345, 353–363 (2018)

    Article  CAS  Google Scholar 

  51. Y. Chen, B. Lin, X. Zhang, J. Wang, C. Lai, Y. Sun, Y. Liu, H. Yang, J. Mater. Chem. A 2, 14118–14126 (2014)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors wish to thank for financial support of this work from the Opening Project of Jiangsu Province Engineering Research Center of Agricultural Breeding Pollution Control and Resource (Grant No. 2021ABPCR009).

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Authors and Affiliations

  1. School of Chemical and Environmental Engineering, Yancheng Teachers University, Yancheng, 224007, People’s Republic of China

    Jing Lin

  2. School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng, 224051, People’s Republic of China

    Mengna Feng

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Contributions

JL:designed and performed the experiments; All authors, JLand MF: contributed to the data analysis and the discussions; MF: wrote the original draft and revised this paper; All the authors approved the final version of the manuscript.

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Correspondence to Mengna Feng.

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Lin, J., Feng, M. Rational Design of Two-Step Functionalized Barium Titanate for Improving Dielectric Properties of poly(Arylene Ether Nitrile) Composites. J Inorg Organomet Polym (2024). https://doi.org/10.1007/s10904-023-02980-7

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