Abstract
In this work, 0.5, 2.5, 5.0, and 7.5 wt% AuSe QDs/TiO2 nanocomposites (x-AST NCs) were successfully fabricated and characterized. According to the XRD and TEM results, the crystal sizes of the tetragonal anatase TiO2 NPs ranged from 40 to 50 nm, whereas those of the spherical AuSe quantum dots (AuSe QDs) ranged from 3.71 to 9.58 nm. The AST NCs showed higher surface areas in the range of 26.51–42.14 m2/g depending on the AuSe QDs content (0.5–7.5 wt%) compared to the neat TiO2 itself (18.61. m2/g). According to the TGA curves, adding AuSe QDs onto the TiO2 NPs resulted in higher thermal stability reached 530 °C at 7.5-AST NC. The UV/vis-diffuse reflectance spectra of x-AST NCs showed a visible light absorption band, a red shift in the absorption to visible light, and a narrow double energy gap. The AuSe QDs, when decorated onto TiO2, enable precise engineering of the band structure of TiO2 NPs with suitable narrow-band energy, which can be controlled to achieve enhanced charge separation and generation of extra oxidizing species, peroxy radicals, both beneficial for enhancing the photocatalytic performance. As expected, the fabricated x-AST NC NCs displayed excellent photocatalytic performance. The 5.0-AST NC exhibited the highest photocatalytic performance reached complete elimination (100%), which is almost 3-folds in comparison to that of neat TiO2 NPs (33.62% and 33.10%) within 45 and 60 min for MG and phenol, respectively. The 5.0-AST NC was recycled five times and is of high stability.
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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by FTA, TMA, and SLA. The first draft of the manuscript was written by SLA and TMA, and the revised version of the manuscript was edited by FTA and RSS. All authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Alasri, T.M., Ali, S.L., Salama, R.S. et al. Band-Structure Engineering of TiO2 Photocatalyst by AuSe Quantum Dots for Efficient Degradation of Malachite Green and Phenol. J Inorg Organomet Polym 33, 1729–1740 (2023). https://doi.org/10.1007/s10904-023-02604-0
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DOI: https://doi.org/10.1007/s10904-023-02604-0