Abstract
The widespread use of organic dyes that are discharged into wastewater from many sectors continues to be a top environmental issue today. The UV–Visible light driven photocatalytic environmental purification is a highly promising field, and spinel ferrites are the prime applicant for waste water purification. In this work, pure phase cobalt doped Mg–Zn nanoferrites with a composition of Mg0.5Zn0.4Co0.1Fe2O4, Mg0.4Zn0.5Co0.1Fe2O4, and Mg0.5Zn0.5Co0.1Fe1.9O4 were fabricated using economic and facile combustion process. The prepared catalysts were caharcteriazed for structural, optical and magnetic properties. The catalyst Z5C1 exhibits 97.76% crystal violet degradation in 90 min under UV–Visible light. The superior photocatalytic efficiency of the Z5C1 catalyst is attributed to the lowest charge carrier recombination rate and moderate band gap of the catalysts. The scavenging experiments revealed the role of holes as reactive species in the catalytic degradation of crystal violet dye. The reusability investigations and simplicity of magnetic separation of the manufactured catalyst show that catalysts have the potential to degrade crystal violet dye and other organic contaminants.
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M.I. Din, R. Khalid, Z. Hussain, Recent research on development and modification of nontoxic semiconductor for environmental application. Separ. Purific. Rev. (2020). https://doi.org/10.1080/15422119.2020.1714658
B. Paul, B. Bhuyan, D.D. Purkayastha, M. Dey, S.S. Dhar, Green synthesis of gold nanoparticles using Pogestemon benghalensis (B) O. Ktz. Leaf extract and studies of their photocatalytic activity in degradation of methylene blue. Mater. Lett. (2015). https://doi.org/10.1016/j.matlet.2015.02.054
P. Dhiman, G. Rana, R.A. Alshgari, A. Kumar, G. Sharma, M. Naushad, Z.A. Alothman, Magnetic Ni–Zn ferrite anchored on g-C3N4 as nano-photocatalyst for efficient photo-degradation of doxycycline from water. Environ. Res. 216, 114665 (2023). https://doi.org/10.1016/j.envres.2022.114665
C.M. Magdalane, K. Kaviyarasu, N. Matinise, N. Mayedwa, N. Mongwaketsi, D. Letsholathebe, G. Mola, N. AbdullahAl-Dhabi, M.V. Arasu, M. Henini, Evaluation on La2O3 garlanded ceria heterostructured binary metal oxide nanoplates for UV/visible light induced removal of organic dye from urban wastewater. S Afr J Chem Eng, 26, 49–60 (2018). https://hdl.handle.net/10520/EJC-1476a49e43
M. Ajaz, A. Rehman, Z. Khan, M.A. Nisar, S. Hussain, Degradation of azo dyes by Alcaligenes aquatilis 3c and its potential use in the wastewater treatment. AMB Express 9, 64 (2019). https://doi.org/10.1186/s13568-019-0788-3
K.H. Vardhan, P.S. Kumar, R.C. Panda, A review on heavy metal pollution, toxicity and remedial measures: current trends and future perspectives. J. Mol. Liq. (2019). https://doi.org/10.1016/j.molliq.2019.111197
Y. Zhou, J. Lu, Y. Zhou, Y. Liu, Recent advances for dyes removal using novel adsorbents: a review. Environ. Pollut. (2019). https://doi.org/10.1016/j.envpol.2019.05.072
A.R. Dinçer, Y. Güneş, N. Karakaya, E. Güneş, Comparison of activated carbon and bottom ash for removal of reactive dye from aqueous solution. Bioresour. Technol. 98, 4 (2007). https://doi.org/10.1016/j.biortech.2006.03.009
F. Fu, Q. Wang, Removal of heavy metal ions from wastewaters: a review. J. Environ. Manag. 92, 3 (2011). https://doi.org/10.1016/j.jenvman.2010.11.011
T.P. Oliveira, G.N. Marques, M.A.M. Castro, R.C.V. Costa, J.H.G. Rangel, S.F. Rodrigues, C.C. dos Santos, M.M. Oliveira, Synthesis and photocatalytic investigation of ZnFe2O4 in the degradation of organic dyes under visible light. J. Mater. Res. Technol. 9, 6 (2020). https://doi.org/10.1016/j.jmrt.2020.10.080
M.I. Din, S. Jabbar, J. Najeeb, R. Khalid, T. Ghaffar, M. Arshad, S.A. Khan, S. Ali, Green synthesis of zinc ferrite nanoparticles for photocatalysis of methylene blue. Int. J. Phytoremed. (2020). https://doi.org/10.1080/15226514.2020.1781783
S. Latif, A. Liaqat, M. Imran, A. Javaid, N. Hussain, T. Jesionowski, M. Bilal, Development of zinc ferrite nanoparticles with enhanced photocatalytic performance for remediation of environmentally toxic pharmaceutical waste diclofenac sodium from wastewater. Environ. Res. (2023). https://doi.org/10.1016/j.envres.2022.114500
Z. Wang, J. You, J. Li, J. Xu, X. Li, H. Zhang, Review on cobalt ferrite as photo-Fenton catalysts for degradation of organic wastewater. Catal. Sci. Technol. (2023). https://doi.org/10.1039/D2CY01300B
A. Rahman, S. Zulfiqar, A.U. Haq, I.A. Alsafari, U.Y. Qazi, M.F. Warsi, M. Shahid, Cd–Gd-doped nickel spinel ferrite nanoparticles and their nanocomposites with reduced graphene oxide for catalysis and antibacterial activity studies. Ceram. Int. (2021). https://doi.org/10.1016/j.ceramint.2020.12.085
Y. Sun, J. Zhou, D. Liu, X. Li, H. Liang, Enhanced catalytic performance of Cu-doped MnFe2O4 magnetic ferrites: tetracycline hydrochloride attacked by superoxide radicals efficiently in a strong alkaline environment. Chemosphere (2022). https://doi.org/10.1016/j.chemosphere.2022.134154
P. Shah, A. Unnarkat, F. Patel, M. Shah, P. Shah, A comprehensive review on spinel based novel catalysts for visible light assisted dye degradation. Process Saf. Environ. Protect. (2022). https://doi.org/10.1016/j.psep.2022.03.030
M. Sundararajan, L.J. Kennedy, P. Nithya, J.J. Vijaya, M. Bououdina, Visible light driven photocatalytic degradation of rhodamine B using Mg doped cobalt ferrite spinel nanoparticles synthesized by microwave combustion method. J. Phys. Chem. Solids (2017). https://doi.org/10.1016/j.jpcs.2017.04.002
P. Dhiman, N. Dhiman, A. Kumar, G. Sharma, M. Naushad, A.A. Ghfar, Solar active nano-Zn1−xMgxFe2O4 as a magnetically separable sustainable photocatalyst for degradation of sulfadiazine antibiotic. J. Mol. Liq. (2019). https://doi.org/10.1016/j.molliq.2019.111574
S.F. Mansour, S. Wageh, R. Al-Wafi, M.A. Abdo, Enhanced magnetic, dielectric properties and photocatalytic activity of doped Mg–Zn ferrite nanoparticles by virtue of Sm3+ role. J. Alloys Compd. (2020). https://doi.org/10.1016/j.jallcom.2020.157437
N. Khaliq, I. Bibi, F. Majid, M.I. Arshad, A. Ghafoor, Z. Nazeer, S. Ezzine, N. Alwadai, A. Nazir, M. Iqbal, Mg1−xNixFe2−xCrxO4 synthesis via hydrothermal route: effect of doping on the structural, optical, electrical, magnetic and photocatalytic properties. Results Phys. (2022). https://doi.org/10.1016/j.rinp.2022.106059
R. Sharma, P. Thakur, M. Kumar, P. Sharma, V. Sharma, Nanomaterials for high frequency device and photocatalytic applications: Mg–Zn–Ni ferrites. J. Alloys Compd. (2018). https://doi.org/10.1016/j.jallcom.2018.02.287
N.S. Al-Bassami, S.F. Mansour, AC conductivity, complex impedance and photocatalytic applications of Co2+ substituted Mg–Zn nanoferrite. Appl. Phys. A 127, 38 (2021). https://doi.org/10.1007/s00339-020-04022-2
P. Dhiman, T. Mehta, A. Kumar, G. Sharma, M. Naushad, T. Ahamad, G.T. Mola, Mg0.5NixZn0.5−xFe2O4 spinel as a sustainable magnetic nano-photocatalyst with dopant driven band shifting and reduced recombination for visible and solar degradation of reactive Blue-19. Adv. Powder Technol. 31, 12 (2020). https://doi.org/10.1016/j.apt.2020.10.010
S. Mansour, R. Al-Wafi, M. Abdo, Zn–Mg–La nanoferrites for storage and high frequency devices with augmenting the photocatalytic performance. J. Alloys Compd. (2020). https://doi.org/10.1016/j.jallcom.2020.154125
S. Kumari, N. Dhanda, A. Thakur, V. Gupta, S. Singh, R. Kumar, S. Hameed, P. Thakur, Nano Ca–Mg–Zn ferrites as tuneable photocatalyst for UV light-induced degradation of rhodamine B dye and antimicrobial behavior for water purification. Ceram. Int. 49, 8 (2023). https://doi.org/10.1016/j.ceramint.2022.12.107
J. Zhao, T. Wang, X. Liu, X. Kan, C. Liu, W. Wang, Y. Li, J. Hu, Q. Lv, J. Huang, Influence of Mg2+ replacement on the structure and magnetic properties of MgxZn1−xFe2O4 (x = 0.1–0.5) ferrites. J. Mater. Sci. Mater. Electron. (2021). https://doi.org/10.1007/s10854-020-05143-3
E. Petrova, D. Kotsikau, V. Pankov, A. Fahmi, Influence of synthesis methods on structural and magnetic characteristics of Mg–Zn-ferrite nanopowders. J. Magn. Magn. Mater. (2019). https://doi.org/10.1016/j.jmmm.2018.09.128
A.G. Abraham, A. Manikandan, E. Manikandan, S. Vadivel, S. Jaganathan, A. Baykal, P.S. Renganathan, Enhanced magneto-optical and photo-catalytic properties of transition metal cobalt (Co2+ ions) doped spinel MgFe2O4 ferrite nanocomposites. J. Magn. Magn. Mater. (2018). https://doi.org/10.1016/j.jmmm.2018.01.001
S. Sugashini, T. Gomathi, R.A. Devi, P.N. Sudha, K. Rambabu, F. Banat, Nanochitosan/carboxymethyl cellulose/TiO2 biocomposite for visible-light-induced photocatalytic degradation of crystal violet dye. Environ. Res. (2022). https://doi.org/10.1016/j.envres.2021.112047
H.R. Sharma, K.M. Batoo, R. Neffati, P. Dhiman, S. Bhardwaj, P. Sharma, S. Hussain, I. Sharma, R. Goel, G. Kumar, Investigation of structural, electrical and magnetic properties of MnAlxFe2−xO4 ferrite nanoparticles processed by solution combustion route. Phys. B Condens. Matter 646, 414368 (2022). https://doi.org/10.1016/j.physb.2022.414368
P. Dhiman, G. Rana, E.A. Dawi, A. Kumar, G. Sharma, A. Kumar, J. Sharma, Tuning the photocatalytic performance of Ni–Zn ferrite catalyst using Nd doping for solar light-driven catalytic degradation of methylene blue. Water 15, 1 (2023). https://doi.org/10.3390/w15010187
P. Dhiman, G. Rana, A. Kumar, G. Sharma, D.-V.N. Vo, T.S. AlGarni, M. Naushad, Z.A. Alothman, Nanostructured magnetic inverse spinel Ni–Zn ferrite as environmental friendly visible light driven photo-degradation of levofloxacin. Chem. Eng. Res. Des. (2021). https://doi.org/10.1016/j.cherd.2021.08.028
M. Basak, M.L. Rahman, M.F. Ahmed, B. Biswas, N. Sharmin, The use of X-ray diffraction peak profile analysis to determine the structural parameters of cobalt ferrite nanoparticles using Debye–Scherrer, Williamson–Hall, Halder–Wagner and size-strain plot: different precipitating agent approach. J. Alloys Compd. (2022). https://doi.org/10.1016/j.jallcom.2021.162694
M. Amer, O. Hemeda, 57Fe Mössbauer and infrared studies of the system Co1−xCdxFe2O4. Hyperfine Interact. (1995). https://doi.org/10.1007/BF02066276
S. Kanagesan, M. Hashim, S. Tamilselvan, N.B. Alitheen, I. Ismail, G. Bahmanrokh, Cytotoxic effect of nanocrystalline MgFe2O4 particles for cancer cure. J. Nanomater. (2013). https://doi.org/10.1155/2013/865024
J. Hammouche, M. Gaidi, S. Columbus, M. Omari, Enhanced photocatalytic performance of zinc ferrite nanocomposites for degrading methylene blue: effect of nickel doping concentration. J. Inorgan. Organ. Polym. Mater. (2021). https://doi.org/10.1007/s10904-021-01960-z
A. Irshad, M. Zulfiqar, H.M. Ali, N. Shahzadi, H.H. Abd El-Gawad, C. Chokejaroenrat, C. Sakulthaew, F. Anjum, M. Suleman, Co-substituted Mg–Zn spinel nanocrystalline ferrites: synthesis, characterization and evaluation of catalytic degradation efficiency for colored and colorless compounds. Ceram. Int. 48, 29805–29815 (2022)
M.I.U. Haq, A.U. Rehman, M. Asghar, M.A.U. Nabi, N. Amin, S. Tahir, M.I. Arshad, Influence of Ce3+ and La3+ substitution on structural and optical parameters and electrical behavior on Mg–Zn ferrites synthesized via Co-precipitation method. J. Superconduct. Novel Magn. (2022). https://doi.org/10.1007/s10948-021-06124-1
M.A. Rahman, M.T. Islam, M.S.J. Singh, M. Samsuzzaman, M.E.H. Chowdhury, Synthesis and characterization of Mg–Zn ferrite based flexible microwave composites and its application as SNG metamaterial. Sci. Rep. (2021). https://doi.org/10.1038/s41598-021-87100-6
S. Kossar, I.S. Banu, N. Aman, R. Amiruddin, Investigation on photocatalytic degradation of crystal violet dye using bismuth ferrite nanoparticles. J. Dispers. Sci. Technol. (2021). https://doi.org/10.1080/01932691.2020.1806861
G. Muhiuddin, I. Bibi, Z. Nazeer, F. Majid, S. Kamal, A. Kausar, Q. Raza, N. Alwadai, S. Ezzine, M. Iqbal, Synthesis of Ni doped barium hexaferrite by microemulsion route to enhance the visible light-driven photocatalytic degradation of crystal violet dye. Ceram. Int. 49, 3 (2023). https://doi.org/10.1016/j.ceramint.2022.09.319
I. Bibi, F. Majid, S. Kamal, K. Jilani, B. Taj, Z. Nazeer, M. Iqbal, Enhanced visible light-driven photocatalytic degradation of crystal violet dye using Cr doped BaFe12O19 prepared via facile micro-emulsion route. J. Saudi Chem. Soc. 26, 6 (2022). https://doi.org/10.1016/j.jscs.2022.101533
A. Jamil, Cu2+ doped nickel spinel ferrites (CuxNi1−xFe2O4) nanoparticles loaded on CNTs for degradation of crystal violet dye and antibacterial activity studies. J. Taibah Univ. Sci. (2021). https://doi.org/10.1080/16583655.2021.2005911
J. Arshad, F.M.A. Alzahrani, S. Munir, U. Younis, M.S. Al-Buriahi, Z.A. Alrowaili, M.F. Warsi, Integration of 2D graphene oxide sheets with MgFe2O4/ZnO heterojunction for improved photocatalytic degradation of organic dyes and benzoic acid. Ceram. Int. (2023). https://doi.org/10.1016/j.ceramint.2023.03.024
M.M. Baig, S. Zulfiqar, M.A. Yousuf, M. Touqeer, S. Ullah, P. Agboola, M.F. Warsi, I. Shakir, Structural and photocatalytic properties of new rare earth La3+ substituted MnFe2O4 ferrite nanoparticles. Ceram. Int. 46, 14 (2020). https://doi.org/10.1016/j.ceramint.2020.06.103
J. Revathi, M.J. Abel, C.L. Pearline, T. Sumithra, P.F.H. Inbaraj, Influence of Zn2+ in CoFe2O4 nanoparticles on its photocatalytic activity under solar light irradiation. Inorgan. Chem. Commun. (2020). https://doi.org/10.1016/j.inoche.2020.108186
N. Tariq, R. Fatima, S. Zulfiqar, A. Rahman, M.F. Warsi, I. Shakir, Synthesis and characterization of MoO3/CoFe2O4 nanocomposite for photocatalytic applications. Ceram. Int. 46, 13 (2020). https://doi.org/10.1016/j.ceramint.2020.05.264
S. Chauhan, B. Tripathi, M. Kumar, M. Sahni, R. Singh, S. Singh, Influence of Na substitution on structural, magnetic, optical and photocatalytic properties of bismuth ferrite nanoparticles. J. Mater. Sci. Mater. Electron. (2020). https://doi.org/10.1007/s10854-020-04540-y
F. Bibi, S. Iqbal, A. Kalsoom, M. Jamshaid, A. Ahmed, M. Mirza, W.A. Qureshi, Magnetically separable Nd and Mn co-doped SrFe12O19 hexa-ferrites nanostructures for the evaluation of structural, magnetic and photo-catalytic studies under solar irradiation for the crystal violet dye removal from the industrial wastes. Ceram. Int. 49, 10 (2023). https://doi.org/10.1016/j.ceramint.2023.01.196
A. Choudhry, A. Sharma, S.I. Siddiqui, I. Ahamad, M. Sajid, T.A. Khan, S.A. Chaudhry, Origanum vulgare manganese-ferrite nanocomposite: an advanced multifunctional carbon material for dye remediation. Environ. Res. (2022). https://doi.org/10.1016/j.envres.2022.115193
M. Abdo, A. El-Daly, Sm-substituted copper–cobalt ferrite nanoparticles: preparation and assessment of structural, magnetic and photocatalytic properties for wastewater treatment applications. J. Alloys Compd. (2021). https://doi.org/10.1016/j.jallcom.2021.160796
R. Jasrotia, J. Prakash, G. Kumar, R. Verma, S. Kumari, S. Kumar, V.P. Singh, A.K. Nadda, S. Kalia, Robust and sustainable Mg1−xCexNiyFe2−yO4 magnetic nanophotocatalysts with improved photocatalytic performance towards photodegradation of crystal violet and rhodamine B pollutants. Chemosphere (2022). https://doi.org/10.1016/j.chemosphere.2022.133706
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Dhiman, P., Rana, G., Kumar, A. et al. Co Doped Mg–Zn Spinel Nano-ferrites as a Sustainable Magnetic Nano-photo-catalyst with Reduced Recombination for Photo Degradation of Crystal Violet. J Inorg Organomet Polym 33, 2776–2789 (2023). https://doi.org/10.1007/s10904-023-02698-6
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DOI: https://doi.org/10.1007/s10904-023-02698-6