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Recent Advancement in Photo-Anode, Dye and Counter Cathode in Dye-Sensitized Solar Cell: A Review

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Abstract

Photovoltaic cells are devices that directly convert sunlight into electricity and it is very simple method to utilize the solar energy. Development of low-cost and high-efficiency solar cell is necessary for the large-scale adaption of solar energy. O’Regan and Gratzel in 1991, developed a new cell called Dye Sensitized Solar Cell (DSSC). Inexpensiveness and easy fabrication technique make DSSC an attractive one. An attempt has been made to review the basic components of Dye Sensitized Solar Cell, which influences the performance of the system. Specific inferences by the researchers around the globe obtained using various photo anodes, dyes and counter electrodes in DSSCs have been thoroughly examined, and the optimum material for a pronounced performance is highlighted. Also, different metals and nanomaterials encapsulated photo anodes and counter electrodes are considered for the review and presented.

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References

  1. K. Xie, M. Guob, H. Huang, Photonic crystals for sensitized solar cells: fabrication, properties, and applications. J. Mater. Chem. C 3, 10665–10686 (2015)

    CAS  Google Scholar 

  2. T.P. Yoon, M.A. Ischay, J. Du, Visible light photocatalysis as a greener approach to photochemical synthesis. Nat. Chem. 2, 527–532 (2010)

    CAS  PubMed  Google Scholar 

  3. B. O’Regan, M. Grätzel, A low-cost, high-efficiency solar cell based on dye sensitized colloidal TiO2 films. Nature 353, 737–740 (1991)

    Google Scholar 

  4. A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, H. Pettersson, Dye sensitized solar cells. Chem. Rev. 110, 6595–6663 (2010)

    CAS  PubMed  Google Scholar 

  5. M. RitaNarayan, Review: dye sensitized solar cells based on natural photosensitizers. Renew. Sustain. Energy Rev. 16, 208–215 (2012)

    Google Scholar 

  6. B.E. Hardin, H.J. Snaith, M.D. McGehee, The renaissance of dye-sensitized solar cells. Nat. Photon 6, 162–169 (2012)

    CAS  Google Scholar 

  7. A. Mishra, M.K.R. Fischer, P. Bauerle, Metal-free organic dyes for dye-sensitized solar cells: from structure: property relationships to design rules. Angew. Chem. Int. Ed. 48, 2474–2499 (2009)

    CAS  Google Scholar 

  8. K. Sharma, V. Sharma, S.S. Sharma, Dye-sensitized solar cells: fundamentals and current status. Nanoscale Res. Lett. 13, 381 (2018)

    PubMed  PubMed Central  Google Scholar 

  9. A. Kay, M. Gratzel, Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Sol. Energy Mater. Sol. Cells 44, 99–117 (1996)

    CAS  Google Scholar 

  10. T. Kitamura, M. Maitani, M. Matsuda, Y. Wada, S. Yanagida, Improved solidstate dye solar cells with polypyrrole using a carbon-based counter electrode. Chem. Lett. 30, 1054–1055 (2001)

    Google Scholar 

  11. T.N. Murakami, M. Gratzel, Counter electrodes for DSC: application of functional materials as catalysts. Inorg. Chim. Acta 361, 572–580 (2008)

    CAS  Google Scholar 

  12. C.S. Wu, T.W. Chang, H. Teng, Y.L. Lee, High performance carbon black counter electrodes for dye-sensitized solar cells. Energy 115, 513–518 (2016)

    CAS  Google Scholar 

  13. A. Ghosh, P. Selvaraj, S. Sundaram, T.K. Mallick, The colour rendering index and correlated colour temperature of dye-sensitized solar cell for adaptive glazing application. Sol. Energy 163, 537–544 (2018)

    CAS  Google Scholar 

  14. U. Mehmood, S.U. Rahman, K. Harrabi, I.A. Hussein, B.V. Reddy, Recent advances in dye sensitized solar cells. Adv. Mater. Sci. Eng. 6346, 1–12 (2014)

    Google Scholar 

  15. S. Sharma, B. Siwach, S.K. Ghoshal, D. Mohan, Dye sensitized solar cells: from genesis to recent drifts. Renew. Sust. Energy Rev. 70, 529–537 (2017)

    CAS  Google Scholar 

  16. C. Sima, C. Grigoriu, S. Antohe, Comparison of the dye-sensitized solar cells performances based on transparent conductive ITO and FTO. Inorg. Chem. 519(2), 595–597 (2010)

    CAS  Google Scholar 

  17. H.K. Jun, M.A. Careem, A.K. Arof, Plasmonic effects of quantum size gold nanoparticles ondye-sensitized solar cell. Mater. Today: Proc. 3S, S73–S79 (2016)

    Google Scholar 

  18. S.A. Kazmi, S. Hameed, A. Azam, Synthesis and characterization of Ag nanowires: improved performance in dye sensitized solar cells. Perspect. Sci. 8, 577–579 (2016)

    Google Scholar 

  19. S. Saravanan, R. Kato, M. Balamurugan, S. Kaushik, T. Soga, Efficiency improvement in dye sensitized solar cells by the plasmonic effect of green synthesized silver nanoparticles. J. Sci.: Adv. Mater. Devices 2, 418–424 (2017)

    Google Scholar 

  20. A.M. Hussein, A.V. Iefanova, R.T. Koodali, B.A. Logue, R.V. Shende, Interconnected ZrO2 doped ZnO/TiO2 network photoanode for dye-sensitized solar cells. Energy Rep. 4, 56–64 (2018)

    Google Scholar 

  21. R.K. Sonker, S.R. Sabhajeet, ZnO nanoneedle structure based dye sensitized solar cell utilizing solid polymer electrolyte. Mater. Lett. 223, 133–136 (2018)

    CAS  Google Scholar 

  22. A.H. Alami, M.A. Assad, K. Aokal, B. Rajab, H. Alawadhi, Application of icosahedral phase compound for mesoporous layer material in dye-sensitized solar cells. Proced. Eng. 184, 616–624 (2017)

    CAS  Google Scholar 

  23. H. Abdullah, N. HaslindaYunos, S. Mahalingam, M. Ahmad, B. Yuliarto, Photovoltaic and EIS performance of SnO2/SWCNTS based–sensitized solar cell. Proced. Eng. 170, 1–7 (2017)

    CAS  Google Scholar 

  24. G. Calogero, P. Calandra, A. Irrera, A. Sinopoli, I. Citro, G. Di Marco, A new type of transparent and low cost counter-electrode based on platinum nanoparticles for dye-sensitized solar cells. Energy Environ. Sci. 4, 1838 (2011)

    CAS  Google Scholar 

  25. R.S. Moraes, E. Saito, D.M.G. Leite, M. Massi, A.S. da Silva Sobrinho, Optical, electrical and electrochemical evaluation of sputteredplatinum counter electrodes for dye sensitized solar cells. Appl. Surf. Sci. 364, 229–234 (2016)

    CAS  Google Scholar 

  26. S. Widodo, G. Wiranto, M.N. Hidayat, Fabrication of dye sensitized solar cells with spray coated carbonnano tube (CNT) based counter electrodes. Energy Procedia 68, 37–44 (2015)

    CAS  Google Scholar 

  27. Wu. Chaoyu, G. Li, X. Cao, B. Lei, X. Gao, Carbon nitride transparent counter electrode prepared by magnetronsputtering for a dye-sensitized solar cell. Green Energy Environ. 2, 302–309 (2017)

    Google Scholar 

  28. J. Ma, S. Qingfeng, Z. Fengbao, W. Mingxing, Improvement on the catalytic activity of the flexible PEDOT counter electrode in dye-sensitized solar cells. Mater. Res. Bull. 100, 213–219 (2018)

    CAS  Google Scholar 

  29. S. Hussain, S.A. Patil, A.A. Memon, D. Vikraman, B.A. Naqvi, S.H. Jeong, H.S. Kim, H.S. Kim, J. Jung, CuS/WS2 and CuS/MoS2 heterostructures for high performance counterelectrodes in dye-sensitized solar cells. Sol. Energy 171, 122–129 (2018)

    CAS  Google Scholar 

  30. J.W. Chew, M.H. Khanmirzaei, A. Numan, F.S. Omar, K. Ramesh, S. Ramesh, Performance studies of ZnO and multi walled carbon nanotubes-basedcounter electrodes with gel polymer electrolyte for dye-sensitized solar cell. Mater. Sci. in Semicond. Process. 83, 144–149 (2018)

    CAS  Google Scholar 

  31. X. De Yang, Y. Hu, G. Wang, G.D. Zhou, P. Li, B. Wu, Q.L. Song, Thermal evaporated C60 modified by Pt as counter electrode for dye sensitized solar cells. Chem. Phys. 513, 73–77 (2018)

    CAS  Google Scholar 

  32. A. Sarkar, A.K. Chakraborty, S. Bera, NiS/rGO nanohybrid: an excellent counter electrode for dye sensitized solar Cell. Sol. Energy Mater. Sol. Cells 182, 314320 (2018)

    Google Scholar 

  33. C.R. Dhas, A.J. Christy, R. Venkatesh, S.K. Panda, B. Subramanian, K. Ravichandran, P. Sudhagar, A.M. Raj, Low-cost and eco-friendly nebulizer spray coated CuInAlS2 counter electrode for dye-sensitized solar cells. Phys. B 537, 23–32 (2018)

    CAS  Google Scholar 

  34. Y. Huang, W.-C. Chen, R. Ghadari, X.-P. Liu, X.-Q. Fang, Yu. Ting, F.-T. Kong, Highly efficient ruthenium complexes with acetyl electron-acceptor unit for dye sensitized solar cells. J. Power Source 396, 559–565 (2018)

    CAS  Google Scholar 

  35. Lu. Futai, S. Qi, J. Zhang, G. Yang, B. Zhang, Y. Fen, New benzoselenadiazole-based D-A-π-A type triarylaminesensitizers for highly efficient dye sensitized solar cells. Dyes Pigm. 141, 161–168 (2017)

    Google Scholar 

  36. T.M. El-Agez, S.A. Taya, K.S. Elrefi, M.S. Abdel-Latif, Dye-sensitized solar cells using some organic dyes as photosensitizers. Opt. Appl. (2014). https://doi.org/10.5277/oa140215

    Article  Google Scholar 

  37. S. Martins, J. Avo, J. Lima, J. Nogueira, L. Andrade, A. Mendes, A. Pereira, P.S. Branco, Styryl and phenylethynyl based coumarin chromophores for dye sensitized solar cells. J. Photochem. Photobiol. 353, 564–569 (2018)

    CAS  Google Scholar 

  38. S.H. Kang, S.Y. Jung, Y.W. Kim, Y.K. Eom, H.K. Kim, Exploratory synthesis and photovoltaic performance comparison of D–π–A structured Znporphyrins for dye-sensitized solar cells. Dyes Pigm. 149, 341–347 (2018)

    CAS  Google Scholar 

  39. Y. Zhao, J. Duan, B. He, Z. Jiao, Q. Tang, Improved charge extraction with N-doped carbon quantum dots in dye-sensitized solar cells. Electrochim. Acta. 282, 255–262 (2018)

    CAS  Google Scholar 

  40. L. Xu, C. Xin, C. Li, W. Wu, J. Hua, W. Zhu, Custom-designed metal-free quinoxaline sensitizer for dye-sensitized solar cells based on cobalt redox shuttle. Sol. Energy 169, 450–456 (2018)

    CAS  Google Scholar 

  41. Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide, L. Han, Dye-sensitized solar cells with conversion efficiency of 11.1%. Jpn. J. Appl. Phys. 45, L638–L640 (2006)

    CAS  Google Scholar 

  42. S. Xiong, Y. Wang, J. Lin, Yu. Xiaoyun, J. Tao, Wu. Yingying, Yu. Guipeng, C. Pana, Y. Yamauchic, D-π-A conjugated polymer dyes-covered TiO2 compact layers for enhancing photovoltaic performance of dye-sensitized solar cells. Synth. Met. 244, 73–79 (2018)

    CAS  Google Scholar 

  43. C.A. Ubani, M.A. Ibrahim, M.A.M. Teridi, Moving into the domain of perovskite sensitized solar cell. Renew. Sust. Energy Rev. 72, 907–915 (2017)

    CAS  Google Scholar 

  44. S. Sathyajothi, R. Jayavel, A.C. Dhanemozhi, The fabrication of natural dye sensitized solar cell (Dssc) based on TiO2 using henna and beetroot dye extracts. Mater. Today: Proc. 4, 668–676 (2017)

    Google Scholar 

  45. M.H. Bazargan, M.M. Byranvand, A.N. Kharat, L. Fatholahi, Natural pomegranate juice as photosensitizers for dyesensitized solar cell (DSSC). J. Optoelectron. Adv. Mater. 5(4), 360–362 (2011)

    CAS  Google Scholar 

  46. L.K. Singh, B.P. Koiry, Natural dyes and their effect on efficiency of TiO2 based DSSCs: a comparative study. Mater. Today: Proc. 5, 2112–2122 (2018)

    CAS  Google Scholar 

  47. M.S. Abdel-Latif, M.B. Abuiriban, T.M. El-Agez, S.A.Taya, Dye-sensitized solar cells using dyes extracted from flowers, leaves, parks, and roots of three trees. Int. J. Renew. Energy Res. 5(1) (2015)

  48. R. Kushwaha, P. Srivastava, L. Bahadur, Natural pigments from plants used as sensitizers for TiO2 based dye-sensitized solar cells. J. Energy (2013). https://doi.org/10.1155/2013/654953

    Article  Google Scholar 

  49. M.K. Hossain, M.F. Pervez, M.N. Mia, A.A. Mortuza, M.S. Rahaman, M.R. Karim, J.M. Islam, F. Ahmed, M.A. Khan, Effect of dye extracting solvents and sensitization time on photovoltaic performance of natural dye sensitized solar cells. Results Phys. 7, 1516–1523 (2017)

    Google Scholar 

  50. A.K. Swarnkar, S. Sahare, N. Chander, R.K. Gangwar, S.V. Bhoraskar, T.M. Bhave, Nanocrystalline titanium dioxide sensitised with natural dyes for eco-friendly solar cell application. J. Exp. Nanosci. 10(13), 1001–1011 (2015)

    CAS  Google Scholar 

  51. H. Chang, M.J. Kao, T.L. Chen, C.H. Chen, K.C. Cho, X.R. Lai, Characterization of natural dye extracted from wormwood and purple cabbage for dye-sensitized solar cells. Int. J. Photoenergy (2013). https://doi.org/10.1155/2013/159502

    Article  Google Scholar 

  52. K. Wongcharee, V. Meeyoo, S. Chavadej, Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Sol. Energy Mater. Sol. Cells 91, 566–571 (2007)

    CAS  Google Scholar 

  53. G. Richhariya, A. Kumar, Fabrication and characterization of mixed dye: natural and synthetic organic dye. Opt. Mater. 79, 296–301 (2018)

    CAS  Google Scholar 

  54. S.S. Khadtare, S.R. Jadkar, K.N. Hui, R.S. Mane, H.M. Pathan, Eosin-Y (EY), Rose Bengal (RB) and EY-RB sensitized ZnO solar cells. IEEE (2014). https://doi.org/10.1109/IRSEC.2014.7059876

    Article  Google Scholar 

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Acknowledgement

The authors from KKU express their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through research groups program under grant number R.G.P.2/38/40. Author T. Alshahrani would like to express her gratitude to Deanship of Scientific Research at Princess Nourah Bint Abdulrahman University for funding this research through the Fast-track Research Funding Program.

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Correspondence to N. Ruba or T. Alshahrani.

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Ruba, N., Prakash, P., Sowmya, S. et al. Recent Advancement in Photo-Anode, Dye and Counter Cathode in Dye-Sensitized Solar Cell: A Review. J Inorg Organomet Polym 31, 1894–1901 (2021). https://doi.org/10.1007/s10904-020-01854-6

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