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In situ Synthesis, Crystal Structure and Photoluminescence of a Novel Coordination Polymer with (4,6,6)-Connected sqc111 Topology

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Abstract

Employing the mixed ligands to react with Cd(NO3)2·4H2O afforded a new 3D coordination polymer [Cd3(BPTC)(bmp)2(ox)(H2O)4] (1) (H4BPTC = biphenyl-3,3′,4,4′-tetracarboxylic acid, bmp = 3,6-bis(imidazol-1-yl)pyridazine, H2ox = oxalic acid), in which ox2− was from the in situ oxidation of ethanol. Compound 1 bears a novel trinodal (4,6,6)-connected net structure, and it is the first replica of the theoretically predicted sqc111 topology net. Moreover, the thermal and photoluminescent properties for 1 were also investigated.

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References

  1. P. Silva, S.M.F. Vilela, J.P.C. Tomé, F.A. Almeida Paz, Chem. Soc. Rev. 44, 6774 (2015)

    Article  CAS  PubMed  Google Scholar 

  2. S.L. Qiu, G.S. Zhu, Coord. Chem. Rev. 253, 2891 (2009)

    Article  CAS  Google Scholar 

  3. D.S. Li, Y.P. Wu, J. Zhao, J. Zhang, J.Y. Lu, Coord. Chem. Rev. 261, 1 (2014)

    Article  CAS  Google Scholar 

  4. S.S.P. Dias, V. André, J. Kłak, M.T. Duarte, A.M. Kirillov, Cryst. Growth Des. 14, 3398 (2014)

    Article  CAS  Google Scholar 

  5. D.S. Li, J. Zhao, Y.P. Wu, B. Liu, L. Bai, K. Zou, M. Du, Inorg. Chem. 52, 8091 (2013)

    Article  CAS  PubMed  Google Scholar 

  6. D.S. Li, F. Fu, J. Zhao, Y.P. Wu, M. Du, K. Zou, W.W. Dong, Y.Y. Wang, Dalton Trans. 39, 11522 (2010)

    Article  CAS  PubMed  Google Scholar 

  7. M. Li, D. Li, M. O’Keeffe, O.M. Yaghi, Chem. Rev. 114, 1343 (2014)

    Article  CAS  PubMed  Google Scholar 

  8. L. Öhrström, Chem. Eur. J. 22, 13758 (2016)

    Article  CAS  PubMed  Google Scholar 

  9. E.V. Alexandrov, V.A. Blatov, A.V. Kochetkov, D.M. Proserpio, CrystEngComm 13, 3947 (2011)

    Article  CAS  Google Scholar 

  10. M. O’Keeffe, M.A. Peskov, S.J. Ramsden, O.M. Yaghi, Acc. Chem. Res. 41, 1782 (2008)

    Article  CAS  PubMed  Google Scholar 

  11. S.J. Ramsden, V. Robins, S.T. Hyde, Acta Crystallogr., Sect. A: Found. Adv. 65, 81 (2009)

    Article  CAS  Google Scholar 

  12. P.N. Zolotarev, M.N. Arshad, A.M. Asiri, Z.M. Al-amshany, V.A. Blatov, Cryst. Growth Des. 14, 1938 (2014)

    Article  CAS  Google Scholar 

  13. L.F. Ma, L.Y. Wang, M. Du, S.R. Batten, Inorg. Chem. 49, 365 (2010)

    Article  CAS  PubMed  Google Scholar 

  14. A.R. Oganov, A.O. Lyakhov, M. Valle, Acc. Chem. Res. 44, 227 (2011)

    Article  CAS  PubMed  Google Scholar 

  15. L.M. Fan, W.L. Fan, W.K. Song, L.M. Sun, X. Zhao, X.T. Zhang, Dalton Trans. 43, 15979 (2014)

    Article  CAS  PubMed  Google Scholar 

  16. X.L. Wang, J. Li, A.X. Tian, G.C. Liu, Q. Gao, H.Y. Lin, D. Zhao, CrystEngComm 13, 2194 (2011)

    Article  CAS  Google Scholar 

  17. Y. Li, Q. Zhou, W.D. Qiu, A. You, X.Z. Zou, J.Z. Gu, B. Chen, Chin. J. Struct. Chem. 36, 661 (2017)

    CAS  Google Scholar 

  18. V.A. Blatov, D.M. Proserpio, Acta Crystallogr., Sect. A: Found. Adv. 65, 202 (2009)

    Article  CAS  Google Scholar 

  19. D.S. Li, P. Zhang, J. Zhao, Z.F. Fang, M. Du, K. Zou, Y.Q. Mu, Cryst. Growth Des. 12, 1697 (2012)

    Article  CAS  Google Scholar 

  20. V.A. Blatov, Acta Crystallogr., Sect. A: Found. Adv. 63, 329 (2007)

    Article  CAS  Google Scholar 

  21. Y. Deng, P. Wang, Y. Zhao, Y.S. Kang, W.Y. Sun, Microporous Mesoporous Mater. 227, 39 (2016)

    Article  CAS  Google Scholar 

  22. G.F. Hou, X.D. Wang, Y.H. Yu, J.S. Gao, B. Wen, P.F. Yan, CrystEngComm 15, 249 (2013)

    Article  CAS  Google Scholar 

  23. A. Schoedel, A.J. Cairns, Y. Belmabkhout, L. Wojtas, M. Mohamed, Z.J. Zhang, D.M. Proserpio, M. Eddaoudi, M.J. Zaworotko, Angew. Chem. Int. Ed. 52, 2902 (2013)

    Article  CAS  Google Scholar 

  24. Y.L. Liu, K.F. Yue, D.S. Li, Y. Yu, L. Hou, Y.Y. Wang, CrystEngComm 15, 2791 (2013)

    Article  CAS  Google Scholar 

  25. Y.L. Gai, F.L. Jiang, K.C. Xiong, L. Chen, D.Q. Yuan, L.J. Zhang, K. Zhou, M.C. Hong, Cryst. Growth Des. 12, 2079 (2012)

    Article  CAS  Google Scholar 

  26. X.Y. Yu, X.B. Cui, J.J. Yang, J.P. Zhang, Y.H. Luo, H. Zhang, W.P. Gao, CrystEngComm 14, 4719 (2012)

    Article  CAS  Google Scholar 

  27. J.C. Zhong, F. Wan, Y.Q. Sun, Y.P. Chen, J. Solid State Chem. 221, 14 (2015)

    Article  CAS  Google Scholar 

  28. X.M. Chen, M.L. Tong, Acc. Chem. Res. 40, 162 (2007)

    Article  CAS  PubMed  Google Scholar 

  29. Q.F. Yang, X.B. Cui, J.H. Yu, J. Lu, X.Y. Yu, X. Zhang, J.Q. Xu, Q. Hou, T.G. Wang, CrystEngComm 10, 1531 (2008)

    Article  CAS  Google Scholar 

  30. S.M. Fang, M. Chen, X.G. Yang, J.Y. Hu, C.S. Liu, Inorg. Chem. Commun. 22, 101 (2012)

    Article  CAS  Google Scholar 

  31. B.Y. Li, D. Jin, B.H. Ma, D. Liu, G.H. Li, Z. Shi, S.H. Feng, Eur. J. Inorg. Chem. 35 (2011)

  32. S. Mohapatra, T.K. Maji, Dalton Trans. 39, 3412 (2010)

    Article  CAS  PubMed  Google Scholar 

  33. O.R. Evans, W.B. Lin, Cryst. Growth Des. 1, 9 (2001)

    Article  CAS  Google Scholar 

  34. T. Wang, C.X. Zhang, S.J. Deng, Y.J. Liu, W.M. Xiao, N. Zhang, J. Inorg. Organomet. Polym Mater. 28, 308 (2018)

    Article  CAS  Google Scholar 

  35. W. Kraus, G. Nolze, Powder Cell for Windows. Version 2.3. (Federal Institute for Materials Research and Testing, Germany, Berlin, 1999;, 1999)

    Google Scholar 

  36. E.V. Peresypkina, E.V. Lider, A.I. Smolentsev, J. Sanchiz, B. Gil-Hernández, A.S. Potapov, A. Khlebnikov, N.A. Kryuchkova, L.G. Lavrenova, Polyhedron 48, 253 (2012)

    Article  CAS  Google Scholar 

  37. G.M. Sheldrick, (SADABS, University of Göttingen, Göttingen, 1996)

  38. G.M. Sheldrick, SHELXTL–97, Program for the Solution of Crystal Structures, (University of Göttingen, Germany, 1997)

    Google Scholar 

  39. L.L. Zhang, J. Guo, Q.G. Meng, H.D. Pang, Z. Chen, D.F. Sun, Inorg. Chem. Commun. 26, 51 (2012)

    Article  CAS  Google Scholar 

  40. K. Wang, Z.L. Chen, H.H. Zou, Z. Zhang, W.Y. Sun, F.P. Liang, Cryst. Growth Des. 15, 2883 (2015)

    Article  CAS  Google Scholar 

  41. P. Thuéry, J. Harrowfield, Inorg. Chem. 54, 8093 (2015)

    Article  CAS  PubMed  Google Scholar 

  42. P.A. Prasad, S. Neeraj, R. Vaidhyanathan, S. Natarajan, J. Solid State Chem. 166, 128 (2002)

    Article  CAS  Google Scholar 

  43. E.H. N.Hao, Y.G. Shen, E.B. Li, C.W. Wang, L. Hu, Xu, Eur. J. Inorg. Chem. 4102 (2004)

  44. G.B. Deacon, R.J. Phillips, Coord. Chem. Rev. 33, 227 (1980)

    Article  CAS  Google Scholar 

  45. L. Du, T. Yan, Y.D. Zhao, X. Wang, X.C. Qian, Q. Wang, Q.H. Zhao, Inorg. Chim. Acta 453, 292 (2016)

    Article  CAS  Google Scholar 

  46. X.T. Zhang, L.M. Fan, W.L. Fan, X. Zhao, Inorg. Chim. Acta 441, 146 (2016)

    Article  CAS  Google Scholar 

  47. L.L. Wen, Z.D. Lu, J.G. Lin, Z.F. Tian, H.Z. Zhu, Q.J. Meng, Cryst. Growth Des. 7, 93 (2007)

    Article  CAS  Google Scholar 

  48. J.P. Li, J.Z. Fan, D.Z. Wang, Chin. J. Inorg. Chem. 32, 753 (2016)

    CAS  Google Scholar 

  49. J.F. Lu, Y.H. Xu, L.X. Jin, X.H. Guo, C.B. Zhao, N. Zheng, M. Jiang, H.G. Ge, Chin. J. Inorg. Chem. 33, 115 (2017)

    Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundations of China (No. 21663016), the Natural Science Foundations of Jiangxi Province (No. 2011ZBAB203013 and 20122BAB203010), and the Foundation of Educational Department of Jiangxi Province (No. GJJ12103).

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Authors and Affiliations

  1. Institute of Applied Chemistry, College of Chemistry, Nanchang University, Nanchang, 330031, Jiangxi, People’s Republic of China

    Tao Wang, Caiyu Wang, Shengjun Deng, Yijian Liu, Weiming Xiao & Ning Zhang

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  1. Tao Wang
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  2. Caiyu Wang
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  3. Shengjun Deng
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Wang, T., Wang, C., Deng, S. et al. In situ Synthesis, Crystal Structure and Photoluminescence of a Novel Coordination Polymer with (4,6,6)-Connected sqc111 Topology. J Inorg Organomet Polym 28, 1865–1871 (2018). https://doi.org/10.1007/s10904-018-0849-0

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